摘要：受到水合镁离子的高脱溶能垒和不良界面水分解行为的限制,水系镁离子电池通常受制于缓慢的离子传输动力学和严重的阴极溶解.为了克服这些障碍,受细胞膜两亲性结构的启发,我们成功构建了一种由疏水性聚(3,4-乙二氧基噻吩)(PEDOT)和亲水性α-MnO_(2)基底组成的MnO_(2)碳基阴极.结合实验和理论计算结果分析,PEDOT层可以有效提高整体电极的导电性,降低水合Mg^(2+)的脱溶能垒,并抑制阴极溶解,从而提高复合电极的性能.因此,本文所制备的复合电极表现出优越的速率性能(58.4mA hg^(-1),3Ag^(-1))和增强的长期循环稳定性(1000个循环后85.92mA hg^(-1),2Ag^(-1)),优于原始的α-MnO_(2)阴极.这项基于生物启发设计理念的工作将为水合镁离子电池的发展提供创新方向.

摘要：光催化废水产氢技术是缓解日益严峻的能源和环境危机的有效方法.然而,由于载流子复合率较高、太阳光利用率较低,目前光催化活性仍然难以满足工业发展的需要.基于以上问题,本文设计了具有全谱太阳光响应的黑磷敏化的金/氮化碳(BP/Au/CN)异质结光催化剂,该三元异质结可以在实现降解双酚A的同时,将水分解为氢气,其光催化产氢活性可达到195.8μmol h^(−1)g^(−1).此外,在紫外-可见光照射下,BP/Au/CN的光催化产氢活性可以达到1400.8μmol h^(−1)g^(−1),是CN或BP/CN样品的近70倍,Au/CN异质结的2倍.光催化活性的提高表明异质结中三种元素具有良好的协同作用.本文将一系列实验表征与理论计算相结合,对BP/Au/CN的光催化机理进行了系统研究.结果表明,黑磷的全谱太阳光吸收能力、金的电子传输介质作用以及三种材料匹配的功函数是其光催化活性提高的关键因素.此外,通过金和黑磷的欧姆接触以及Au/CN杂化体系中肖特基异质结的构筑,实现了电子从黑磷到金,再到氮化碳的单向转移,从而提高了载流子的传输性能.

摘要：In order to investigate the complex flow characteristics inside an unshrouded centrifugal impeller with splitter blades at off-design conditions,and analyze its influence on pump operation stability,a numerical simulation study was carried on using the curvature-corrected SST-CC turbulence model;the head and efficiency accorded with experimental *** pressure fluctuation,unsteady radial force and velocity were analyzed quantitatively and the numerical results indicate this:the peak to peak value of pressure fluctuation in the impeller channel gradually increases in the flow direction and at 0.49Qn,the slope of peak to peak value to normalized impeller channel behind the splitter blade is 8.57 times greater than that before the splitter *** greater the flow rate deviates from the design condition,the larger the peak to peak value of the pressure fluctuation and radial force;in particular at 0.27Qn,the maximum radial force is 194.29%greater than that of the design *** the operating flow rate is smaller than 0.83Qn,the stall occurs and the stall vortex could block the impeller discharge;as the flow rate decreases further,the pressure amplitude at rotational frequency gradually increases in the impeller channel and the prevailing frequency changes from the blade passage frequency(BPF)to the rotating stall frequency in the *** tip leakage vortex(TLV)is generated in the tip region and rotated move downstream in the impeller flow channel,and the backflows appear on the blade suction side and in the tip and the tongue regions;the smaller the flow rate,the more serious the TLV and backflow *** rotating stall causes uneven flow in the impeller channel,increasing the pressure fluctuation and the radial force,and resulting in an imbalance of the impeller rotation.

摘要：This paper proposes the cooling system type and cooling equipment type which are deep mine with high temperature during the construction,and presents auxiliary cooling measures making up duct temperature rise since compression and heat transfer temperature rise. The cooling system designed against Zhaolou mine's ground temperature and weather conditions,with its sprinkler room handling an average temperature difference up to 19.5～23.8 ℃,and the average enthalpy difference could reach 48.4～60.7 kJ/kg. At the same time,it gets a series of basic data used for mine construction during the cooling system design and equipment selection according to the measured results; using the analysis software Matlab,it obtains the change relations between the temperature of sprinkler room and fan export supply air temperature,wind casing temperature rise and fan export supply air temperature,working face temperature and supply air temperature,used for the mine cooling which has the similar conditions.