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摘要:Molybdenum-based catalysts have demonstrated significant potential in the electrocatalytic hydrogen evolution reaction(HER).However,the limited exposure of active sites and strong hydrogen adsorption result in suboptimal ***,a Mo_(2)N±MoSe_(2) heterojunction is prepared on carbon cloth(MNS/CC)to enhance the *** strong electronic interaction between Mo_(2)N and MoSe_(2),combined with the lower work function of Mo_(2)N,creates an intrinsic electric field at the heterojunction interface,which markedly improves charge transfer ***,the optimized electronic structure of Mo sites further enhances charge transfer and intrinsically catalytic activity in *** a result,MNS/CC requires overpotentials of mere 65 and 210 mV to achieve current densities of 20 mA cm^(−2) and 1 A cm^(−2),respectively,with a Tafel slope of only 96 mV dec−***,MNS/CC maintains stable operation at 1 A cm^(−2) for 240 h without significant *** results offer insights into the design of non-precious metal-based electrocatalysts for industrial hydrogen production.
摘要:The durability of trouser's appearance involves the durability of crease and seam line after pressing, bagging resistance, wrinkle resistance, pilling resistance on the surface during wear. These properties are very important for the tailored trousers. It is investigated how the durability of trousers appearance is related to properties of the blend ratio of wool and PET, the yarn structure and fabric mechanical properties.
摘要:This paper presents a discussion of the characters and design patterns of the digital texture design in fashion fabrics. It starts from the characters of fabric texture design, taking digital printing technology as a detailed example, and raises a possible design route and pattern of the innovative design of fashion fabrics under digital technology.
摘要:How to efficiently treat cancer in a minimally invasive manner has become one of the major focuses of recent developments in *** this research,biodegradable sodium alginate(SA)hydrogel encapsulated with NaHCO_(3)and glucose oxidase(GOX)was synthesized using Fe^(3+)as the crosslinker for the tumor chemodynamic therapy(CDT)and starvation therapy(ST).Material safety assessments revealed that this hydrogel possesses good in vitro and in vivo *** tumor microenvrionment(TME),the Fe^(3+)further reacted with the intracellular glutathione and was transformed into Fe^(2+),which triggered the Fenton reaction with the H_(2)O_(2)within TME and produced abundant highly toxic·OH(hydroxyl radicals)for efficient tumor ***,the GOXcatalyzed the enzymolysis of glucose to consume the nutrient of the tumor and enhance the H_(2)O_(2)level in ***,the CO_(2)bubbles that were generated from the decomposing of NaHCO_(3)promoted the contact between glucose and *** in this research would have important implications for the present status of tumor therapy.
摘要:一维二氧化锆纳米纤维(ZrO_(2)NFs)作为一种重要的无机材料,以其独特的结构特性、优异的化学/热稳定性,以及杰出的光学/电子性能而备受关注.生物模板法、相转化法、离心纺丝法和静电纺丝法是合成ZrO_(2)NFs的简便且高度通用的方法,在隔热、空气过滤、水净化、催化剂载体、染料敏化电池和锂离子电池等新兴应用领域具有巨大的潜力.本文对多孔、中空、层状、甚至三维自组装等多种结构的ZrO_(2)NFs的合成策略进行了详细的描述和分析.此外,本文还讨论了近年来打破陶瓷脆性、构建柔性ZrO_(2)NFs的革命性进展及其变形机制.接着介绍了ZrO_(2)NFs在隔热、环境修复、催化、电池等领域的应用成果.最后,我们提供了关于ZrO_(2)NFs的全面总结、关键挑战和未来展望.本文对未来新型ZrO_(2)NFs的研究具有一定的指导意义.
摘要:Rapid formation of a continuous endothelial cell(EC)monolayer with healthy endothelium function on the luminal surface of vascular implants is imperative to improve the longtime patency of small-diameter vascular *** the present study,we combined the contact guidance effects of aligned nanofibers,which enhance EC adhesion and proliferation because of its similar fiber scale with native vascular basement membranes,and aligned microfibers,which could induce EC elongation effectively and allow ECs *** was followed by successive immobilization of collagen IV and laminin to fabricate a biomimetic basement membrane(BBM)with structural and compositional *** hemolysis assay and platelet adhesion results showed that the BBM exhibited excellent ***,the adhered human umbilical vein endothelial cells(HUVECs)onto theBBMaligned along the orientation of the microfibers with an elongated morphology,and the data demonstrated that the BBM showed favorable effects on EC attachment,proliferation,and *** oriented EC monolayer formed on the BBM exhibited improved antithrombotic capability as indicated by higher production of nitric oxide and prostacyclin(PGI2).Furthermore,fluorescence images indicated that HUVECs could infiltrate into the BBM,implying theBBM’s ability to enhance transmural ***,theBBMpossessed the properties to regulate ECbehaviors and allow transmural ingrowth,demonstrating the potential to be applied as the luminal surface of small-diameter vascular implants for rapid endothelialization.
摘要:The design method of small-flow high-head centrifugal-vortex pump was presented. This pump, configured with inducer, complex-centrifugal impeller and open-vortex impeller, was put forward to deliver gas-liquid two-phase mixture. An HTB-5/60 type sample pump was developed and tested on a closed-loop test rig. Experimental studies on performance and cavitation tests for gas-liquid two-phase mixture were carried out compared with pure-water experimental results. Also the effect of gas phase on pump was analyzed and discussed. The experimental results show that performance and cavitation characteristics of the sample purnp deteriorates progressively with increasing volume fraction of gas. When the total capacity Qm is between 4.5 m^3·h^-1 and 6 m^3·h^-1 and the gas flow rate qg below 0.66 m^3·h^-1, or qg/Qm is lower than 15%, the characteristic curves are approximately parallel to those in pure water test, but the performance deteriorates sharply until an abrupt flow-cutting at a critical volume fraction of gas. This pump is found suitable for transporting gas-liquid two-phase mixture when working around rated capacity of 5 m^3·h^-1 with qglQm below 15%.
摘要:As an art, Chinese knot is aged and refreshing. Those kinds of knots have come down from time immemorial. It exemplified the wisdom of the working people. The knots have the beauty of plainness and nature. Applying it in modem decoration would give the Modem decorative art personality and all kinds of form are available. The two parts would interact and help each other forward. Through the research, this paper analyzed the styles and features of Chinese knot. As well as the development and application of Chinese knot in Modem decorative art. In order to make the theoretical bases, for the sake of inheriting and continuing fine folk arts.
摘要:The demand for advanced fiber biomaterials and medical devices has risen rapidly with the increasing of aging population in the world. To address this grand societal challenge, textile biomedical engineering(TBE) has been defined as a holistic and integrative approach of designing and engineering advanced fiber materials for fabricating textile structures and devices to achieve various functions such as drug delivery, tissue engineering and artificial implants, pressure therapy and thermal therapy,bioelectric/magnetic detection and stimulation for the medical treatment and rehabilitation of human body. TBE is multidisciplinary in nature and needs integration of cross disciplinary expertise in medical science, healthcare professionals, physiologists, scientists and engineers in chemistry, materials, mechanics, electronics, computing, textile and designers. Engineering fiber materials and designing textile devices for biomedical applications involve the integration of the fundamental research in physics, chemistry, mathematics, and computational science with the development of engineering principles and understanding on the relationship between textile materials/devices and human physiology, behaviour, medicine and health. Theoretical concepts have been advanced together with creating new knowledges created from molecules to cells, organs and body-textile systems, and developing advanced fiber materials, innovative textile devices and functional apparel products for healthcare,comfort, protection against harmful external environment, diseases prevention, diagnosis and treatment, as well as rehabilitations. A holistic, integrative and quantitative approach has been adopted for deriving the technical solutions of how to engineer fibers and textiles for the benefits of human health. This paper reviews the theoretical foundations for textile biomedical engineering and advances in the recent years.
摘要:静电纺丝技术是制备纳米纤维膜的一种有效、简易方法,广泛用于基于能量收集的可穿戴电子器件.然而,由于超低的性能以及难以建立稳定的温差,其在热电领域的应用鲜有报道.本文结合静电纺丝技术和表面涂层的方法设计了具有优异拉伸性能和热电性能的高取向有机/无机复合纳米纤维膜.取向结构有利于载流子的快速传输,与无序结构的纳米纤维膜相比,其热电功率因子增加了7倍.此外,基于独特的取向纳米纤维结构,我们设计了新颖的辐射冷却-光热加热电极用于制备光驱动热电器件,为构建薄膜热电器件面内温差提供了一种新思路.而且,通过将两个高取向有机/无机复合纳米纤维膜正交堆叠,组装了用于识别人体关节复杂运动的多方向应变传感器.这些研究将推动静电纺纳米纤维基热电器件在下一代可穿戴电子器件领域的发展和应用.
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