摘要：A polymeric hydroxyl ferric phosphate(PHFP)was prepared by using a byproduct of titanium dioxide containing ferrous sulfate and phosphates under alkaline *** PHFP was used to immobilize lead(Pb)and cadmium(Cd)in *** transform infrared spectra,X-ray diffraction were applied to revealing the characteristics of PHFP,and the modified Tessier sequential extraction and column leaching experiment with simulated acid rain were used to assess the effectiveness of immobilization of Cd and Pb in soils by *** results showed that PHFP was indeed a polymer with complicated OH-Fe-P structure and consisted of Fe6(OH)5(H2O)4(PO4)4(H2O)2and Fe25(PO4)14(OH)***,the removal rates of DTPA-extractable Cd and Pb in soils reached up to33%and45%,and the water-soluble Cd and Pb decreased by56%and58%,respectively,when PHFP was added in soils at4%*** addition,the immobilization of Cd and Pb contributed to transforming water soluble,exchangeable and carbonate-bonded fractions to Fe and Mn oxides-bonded,organic-bonded and residual *** leaching with simulated acid rain,Cd and Pb release amount in PHFP amended soil declined by53%and52%,respectively,as compared with non-treated *** result implied that PHFP had a potential application for the remediation of Cd-and Pb-contaminated soils.