摘要：Kirigami arts have provided a more promising method for building multiscale structures,which can shape two-dimensional(2D)sheets into three-dimensional(3D)configurations by cutting and ***,we first carried out a theoretical analysis of the mechanical properties of 2D honeycomb lattice structures and experimental verification combined with finite element(FE)***,a series of thick-walled 3D kirigami-inspired honeycomb(TW3KH)structures with different mechanical properties were designed and fabricated on the exploration and optimization of geometric parameters of 2D honeycomb *** investigations of folding feasibility,self-expansion,and self-folding performance experimentally showed that our designed four-dimensional(4D)printing structure had good programmability and shape memory capability and a large volume change ratio during shape ***,research on its compression deformation behavior found that the TW3KH structures can recover load-bearing capacity very well when the angle is ***,these TW3KH structures have great advantages in space-saving smart load-bearing equipment.

摘要：Combining the stability of chemical crosslinking and the processability of physical crosslinking is a well-established strategy to design new materials with desirable stimuli–responsive properties. Herein, a series of azobenzenebased thermotropic liquid crystalline polyesters were synthesized by introducing mesogenic dial named 4,4＇-bis（6-hydroxyhexyloxy）azobenzene（BHHAB）, 2-phenylsuccinic acid（PSA）, and different contents of 1,2,3-propanetricarboxylic acid（PTA） as the chemical crosslinker. All these polyesters showed good thermal stability and smectic liquid crystalline phase. Wide-angel X-ray diffraction（WAXD） and the fluorescence emission spectra confirmed the existence of π–πstacking interactions as the physical crosslinking in the polymer chains, particularly at the lower content of PTA. However, when the PTA content increased, the chemical crosslinking changed the chain conformation, and thus the intensity of physical crosslinking slackened gradually. Combining the physical and chemical crosslinking, these polyesters showed the thermoplastic processability, thermal shape memory, heat-assisted healing and photoresponsive behaviors. Taking advantages of these features, these multiple stimuli–responsive polymers can bring more chances for smart materials such as soft actuator.