摘要：Metal-based electrocatalysts with different sizes(single atoms,nanoclusters,and nanoparticles)show different catalytic behaviors for various electrocatalytic *** the coordination environment of active sites with precision to rationally design an efficient electrocatalyst is of great significance for boosting electrocatalytic *** review summarizes the recent process of heterogeneous supported single atoms,nanoclusters,and nanoparticles catalysts in electrocatalytic reactions,respectively,and figures out the construct strategies and design concepts based on their strengths and ***,four key factors for enhancing electrocatalytic performance,including electronic structure,coordination environment,support property,and interfacial interactions are proposed to provide an overall comprehension to readers in this ***,some insights into the current challenges and future opportunities of the heterogeneous supported electrocatalysts are provided.

摘要：A catalyst of ferroelectric-BaTiO_(3)@photoelectric-TiO_(2) nanohybrids(BaTiO_(3)@TiO_(2))with enhanced photocatalytic activity was synthesized via a hydrolysis precipitation combined with a hydrothermal *** to pure TiO_(2),pure BaTiO_(3) and BaTiO_(3)/TiO_(2) physical mixture,the heterostructured BaTiO_(3)@TiO_(2) exhibits significantly improved photocatalytic activity and cycling stability in decomposing Rhodamine B(RhB)and the degradation efficiency is 1.7 times higher than pure TiO_(2) and 7.2 times higher than pure BaTiO_(3).These results are mainly attributed to the synergy effect of photoelectric TiO_(2),ferroelectric-BaTiO_(3) and the rationally designed interfacial *** mesoporous microstructure of TiO_(2) is of a high specific area and enables excellent photocatalytic *** ferroelectric polarization induced built-in electric field in BaTiO_(3) nanoparticles,and the intimate interfacial interactions at the interface of BaTiO_(3) and TiO_(2) are effective in driving the separation and transport of photogenerated charge *** strategy will stimulate the design of heterostructured photocatalysts with outstanding photocatalytic performance via interface engineering.