摘要：Fast electron-hole recombination issues during titanium dioxide(TiO_(2))photocatalysis limit its application in preventing bacterial infection during bone defect *** this study,TiO_(2)@reduced graphene oxide(rGO)composites were synthesized using a hydrothermal method in which rGO,which possesses very high electrical conductivity,promotes the separation of photoelectron-hole pairs of TiO_(2),thus improving the efficiency of photocatalytic production of reactive oxygen species(ROS).Subsequently,TiO_(2)@rGO composites were introduced into poly-L-lactic acid(PLLA)to prepare bone scaffolds with photocatalytic antibacterial function via selective laser *** results showed that TiO_(2)grew on the surface of rGO and formed a covalent bond connection(Ti-O-C)with rGO.A decreased electrochemical impedance of TiO_(2)@rGO composites was observed,and the transient photocurrent intensity increased from 0.05 to 0.5μA/cm^(2).Analysis of electron spin resonance found that the photocatalytic products of TiO_(2)were·OH and·O^(2-),two kinds of ROS capable of killing bacteria via disrupting the structure of the bacterial membrane in *** experiments showed that the PLLA/TiO_(2)@rGO scaffolds had good antibacterial properties against Escherichia coli and Staphylococcus ***,we report that these scaffolds exhibited both enhanced mechanical properties due to the addition of TiO_(2)@rGO as a reinforcement material and good biocompatibility during cell proliferation.

摘要：Metal sulfides are promising candidates for supercapacitors,but their slow reaction kinetics hinders their electrochemical *** electrochemical surface area and combination with conductive carbon are potential methods to improve their capacitive ***,seeking for a generalized and simple approach to prepare two-dimensional composites of metal sulfide and conductive carbon for supercapacitors is ***,a generalized and facile one-step pyrolysis method was designed for in situ growth of cobalt nickel sulfides(CoNi2S4)on reduced graphene oxide(rGO)nanosheets(CoNi2S4/rGO)under mild *** as-prepared CoNi2S4/rGO materials possess the nanoparticles-on-nanosheets structure,which is effective to provide a myriad of active sites and optimized electron/ion diffusion *** from those advantages,the resultant CoNi2S4/rGO electrodes exhibit impressed specific capacitances of 1526 and 988 F g^−1 at 2 and 20 A g^−1,*** supercapacitors based on CoNi2S4/rGO showcase an operation potential window of 1.6 V,and energy density of 54.8 W h kg^−1 at the power density of 798 W kg^−*** capacitance retention of the supercapacitor is about 93.7%after 8000 cycles at 3 A g^−***,a series of metal sulfide/rGO hybrids are obtained by this generalized strategy,which could be extended to construct electrode materials for various energy devices.

摘要：Exploring and designing a high-performance non-noble metal catalyst for hydrogen evolution reaction(HER)are crucial for the large-scale application of H2 by water ***,novel catalysts with NiMo nanoparticles decorated on reduced graphene oxide(NiMo@r GO)synthesized by a two-step hydrothermal method were *** characterization results showed that the prepared NiMo@r GO-1 had an irregular lamellar structure,and the NiMo nanoparticles were uniformly dispersed on the ***@rGO-1 exhibited outstanding HER performance in an alkaline environment and required only 93 and 180 mV overpotential for HER in 1.0 M KOH solution to obtain current densities of-10 and-50 mA·cm^(-2),*** tests showed that NiMo@rGO-1 had a certain operating stability for32 *** the same condition,the performance of NiMo@rGO-1 can be comparable with that of commercial Pt/C catalysts at high current *** synergistic effect between NiMo particles and lamellate graphene can remarkably promote charge transfer in electrocatalytic *** a result,NiMo@rGO-1 presented the advantages of high intrinsic activity,large specific surface area,and small electrical *** lamellar graphene played a role in dispersion to prevent the aggregation of *** prepared NiMo@rGO-1 can be used in anion exchange membrane water electrolysis to produce *** study provides a simple preparation method for efficient and low-cost water electrolysis to produce hydrogen in the future.

摘要：Interfacial solar steam generation is an efficient water evaporation technology which has promising applications in desalination,sterilization,water purification and treatment.A common component of evaporator design is a thermal-insulation support placed between the photothermal evaporation surface and bulk *** configuration,common in 2-dimensional(2 D)evaporation systems,minimizes heat loss from evaporation surface to bulk water,thus localizing the heat on the evaporation surface for efficient *** design is subsequently directly adopted for 3-dimensional(3 D)evaporators without any consideration if it is ***,unlike 2 D solar evaporators,the 3 D evaporators can also harvest additional energy(other than solar light)from the air and bulk water to enhance evaporation *** this scenario,the use of thermal insulator support is not proper since it will hinder energy extraction from ***,the traditional 3 D evaporator configuration was completely redesigned by using a highly thermally conductive material,instead of a thermal insulator,to connect evaporation surfaces and the bulk *** higher evaporation rates were achieved by this strategy,owing to the rapid heat transfer from the bulk water to the evaporation *** and outdoor tests both confirmed that evaporation performance could be significantly improved by substituting a thermal insulator with thermally conductive *** findings will redirect the future design of 3 D photothermal evaporators.

摘要：Interfacial solar-steam generation is a promising and cost-effective technology for both desalination and wastewater *** process uses a photothermal evaporator to absorb sunlight and convert it into heat for water *** solar-steam generation can be somewhat inefficient due to energy losses via conduction,convection and ***,efficient energy management is crucial for optimizing the performance of solar-steam ***,via elaborate design of the configuration of photothermal materials,as well as warm and cold evaporation surfaces,performance in solar evaporation was significantly *** was achieved via a simultaneous reduction in energy loss with a net increase in energy gain from the environment,and recycling of the latent heat released from vapor condensation,diffusive reflectance,thermal radiation and convection from the evaporation ***,by using the new strategy,an evaporation rate of 2.94 kg m^-2 h^-1,with a corresponding energy efficiency of solar-steam generation beyond theoretical limit was achieved.

摘要：Restraining the aggregation and polysulfide dissolution of edge-enriched metal sulfides is of significance for their applications as anode materials of lithium-ion batteries(LIBs)with high capacity and long *** this work,we have reported the incorporation of MoS2 nanocrystals into amorphous carbon on the surface of reduced graphene oxide(rGO)by balancing the decomposition rates of phenolic resin(PF)-impregnated ammonium thiomolybdate(ATM),which subsequently forms the MoS2@C/rGO film through redispersion and vacuum *** structural design effectively avoids the aggregation of MoS2 nanocrystals and Li2S loss,and meanwhile ion enrichment in amorphous carbon and diffusion reinforcement can greatly accelerate the electrochemical reaction *** applied as the selfstanding anode,the MoS2@C/rGO film possesses high reversible capacities of 1164 mA h g^-1 at the current density of 0.2 A g^-1 and 810 mA h g^-1 at 6.4 A g^-*** also exhibits quite a high capacity retention after 1000 cycles at 3.2 A g^-*** work develops the formation theory of incorporation structures and promotes their applications in energy storage devices.