摘要：TiO_(2)-based materials have been considered as one of most promising alternatives for high-performance Li(Na)-ion batteries because of the low cost,simple composition,easy synthesis,good environmental protection,excellent safety and relatively high specific ***,the inferior electronic conductivity and poor ion diffusion coefficients are the biggest bottlenecks that restrict the popular *** effort has been focused on resolving these problems toward large-scale applications,and numerous significant advances have been *** the present work,a comprehensive overview of structure characteristics,electrochemical reaction mechanism and modification strategies of TiO_(2)-based materials was *** recent advances of various efficient ways for improving conductivity,Li(Na)storage capacity,rate capability and cycle stability are systematically summarized,including surface engineering,constructing composite and element doping,*** TiO_(2)-based materials with novel porous heterogeneous core-shell structures have been regarded as one of the most effective ways to resolve these ***,the future research directions and development prospects of TiO_(2)-based anode materials used in the manufacture of high-performance Li(Na)-ion batteries are *** review can provide important comprehension for the construction and optimization of highperformance of TiO_(2)-based anode materials.

摘要：Electrocatalytic nitrogen reduction reaction under ambient conditions is a promising pathway for ammonia *** nitrogen reduction reactions are carried out in N_(2)-saturated environments and use high-purity nitrogen as feedstock,which is ***,we prepared carbon-coated ultra-low 4d metal Ru-doped liquid metal Ga(Ru_(0.06)/LM@C)for NRR over a wide range of N_(2) *** analyses show that the introduction of the ultra-low 4d element Ru can effectively adjust the electronic structure through orbital interactions,thus enhancing the adsorption of nitrogen-containing *** liquid catalyst utilized its mobility to provide a higher density of active *** addition,the material Ru_(0.06)/Ga@C itself has the ability to promote product *** three act synergistically to optimize the N_(2) mass transfer path,thereby increasing the*NNH coverage and further improving the ammonia yield over a wide range of N_(2) *** maximum NH_(3) yield of the catalyst can reach 126.0μg h^(-1) mgcat^(-1)(at–0.3 V ***)with high purity N_(2) as feed gas,and the Faraday efficiency is 60.4%at–0.1 V *** a wide range of N_(2) concentrations,the NH_(3) yield of the catalyst was greater than 100μg h^(-1) mgcat^(-1) with a Faraday efficiency higher than 47%.The catalytic performance is much higher than that of solid Ga@C and reported p-block metal-based catalysts.

摘要：In order to improve the energy efficiency, reduce the CO2 emission and decrease the cost, a cogenera- tion system for desalination water, heat and power production was studied in this paper. The superstructure of the cogeneration system consisted of a coal-based thermal power plant （TPP）, a multi-stage flash desalination （MSF） module and reverse osmosis desalination （RO） module. For different demands of water, heat and power production, the corresponding optimal production structure was different. After reasonable simplification, the process model ot each unit was built. The economical model, including the unit investment, and operation and maintenance cost, was presented. By solving this non-linear programming （NLP） model, whose objective is to minimize the annual cost, an optimal cogeneration system can be obtained. Compared to separate production systems, the optimal system can reduce 16.1%-21.7% of the total annual cost. showing this design method was effective.

摘要：Two new metal-organic frameworks（MOFs）,[Cu2（H_2O）_2（BCPIA）]（BUT-20）and（Me_2NH_2）[In（BCPIA）]（BUT-21）were designed and synthesized through the solvothermal reaction between a newly created desymmetric 4-connected ligand,5-（2,6-bis（4-carboxyphenyl）pyridin-4-yl）isophthalic acid（H_4BCPIA）and Cu（NO_3）2 2.5H_2O or In（NO_3）_3·5H_2O,respectively,and characterized by single-crystal and powder Xray diffraction,thermogravimetric analysis,infrared spectroscopy,and elemental *** two MOFs have three-dimensional structures,in which both the BCPIA 4 ligand and metal-containing entities,Cu_2（COO）_4（H_2O）_2 and In（COO）_4 act as 4-connected ***,different linkage configurations of the two metal-containing nodes,quadrilateral Cu_2_TD_2（COO）_4（H_2O）_2and tetrahedral In（COO）_4,lead to distinct structural networks of BUT-20 and 21,with Nbo and Unc topologies,respectively.

摘要：Starch has a wide range of sources and can be used as a high-quality precursor for sodium-ion battery anode ***,the carbonization yield and specific capacity of carbon materials obtained by directly pyrolyzing starch are ***,starch is used as the carbon source,and ammonium polyphosphate(APP)is used as the cross-linking agent and dopant to prepare a nitrogen and phosphorus co-doped porous carbon(NPPC).As the anode for sodium-ion batteries,NPPC-2 exhibits a high reversible capacity of 385.8 mAhg^(-1)at 50 mAg^(-1).Even after 1000 cycles at a large current density of 5 Ag^(-1),the reversible capacity can still be maintained at 126.9 mAhg^(-1).Based on detailed data and first-principles calculations,the excellent performance of NPPC is due to the effective doping of nitrogen and phosphorus elements,which distorts the graphite sheet,introduces defects,and increases the graphite layer spacing,thereby enhancing the adsorption capacity of the carbon material for sodium ions,reducing the diffusion barrier of sodium *** work provides a new idea for heteroatom doping and carbon material modification.

摘要：By pairing two fluoropho res according to their optical prope rties such as absorption spectral overlap and absorptivity,fluorescent quantum yield and emission spectral separation,a bifunctional fluorescent probe,TQBF-NBD,was rationally designed and synthesized to discriminatively sense Hcy/Cys and GSH with good selectivity and *** is noted that this probe could work under a single-wave length excitation and displayed a mega-large Stokes ***-NBD reacted with Hcy/Cys to give a mixed green-red fluorescence and displayed a red fluorescence upon the treatment with *** imaging of intracellular Hcy/Cys from GSH with the help of TQBF-NBD was realized in living cells and zebrafish.

摘要：Aqueous rechargeable zinc-ion hybrid supercapacitors are considered to be a promising candidate for large-scale energy storage devices owing to their high safety,long life,and low *** this paper,a nitrogen doped hierarchical porous carbon is evaluated as the cathode for aqueous rechargeable zinc-ion hybrid *** from the synergistic merits of excellent structural features of N-HPC and tiny zinc dendrite of Zn anode in ZnSO4 electrolyte,the zinc-ion hybrid supercapacitor exhibits excellent energy storage performance including high capacity of 136.8 mAh·g^−1 at 0.1·Ag^−1,high energy density of 191 Wh·kg^−1,large power density of 3,633.4 W·kg^−1,and satisfactory cycling stability of up to 5,000 cycles with a capacity retention of 90.9%.This work presents a new prospect of developing high-performance aqueous rechargeable zinc ion energy storage devices.

摘要：A novel type of molecular tweezers with different chiral center and cleft has been designed and prepared by using α- hyodeoxycholic acid as spacer and D/L-amino acid methyl ester as chiral arm attached at 3-position. Their structures were elucidated by ^1H NMR, FTIR and elemental analysis. Their recognition properties for various D/L-amino acid methyl esters were also investigated. The preliminary results indicated that these chiral single-armed molecular tweezers exhibited good recognition ability for D/L-amino acid methyl esters with high association constant （up to 5.24 × 10^3 L mol^-1）.

摘要：CoFe_(2)O_(4)has been widely used for electromagnetic wave absorption owing to its high Snoek limit,high anisotropy,and suitable saturation magnetization;however,its inherent shortcomings,including low dielectric loss,high density,and magnetic agglomeration,limit its application as an ideal *** study investigated a microstructure regulation strategy to mitigate the inherent disadvantages of pristine CoFe_(2)O_(4)synthesized via a sol–gel auto-combustion method.A series of CoFe_(2)O_(4)foams(S0.5,S1.0,and S1.5,corresponding to foams with citric acid(CA)-to-Fe(NO_(3))_(3)·9H_(2)O molar ratios of 0.5,1.0,and 1.5,respectively)with two-dimensional(2D)curved surfaces were obtained through the adjustment of CA-to-Fe^(3+)ratio,and the electromagnetic parameters were adjusted through morphology *** to the appropriate impedance matching and conductance loss provided by moderate complex permittivity,the effective absorption bandwidth(EAB)of S0.5 was as high as 7.3 GHz,exceeding those of most CoFe_(2)O_(4)-based ***,the EAB of S1.5 reached 5.0 GHz(8.9–13.9 GHz),covering most of the X band,owing to the intense polarization provided by lattice defects and the heterogeneous *** three-dimensional(3D)foam structure circumvented the high density and magnetic agglomeration issues of CoFe_(2)O_(4)nanoparticles,and the good conductivity of 2D curved surfaces could effectively elevate the complex permittivity to ameliorate the dielectric loss of pure CoFe_(2)O_(4).This study provides a novel idea for the theoretical design and practical production of lightweight and broadband pure ferrites.

摘要：Ethanol is the main byproduct of anaerobic H2-producing fermentation in Klebsiella oxytoca HP1. Two moles of NAD(P)H are consumed to yield one mole of ethanol that may decrease bacterial hydrogen production. In this article the adhE gene that codes for acetaldehyde dehydrogenase was disrupted for the first time. A homologous recombination vector pTA-Str was constructed in which the adhE gene was disrupted by inserting an aminoglycoside-3'-adenyltransferase (aadA) gene. As expected, the vector includes the insertion 5′-adhE-aadA-adhE-3′. The amplified DNA fragment 5′-adhE-aadA-adhE-3′ from pTA-Str was transformed into K. oxytoca HP1 and one recombinant was obtained. PCR analysis of the resulting genomic DNA indicated the appropriate deletion and insertion. Compared with the H2-production of wild type K. oxytoca HP1, the hydrogen yield of the mutant increased by 16.07% and ethanol concentration decreased by 77.47%, suggesting that inactivation of the adhE gene in K. oxy- toca HP1 is a potential method for enhancing bacterial H2-production.