摘要：Ti−Al−V−Nb alloys with the cluster formula,12[Al−Ti_(12)](AlTi_(2))+5[Al−Ti1_(4)](V,Nb)2Ti,were designed by replacing V with Nb based on the Ti−6Al−4V ***-track cladding layers and bulk samples of the alloys with Nb contents ranging from 0 to 6.96 wt.%were prepared by laser additive manufacturing to examine their formability,microstructure,and mechanical *** single-track cladding layers,the addition of Nb increased the surface roughness slightly and decreased the molten pool height to improve its *** alloy,Ti−5.96Al−1.94V−3.54Nb(wt.%),exhibited better geometrical accuracy than the other alloys because its molten pool height was consistent with the spread layer thickness of the *** microstructures of the bulk samples contained similar columnar β-phase grains,regardless of Nb *** grains grew epitaxially from the Ti substrate along the deposition direction,with basket-weaveα-phase laths within the columnar ***α-phase size increased with increasing Nb contents,but its uniformity *** the deposition direction,the Vickers hardness increased from the substrate to the *** Ti−5.96Al−1.94V−3.54Nb alloy exhibited the highest Vickers hardness regardless of deposition position because of the optimal matching relationship between theα-phase size and its content among the designed alloys.

摘要：From the perspective of biomechanics and forming technology,Ti−Fe−Zr−Sn−Y eutectic alloy was designed using a“cluster-plus-glue-atom”model,and then the alloy was prepared by laser additive manufacturing(LAM)on pure titanium *** mechanical properties of the alloy were evaluated using micro-hardness and compression tester,and the elastic modulus was measured by *** results show that the alloy exhibits a high hardness of HV(788±10),a high strength of 2229 MPa,a failure strain of 14%,and a low elastic modulus of 87.5 *** alloy also has good tribological,chemical,forming,and biological *** comprehensive performances of the Ti64.51Fe26.40Zr5.86Sn2.93Y0.30 alloy are superior to those of the Ti70.5Fe29.5 eutectic alloy and commercial Ti−6Al−4V *** the above-mentioned qualities make the alloy a promising candidate as LAM biomaterial.

摘要：The electrochemical dissolution and passivation of laser additive manufactured Ti6Al4V were investigated through Tafel polarization,potentiostatic polarization and AC impedance *** results show that the solution treatment−aging(STA)process aggravates the element micro-segregation compared to the annealing process,leading to varied Al and V contents of the phases from different *** is proven that either Al-rich or V-rich condition can highly affect the electrochemical dissolution behaviors due to thermodynamical instability caused by element *** dissolution rate in the metastable passivation process is controlled by the stability of the produced film that is affected by phases distribution,especially the difficult-to-dissolve *** then,the dissolution rate of the phases in the transpassivation region is consistent with the rank in the activation process because the dense film is not capable of being *** to the annealed sample,the higher dissolution rate of the STA sample is beneficial to the electrochemical machining(ECM)of Ti6Al4V.