摘要：The design and construction of low‐cost and high‐performance hybrid materials for the photocatalytic hydrogen production reaction(HER)are extremely important for the large‐scale application of hydrogen ***‐organic frameworks(MOFs)are considered to be potential photocatalytic ***,monodisperse,small size,non‐precious metal transition metal phosphide Ni2P is encapsulated into a typical MOF(UiO‐66‐NH2)as a hybrid core‐shell cocatalyst to modify Zn_(0.5)Cd_(0.5)S for photocatalytic hydrogen ***2P is wrapped in UiO‐66‐NH_(2)via an in situ solvothermal method,and Zn_(0.5)Cd_(0.5)S sulfide is decorated with a core‐shell Ni_(2)P@UiO‐66‐NH_(2)cocatalyst to obtain ternary Ni_(2)P@UiO‐66‐NH_(2)/Zn_(0.5)Cd_(0.5)S composite *** and chemical characterization confirms that the ternary composites have good kinetic hydrogen production *** hydrogen production rate of 10%10 mg Ni_(2)P@UiO‐66‐NH_(2)/Zn_(0.5)Cd_(0.5)S reaches 40.91 mmol·g^(–1)·h^(–1)with an apparent quantum efficiency at 420 nm of 13.57%.The addition of 10 mg Ni_(2)P@UiO‐66‐NH_(2)increases the surface area of the ternary material,providing abundant reaction sites and forming an efficient charge transfer channel,which is conducive to efficient hydrogen production by the ternary *** is shown that the formation of a ternary composite system is beneficial to the occurrence of an efficient catalytic *** study provides a new perspective for the construction of high‐performance photocatalytic materials.

摘要：Nanocatalysts consisting of three‐dimensionally ordered macroporous(3DOM)TiO2‐supported ultrafine Pd nanoparticles(Pd/3DOM‐TiO2‐GBMR)were readily fabricated by gas bubbling‐assisted membrane reduction(GBMR)*** catalysts had a well‐defined and highly ordered macroporous nanostructure with an average pore size of 280 *** addition,ultrafine hemispherical Pd nanoparticles(NPs)with a mean particle size of 1.1 nm were found to be well dispersed over the surface of the 3DOM‐TiO2 support and deposited on the inner walls of the *** nanostructure of the 3DOM‐TiO2 support ensured efficient contact between soot particles and the *** large interface area between the ultrafine Pd NPs and the TiO2 also increased the density of sites for O2 activation as a result of the strong metal(Pd)‐support(TiO2)interaction(SMSI).A Pd/3DOM‐TiO2‐GBMR catalyst with ultrafine Pd NPs(1.1 nm)exhibited higher catalytic activity during diesel soot combustion compared with that obtained from a specimen having relatively large Pd NPs(5.0 nm).The T10,T50 and T90 values obtained from the former were 295,370 and 415°*** the activity and nanostructure of the Pd/3DOM‐TiO2‐GBMR catalyst were stable over five replicate soot oxidation *** results suggest that nanocatalysts having a 3DOM structure together with ultrafine Pd NPs can decrease the amount of Pd required,and that this approach has potential practical applications in the catalytic combustion of diesel soot particles.

摘要：Conventional f-x prediction filtering methods are based on an autoregressive model. The error section is first computed as a source noise but is removed as additive noise to obtain the signal, which results in an assumption inconsistency before and after filtering. In this paper, an autoregressive, moving-average model is employed to avoid the model inconsistency. Based on the ARMA model, a noncasual prediction filter is computed and a self-deconvolved projection filter is used for estimating additive noise in order to suppress random noise. The 1-D ARMA model is also extended to the 2-D spatial domain, which is the basis for noncasual spatial prediction filtering for random noise attenuation on 3-D seismic data. Synthetic and field data processing indicate this method can suppress random noise more effectively and preserve the signal simultaneously and does much better than other conventional prediction filtering methods.

摘要：The electronic modulation characteristics of efficient metal phosphide electrocatalysts can be utilized to tune the performance of oxygen evolution reaction(OER).However,improving the overall water splitting performance remains a challenging *** building metal organic framework(MOF)on MOF heterostructures,an efficient strategy for controlling the electrical structure of MOFs was presented in this ***-67 was in-situ synthesized on MIL-88(Fe)using a two-step self-assembly method,followed by low-temperature phosphorization to ultimately synthesize FeP-CoP_(3)bimetallic *** combining atomic orbital theory and theoretical calculations(density functional theory),the results reveal the successful modulation of electronic orbitals in FeP-CoP_(3)bimetallic phosphides,which are synthesized from MOF on MOF *** synergistic impact of the metal center Co species and the phase conjugation of both kinds of MOFs are responsible for this regulatory ***,the catalyst demonstrates excellent properties,demonstrating HER 81 mV(η10)in a 1.0 mol L^(−1)KOH solution and OER 239 mV(η50)low *** FeP-CoP_(3)linked dual electrode alkaline batteries,which are bifunctional electrocatalysts,have a good electrocatalytic ability and may last for 50 *** require just 1.49 V(η50)for total water *** this technique,the electrical structure of electrocatalysts may be altered to increase catalytic activity.

摘要：Scaled physical model tests for steam breakthrough were conducted based on the analysis of mechanisms and influence factors of steam breakthrough. Physical simulation results showed that at the initial steam breakthrough, preferential flow channels were formed in narrow sand packs and most residual oil left in these channels was immobile. This shortened the steam breakthrough time of follow-up steam flooding and decreased the increment of oil recovery efficiency. Steam breakthrough occurred easily for a smaller producer-injector spacing, and a bigger difference in physical properties between fluids and rock. Steam breakthrough is more likely to occur at a larger formation permeability （k）, greater steam displacement velocity （u） and smaller producer-injector spacing （L）. Steam breakthrough time is a function of the parameter group （uk/L）, i.e. tb=3.2151 （uk/L）^-0.5142. A non piston-like displacement model was built based on steam breakthrough observation for a steam stimulated well in the Jinglou Oilfield, Henan Oilfield Company. The steam volume swept in different directions could be obtained from inter-well permeability capacity and breakthrough angle, and the steam swept pore volume （SSPV） was also determined. Numerical simulation showed that steam sweep efficiency reached its peak value when a slug of profile control agent （slug size 10%-15% SSPV） was set at one half of the inter-well spacing. Field test with 12.5% SSPV of profile control agents in the Jinglou Oilfield achieved success in sealing breakthrough channels and good production performance of adjacent producers.

摘要：In this paper, the novel control structures of differential pressure thermally coupled reactive distillation process for methyl acetate hydrolysis were proposed. The RadFrac module of Aspen Plus was adopted in the steady-state simulation. Sensitive analysis was applied to find the stable intial value and provide a basis for the improved control structure design. The Aspen Dynamics software was adopted to study the process dynamic behaviors, and two novel control structures provided with feed ratio controllers and sensitive tray temperature controllers were proposed. The reflux ratio controllers were applied in the improved novel control structures. Both control structures abandoned the composition controllers that were replaced by simpler controllers with which the product purity could meet the specification requiring under a ± 20% disturbance to the total feed flowrate / MeAc composition.

摘要：The C–H bond activation in alkane dehydrogenation reactions is a key step in determining the reaction *** understand the impact of entropy,we performed ab initio static and molecular dynamics free energy simulations of ethane dehydrogenation over Co@BEA zeolite at different *** simulations showed that a sharp decrease in free energy barrier as temperature *** analysis of the temperature dependence of activation free energies uncovered an unusual entropic effect accompanying the *** unique spatial structures around the Co active site at different temperatures influenced both the extent of charge transfer in the transition state and the arrangement of 3d orbital energy *** provided explanations consistent with the principles of thermodynamics and statistical *** insights gained at the atomic level have offered a fresh interpretation of the intricate long-range interplay between local chemical reactions and extensive chemical environments.

摘要：The experimental study was carried out to optimize the nozzle shape and dimension for the pulse cleaning of a ceramic filter candle. A bench scale unit of ceramic filter consisting of four commercial filter elements was used to measure the traces of the transient pressure around the nozzle and the overpressure in the filter cavity during the pulse-jet injection of pulse gas. Overpressure in the filter cavity is related to the pulse cleaning force. Nozzle design is concerned to increase the overpressure at the open end of filter element of pulse cleaning inlet, as well as to minimize the consumption of pulse gas. Convergent nozzle induces more secondary flow and generates higher pulse cleaning effect than straight nozzle. Nozzles of different convergent ratio （ratio of outlet to inlet diameter of nozzle） by changing the convergent angle and height were tested. The outlet diameter of convergent nozzle seriously influences the cleaning effect. The optimum convergent ratio increases with the increase of pulse gas pressure The nozzle position （distance of nozzle tip from the open end of filter inlet） is also important to decide the nozzle dimension. Nozzle of large outlet diameter accepts high pressure of pulse gas to provide large overpressure in the filter cavity of top position by applying long distance.

摘要：Digital radiographic(DR)testing equipment has been widely promoted and applied in the inspection of circumferential welds in oil and gas *** order to establish a comprehensive quality control system for digital radiographic testing and fully evaluate the integrated system inspection ability of equipment,personnel,and processes,a scientific and standardized evaluation method to the system is very *** investigates the precedents of relevant non-destructive testing evaluation methods at home and abroad,considers the testing characteristics of DR equipment,develops a complete set of DR testing system evaluation *** deeply studies the adaptability methods of program processes from defect production to slicing processing and data statistical calculation for digital radiographic testing *** check the repeatability and reliability of the detectable system,five process welds with 200 real metallographic defects were fabricated in the *** the detected results,the DR system has good repeatability in image quality,and the detectable defect size reaches 0.85 mm under achieving 90%detection probability at a confidence level of 95%,the error of detected defect length is±2 mm,and the error of detected defect localization is±5 *** qualitative and quantitative detection of defects are accurate and *** test further confirmed the reliable detection ability of the DR detection system,and fully validated the scientific and practical evaluation method *** research on the evaluation test method can serve as an important link in the quality control system for the on-site application of digital ray equipment in long-distance *** designed program,test,and evaluation content can serve as an important basis for the formulation of relevant specifications or standards.

摘要：When a seismic wave propagates through subsurface viscoelastic media,the formation absorbs the high-frequency energy of the seismic wave more strongly than the low-frequency *** the depth and the off set increase,the diff erence between the logarithmic spectral areas with high and low frequencies gradually *** on this seismic wave characteristic,we have developed a novel Q-estimation method based on logarithmic spectral area diff erence of high and low frequencies(referred to as the LSAD_LH method).In this paper,we derive the theoretical relationship between the Q value and difference of logarithmic spectral areas with high and low frequencies and prove the applicability of the LSAD_LH method using a single-layer medium numerical *** verify the sensitivity of the LSAD_LH method to bandwidth selection and noise,we compare the LSAD_LH method with two credible methods—the logarithmic spectral ratio(LSR)and logarithmic spectral area diff erence(LSAD)methods using a synthetic model containing the random *** results demonstrate that the LSAD_LH method is not highly dependent on bandwidth,and in terms of noise immunity,it is signifi cantly better than the LSR method and has the same advantages as the LSAD *** further highlight the advantages of the LSAD_LH method,we apply the LSAD_LH and LSAD methods to the vertical seismic profi ling(VSP)numerical simulation of the multilayer media and the fi eld zero-off set VSP *** application of the two cases proves the applicability of the LSAD_LH method and the accuracy of the high Q-value estimation relative to the LSAD ***,via the transmission coeffi cient,the LSAD_LH method overcomes the weakness of the LSAD method.