摘要：非晶合金是非晶材料家族中的新成员,由于缺乏原子排列长程有序特征,具有独特的性能和广泛应用前景.然而,非晶合金的形成、成分设计和形变问题在该领域长期未得到解决,制约着新型非晶合金的高效开发.传统上,多组元非晶合金的成分设计主要遵循相图研究范式,以温度调控为出发点,确定低液相线的成分为落脚点,尤其强调深共晶成分.然而,对于缺乏相图的多组元体系则力所不及,亟需新的理论突破.本文综述了非晶转变中的热力学与动力学基本规律,重点探讨了热力学与动力学性质之间的关联性,尤其是梳理了材料熔化熵与熔点粘度、熔点等多个非晶形成经典参量之间的内在关联,提出并论证了熔化熵和振动熵为非晶形成的关键热力学参量,可有效指导高性能非晶合金的设计和表征.结合实际应用中对非晶材料的工程要求,讨论了化学成分调控对非晶合金剪切带的萌生密度和扩展稳定性的影响,并总结了在单调加载和疲劳加载条件下剪切带行为对非晶合金断裂过程的作用.最后展望了振动熵和构型熵之间争议问题,提出未来工作中需要发展具有物理意义玻璃形成能力指标和可靠数据库的需求,混合加载模式下的韧性以及疲劳和韧性之间的权衡等问题.本文为进一步建立高性能非晶材料成分设计路径提供了参考与指导.

摘要：Crimping is widely adopted in the production of large-diameter submerged-arc welding pipes. Traditionally, designers obtain the technical parameters for crimping from experience or by trial and error through experiments and the finite element(FE) method. However, it is difficult to achieve ideal crimping quality by these approaches. To resolve this issue, crimping parameter design was investigated by multi-objective optimization. Crimping was simulated using the FE code ABAQUS and the FE model was validated experimentally. A welding pipe made of X80 high-strength pipeline steel was considered as a target object and the optimization problem for its crimping was formulated as a mathematical model and crimping was optimized. A response surface method based on the radial basis function was used to construct a surrogate model; the genetic algorithm NSGA-II was adopted to search for Pareto solutions; grey relational analysis was used to determine the most satisfactory solution from the Pareto solutions. The obtained optimal design of parameters shows good agreement with the initial design and remarkably improves the crimping quality. Thus, the results provide an effective approach for improving crimping quality and reducing design times.

摘要：铁电材料的力电耦合特性以及在纳米尺度的快速失效导致其剪切过程很难研究,而材料的脆性也限制了这些材料在铁电器件中的潜在应用.在这项工作中,我们使用分子动力学方法模拟了剪切和畴演变的动态过程,揭示了这些畴结构如何影响材料的力电性能.在原子尺度上,一个明显的极化旋涡状的畴结构出现在剪切带的尖端,两侧分别有180°和90°的畴壁.由应变梯度引起的挠曲电效应导致了这些复杂的畴结构.施加外部电场阻碍畴的翻转,并通过减少积累的能量减少了失配应变区域,加速了剪切过程.结果表明极化旋涡畴阻碍了剪切破坏过程,这启示我们可以通过设计畴结构来增韧铁电材料.