摘要：The flammability of thermoplastic polyesters and the subsequent heavy smoke and severe melt drips formed after ignition are the main obstacles hindering their widespread application. In this study, a novel ionic monomer containing sulfonate and benzimidazole was synthesized and incorporated into the main chain of poly(ethylene terephthalate)(PET, used as a model thermoplastic polyester) by melt copolymerization. The synergetic effect of ionic aggregation and carbonization endowed the obtained copolyester with high melt viscosity and excellent char-forming ability at high temperatures. The copolyester having a monomer content of 8 mol.% easily achieved the Underwriters Laboratories Inc 94(UL-94) V-0 flammability rating without dripping and the limiting oxygen index value reached 33.0 vol.%.In addition, the total smoke production, peak heat release rate,and maximum CO production decreased by 45.2%, 60.5%, and75.0%, respectively, compared with those of PET. In addition,the copolyester was spinnable, and showed greater adsorption efficiency(99.6%) for a cationic dye from solution compared to PET(6.5%), demonstrating the excellent affinity of the copolyester for the cationic dye. The obtained inherently firesafe PET copolyester has great potential for applications in flame retardant textiles, artwork base materials, and decorative materials for transportation applications.

摘要：Differences and similarities of durability design for concrete bridges in Chinese-code and Eurocode are identified and discussed. Exposure environment classes and regulations of the minimum concrete cover and strength of the two codes are compared and analyzed. Numerical calculations for predicting the durable life of bridges related to carbonization and chlorides corrosion （marine and de-icing） are conducted. The results show that provisions in the two codes can satisfy the durability requirements under carbonization whereas they cannot guarantee the durability for bridges in spray and splash zones. Enhancing the waterproof capacity and reducing the frequent use of de-icing agents are vital to improving the bridge durability. Some recommendations for upgrading the durability are also included.