摘要：提出了一种将混沌序列变换成均匀伪随机序列的普适算法.这种算法基于计算机浮点数表示的bit位操作,不针对任何具体对象,可将任意连续或分段连续分布的实型随机变量转换成均匀分布的随机变量.理论分析表明,这种算法源于实型随机变量中普遍存在着的沿bit位以指数规律增强的均匀化趋势.任何实型的混沌序列,不论来自混沌映射系统还是混沌微分动力系统,都可以在同一个标准算法下变换成均匀分布的伪随机序列,因而是混沌伪随机数发生器标准化模块设计和硬件实现的关键技术基础.

摘要：β-Lapachone (β-Lap) is a promising orthonaphthoquinone drug for cancer treatment and has been inclinical trials. Its application is constrained by the low aqueoussolubility, and severe side effects. Even prodrug designation isan effective approach to render it with tumor selectivity, it islimited by the lack of modifiable groups on β-Lap. Herein, anovel azo bond primary cleavage and carbon–carbon (C–C)bond secondary cleavage-based polymeric β-Lap prodrug(Azo-Lap NP) is designed, in which the self-immolated paraaminobenzyl linker is connected to poly(L-glutamic acid)(PGlu) via azo linkage and the responsive drug release of β-Lapagainst tumors can be achieved under high NAD(P)H:quinoneoxidoreductase 1 (NQO1) expression and low pH environmentin tumors. The effective covalent loading of β-Lap by Azo-LapNPs permitted a high administration dose of β-Lap and enabled significant tumor retention time. Moreover, Azo-LapNPs markedly reduced the side effects of β-Lap by avoidinghemolysis and the production of methemoglobin. The safety ofAzo-Lap NPs administration is validated in the antitumorexperiment of mice. In the 4T1 model, Azo-Lap NPs exhibiteda markedly higher tumor suppression rate than β-Lap. Thiswork provides an effective and safe polymeric prodrug fortumor selective delivery of β-Lap.

摘要：A new ion-imprinted polymer （liP） was synthesized by copolymerization of 4-vinylpyridine （monomer）, ethyleneglycoldimethacrylate （cross-linker） and 2,2-azobis-isobutyronitrile （initiator） in the presence of Cd2＋ and quinaldic acid （complexing agent）. It was found that the adsorption capacity of IIP and blank polymer were 45.0 and 6.2 mg g-l, respectively. The relative selectivity coefficients of the imprinted polymer for different binary mixture were also calculated. Compared to non-imprinted polymer （NIP）, the IIP had higher selectivity for Cd（II）. The IIP was used as a sorbent for cadmium extraction from water samples by using a simple batch extraction procedure. The effect of different parameters on Cd2＋ extraction and its recovery from the IIP were evaluated and optimized by using experimental design methodology. The optimized adsorption/desorption procedure was applied for cadmium removal from the real water samples. The obtained recoveries proved that this IIP could be used for removal of trace cadmium ions from water samples.

摘要：It is presented in this paper that the new design and its analysis of finite difference domain decomposition algorithms for the two-dimensional heat equation, and the numerical results have shown the stability and accuracy of the algorithms, where SauFyev asymmetric schemes have been used at the interface points. The Algorithm II in this paper has further extended those developed by Dawson and the others, Zhang and Shen.

摘要：Based on the similarities in the conformation of VS008（N-（4-methylphenyl）-3-（tert-butyl）-1-（phenylmethyl）-1H-pyrazole-5-carboxamide） and BYIO6830（N＇-（3,5-dimethylbenzoyl）-N＇-tert-butyl-5-methyl-2,3-dihydro-l,4-benzodioxine-6-carbohydrazide） bound to the active site of the EcR subunit of the ecdysone receptor（EcR）-ultraspiracle protein（USP） heterodimeric receptor,a series of new pyrazole amide derivatives were designed and *** structures were confirmed by IR,~1H NMR,^（13）C NMR and elemental *** from a preliminary bioassay revealed that two of the pyrazole derivatives exhibited promising insecticidal ***,compounds 6e and 6i exhibited good activity against Helicoverpa armigera（cotton bollworm） at low *** displayed by tebufenozide-treated *** were identical with those displayed by its treated counterpart.6i showed the same poisoning symptoms as those of *** addition,results from molecular docking result indicated that the binding modes of 6e and 6i at the active site of the EcR subunit of the heterodimeric receptor were similar to that of the bound tebufenozide.

摘要：Water electrolysis technology holds the perfect promise of the hydrogen production,yet control of efficiency and rate of water electrolysis greatly relies on the availability of high-performance electrode materials for kinetic-sluggish oxygen evolution reaction(OER).Accordingly,substantial endeavors have been made to explore advanced electrode materials over the past ***,RuO_(2) and RuO_(2)-based materials have been demonstrated to be promising for OER due to their remarkable electrocatalytic activity and pH-universal ***,the great achievements and progresses of this flourishing spot are comprehensively reviewed,which are started by a general description of OER to understand the reaction mechanism in ***,the key advantages and issues of RuO_(2) towards OER are also introduced,followed by proposing many advanced strategies for further promoting the electrocatalytic OER performance of RuO_(2).Finally,the daunting challenges and future progresses of RuO_(2) electrocatalysts toward practical water oxidation are highlighted,aiming to provide guidance for the fabrication of desirable RuO_(2)-based electrocatalysts toward OER.

摘要：Hydrogenated amorphous Si （a-Si：H） is a promising material for photovoltaic applications due to its low cost, high abundance, long lifetime, and non-toxicity. We demonstrate a device designed to investigate the effect of nanostructured back reflectors on quantum efficiency in photovoltaic devices. We adopt a superstrate configuration so that we may use conventional industrial light trapping strategies for thin film solar cells as a reference for comparison. We controlled the nanostructure parameters via a wafer-scale self-assembly technique and systematically studied the relation between nanostructure size and photocurrent generation. The gain/loss transition at short wavelengths showed red-shifts with decreasing nanostructure scale. In the infrared region the nanostructured back reflector shows large photocurrent enhancement with a modified feature scale. This device geometry is a useful archetype for investigating absorption enhancement by nanostructures.

摘要：We investigate thermodynamics of the (2+1)-dimensional AdS black hole in grand canonical ensemble. In the York's formalism, the black hole is enclosed in a "box" with a finite radius and the boundary temperature, radius and potential are fixed in the grand canonical ensemble. We investigate the thermodynamical properties such as action,entropy, temperature, etc. We only find the stable solution for (2+1)-dimensional AdS black hole and do not find the instanton with the negative heat capacity.

摘要：In this study,the enhancement of catalytic activity of ceria when modified with co-catalysts such as graphitic carbon nitride and silver was establishe *** material was synthe sized using phytogenic combustion method,a green alternative to the traditional preparative *** catalyst was characterized using XRD,FTIR,SEM,EDX,XPS and TEM *** synergistic effect of the composite CeO2/g-C3 N4/Ag was tested for catalytic reduction of 4-nitrophenol in the prese nce of sodium *** reaction was carried out at room tempe rature without any light source or exte rnal *** individual and combined effects of four parameters,viz.,concentration of 4-NP,amount of catalyst,amount of NaBH4 and time for the reduction of reduction 4-NP were investigated using Box-Behnken design of response surface methodology(RSM).This statistical model was used to optimize the reaction conditions for maximum reduction of *** optimum conditions for the reduction reaction are found to be 0.01 mmol/L 4-NP,15 mg catalyst,20 mg NaBH4 and 13.7 min time interval.

摘要：Spectral and directional control of thermal emission based on excitation of confined electromagnetic resonant modes paves a viable way for the design and construction of microscale thermal emitters/absorbers. In this paper, we present numerical simulation results of the thermal radiative properties of a silicon carbide（Si C） thermal emitter/absorber composed of periodic microstructures. We illustrate different electromagnetic resonant modes which can be excited with the structure,such as surface phonon polaritons, magnetic polaritons and photonic crystal modes, and the process of radiation spectrum optimization based on a non-linear optimization algorithm. We show that the spectral and directional control of thermal emission/absorption can be efficiently achieved by adjusting the geometrical parameters of the structure. Moreover, the optimized spectrum is insensitive to 3% dimension modification.