摘要：Achieving a satisfactory energy-power combination in a supercapacitor that is based on all-carbon electrodes and operates in benign aqueous media instead of conventional organic electrolytes is a major challenge. For this purpose, we fabricated carbon nanoflakes （20-100 nm in thickness, 5-μm in width） containing an unparalleled combination of a large surface area （3,000 m2-g-1 range） and mesoporosity （up to 72%）. These huge-surface area functionalized carbons （HSAFCs） also had a substantial oxygen and nitrogen content （N10 wt.% combined）, with a significant fraction of redox-active carboxyl/phenol groups in an optimized specimen. Their unique structure and chemistry resulted from a tailored single-step carbonization-activation approach employing （2-benzimidazolyl） acetonitrile combined with potassium hydroxide （KOH）. The HSAFCs exhibited specific capacitances of 474 F-g-1 at 0.5 A.g-1 and 285 F-g-1 at 100 A.g-1 （charging time 〈 3 s） in an aqueous 2 M KOH solution. These values are among the highest reported, especially at high currents. When tested with a stable 1.8-V window in a 1 M Na2SO4 electrolyte, a symmetric supercapacitor device using the fabricated nanoflakes as electrodes yielded a normalized active mass of 24.4 Wh-kg-1 at 223 W·kg-1 and 7.3 Wh·kg-1 at 9,360 W·kg-1. The latter value corresponds to a charge time of 〈3 s. The cyclability of the devices was excellent, with 93% capacitance retention after 10,000 cycles. All the electrochemical results were achieved by employing electrodes with near-commercial mass loadings of 8 mg-cm-2.

摘要：In this study the flow field and the nanoparticle collection efficiency of supersonic/hypersonic impactors with different nozzle shapes were studied using a computational modeling approach. The aim of this study was to develop a nozzle design for supersonic]hypersonic impactors with the smallest possible cut-off size d5o and rather sharp collection efficiency curves. The simulation results show that the changes in the angle and width of a converging nozzle do not alter the cut-off size of the impactor; however, using a conical Laval nozzle with an L]Dn ratio less than or equal to 2 reduced d5o. The effect of using a cap as a focuser in the nozzle of a supersonic/hypersonic impactor was also investigated. The results show that adding a cap in front of the nozzle had a noticeable effect on decreasing the cut-off size of the impactor. Both fiat disks and conical caps were examined, and it was observed that the nozzle with the conical cap had a lower cut-off size.

摘要：采用DynaRICE二维河冰模型模拟弯道及其取水口附近的水面冰运动和堆积过程,探讨弯道取水口导冰筏的优化设计。该模型耦合了水动力方程和冰动力方程,分别采用有限元法和光滑粒子流体动力学法对水动力方程和冰动力方程进行求解。模拟得到弯道取水口处水流水力特性、不同角度导冰筏下河冰运动规律及其受力情况。结果表明河冰靠弯道凹岸一侧运动,并在取水口附近及其下游堆积,横向环流对河冰运动影响可忽略,取水口上游设置角度和长度合理的导冰筏可有效阻止河冰进入引水渠。但是,下游也需设置导冰筏来防止河冰在取水口下游堆积及向上游延伸到取水口。

摘要：针对药物构效关系呈非线性的特征,提出一种径基函数(radial basis function,RBF)-自适应偏最小二乘回归(adaptive partial least squares regression,APLSR)相结合的建模方法。该组合方法应用RBF实现自变量非线性变换,应用APLSR方法消除非线性变换后输出变量间存在的复共线性,并以模型的预报能力为目标,自适应地确定PLSR模型的最佳隐变量个数,从而获得预报性能良好的模型。本文将RBF-APLSR方法应用于含硫苯衍生物的定量构效关系建模,取得了令人满意的效果,其预报精度高于PLSR方法。