摘要：The special electronic characteristics and high atom usage efficiency of metal-nitrogen-carbon(M-N-C)materials have made them extremely attractive for oxygen reduction reactions(ORRs).However,it is inevitable that hydrogen peroxide(H_(2)O_(2))will be formed via the two-electron pathway in ***,the Cu nanoparticles(NPs)have been encapsulated into Ni doped hollow mesoporous carbon spheres(Ni-HMCS)to reduce the generation of H_(2)O_(2)in *** tests confirm that the introduction of Cu NPs improves the ORR performance *** obtained Cu/Ni-HMCS exhibits a half-wave potential of 0.82 V *** hydrogen electrode and a limited current density of 5.5 mA cm^(-2),which is comparable with the commercial Pt/***,Cu/Ni-HMCS has been used in Zn-air battery,demonstrating a high power density of 161 mW cm^(-2)and a long-term recharge capability(50 h at 5 mA cm^(-2)).The theoretical calculation proposes a tandem catalysis pathway for Cu/Ni multi-sites catalysis,that is,H_(2)O_(2)released from the Ni-N_(4)and Cu-N_(4)sites migrates to the Cu(111)face,on which the captive H_(2)O_(2)is further reduced to H_(2)*** work demonstrates an interesting tandem catalytic pathway of dual-metal multi-sites for ORR,which provides an insight into the development of effective fuel cell electrocatalysts.

摘要：氢键有机框架材料(HOFs)在催化领域具有巨大的潜力,但其孔道空间在去除溶剂后易塌陷,限制了其在光催化能源转换和存储方面的应用.本研究采用孔道分割策略成功设计并合成了一种稳定孔道结构、高效光催化CO_(2)还原活性的HOF催化剂.H4TBAPy分子通过与HOF孔道中大量的CH…π相互作用锚定自身,并将HOF的大孔道分隔成多个小空间,显著增加了HOF框架的稳定性.同时,富电子属性的H4TBAPy分子提升了HOF体系中电子的传输速率,从而提高了催化活性.这项研究为设计稳定、高性能的HOFs光催化剂提供了新策略.

摘要：化学取代是有效调节分子电导,产生多通道输运、量子干涉效应和其他机制的关键方法.但分子骨架和侧基之间存在复杂的相互作用,目前仍未被研究清楚.在本工作中,我们结合扫描隧道显微镜裂结实验技术和第一性原理计算方法,深入研究了具有不同σ和π侧基的分子电导.实验结果及理论分析表明,σ侧基的加入引起了分子前线轨道的对称性破缺并加剧了分子内散射,从而导致电导的降低.相反,π侧基引入了额外的电荷传输通道,实现了电荷传输的多通道效应,增加了分子的电导.这些发现为未来分子功能化和分子电子器件的设计提供了坚实的基础.

摘要：单价Ag+或Li+引入到类金刚石结构的MQ22-(M=Ga,In;Q=S,Se)阴离子基团中能合成出良好的二阶非线性光学(NLO)晶体材料.然而,这些晶体分别面临着较低的抗激光损伤阈值(LIDT)或二氧化硅易被腐蚀等缺点,严重限制了其在高功率激光应用中的实用性.在本研究中,基于类金刚石结构的ZnSe,我们采用[Se_(4)Zn_(13)]Se_(2)4→[ClRb_(3)Ba]Se_(24)非常规的聚阳离子取代策略,设计并合成了一种新型的盐包硫属化合物[Rb_(3)BaCl][In_(8)Se_(14)](1).化合物1属于压缩黄铜矿型硒化物并保持了与AgInSe_(2)相同的晶体对称性(I-42d空间群).值得注意的是,由于InSe_(4)四面体结构单元的平行排列,化合物1具有相位匹配的强二次谐波(SHG)响应(2.0倍于AgGaS_(2)@2.90μm).此外,聚阳离子[Rb_(3)BaCl]^(4+)的引入促进了光学带隙(2.02 eV)的增强,有效地避免了对2.09μm激光的双光子吸收;同时结合较低的热膨胀系数,使得化合物1表现出高的LIDT(3.2倍于AgGaS2@2.09μm).本研究验证了在类金刚石结构中进行聚阳离子取代的可行性,并成功获得了性能优异的中远红外NLO材料.

摘要：A novel assembly control algorithm named burst-size feedback adaptive assembly period （BFAAP） is proposed. The major difference between BFAAP and other similar adaptive assembly algorithms is that the control curve of BFAAP is dynamically adjusted according to the feedback of outgoing burst size. BFAAP is compared with two typical algorithms fixed assembly period （FAP） and min-burst length max- assembly period （MBMAP） in simulation in terms of burst size distribution and assembly period. Moreover, the transmission control protocol （TCP） performance over BFAAP is also considered and simulated.

摘要：The architecture of and the corresponding control algorithm for a devised optical cross-connect, limited- range wavelength converision wavelength interchangeable cross-connect （L-WIXC）, are presented. The performances of L-WIXC including blocking probability, switching time, and throughput are simulated. Cost comparison with wavelength selective cross-connect （WSXC） and WIXC is calculated. Key optical parameters, such as crosstalk, eye diagram, bit error rate, and linear Q factor, are measured and discussed.

摘要：In order to integrate heterogeneous location-aware systems into pervasive computing environment,a novel pervasive computing location-aware model based on ontology is presented.A location-aware model ontology(LMO)is *** location-aware model has the capabilities of sharing knowledge,reasoning and adjusting the usage policies of services dynamically through a unified semantic location *** last,the work process of our proposed location-aware model is explained by an application scenario.

摘要：The three-dimensional discontinuous deformation analysis(3D-DDA) is a promising numerical method for both static and dynamic analyses of rock systems. Lacking mature software, its popularity is far behind its ability. To address this problem, this paper presents a new software architecture from a software engineering viewpoint. Based on 3D-DDA characteristics, the implementation of the proposed architecture has the following merits. Firstly, the software architecture separates data, computing, visualization, and signal control into individual modules. Secondly, data storage and parallel access are fully considered for different conditions. Thirdly, an open computing framework is provided which supports most numerical computing methods; common tools for equation solving and parallel computing are provided for further development. Fourthly, efficient visualization functions are provided by integrating a variety of visualization algorithms. A user-friendly graphical user interface is designed to improve the user experience. Finally, through a set of examples, the software is verified against both analytical solutions and the original code by Dr. Shi Gen Hua.

摘要：This paper presents an embedded SRAM design for write buffer applications in flash *** write buffer is implemented with a newly proposed self-adaptive timing control circuit,an area-saving sense-latch circuit and 6 T SRAM cell units.A 2 kb SRAM macro with the area of 135μm×180μm is implemented in and applied to a 128 Mb NOR flash memory with the SMIC 65 nm NOR flash memory *** simulation and chip test results show that the SRAM write buffer is beneficial to high-density flash memory design.

摘要：An optimized micro-gated terahertz detector with novel triple resonant antenna is *** novel resonant antenna operates at room temperature and shows more than a 700% increase in photocurrent response compared to the conventional bowtie *** finite-difference-time-domain simulations,we found the performance of the self-mixing GaN/AlGaN high electron mobility transistor detector is mainly dependent on the parameters L gs（the gap between the gate and the source/drain antenna） and L w（the gap between the source and drain antenna）.With the improved triple resonant antenna,an optimized micrometer-sized AlGaN/GaN high electron mobility transistor detector can achieve a high responsivity of 9.45×102 V/W at a frequency of 903 GHz at room temperature.