摘要：An empirical formula for composition demixing analysis in cathodic arc ion plating using alloy target is established based on the concepts of average charged state and relative demixing parameter. The level of composition demixing effect is presented by demixing degree of one element. For binary constituent alloy target, the composition change trend in coating is discussed and the limit of demixing degree for each element is determined. The content of one element with higher average charged state gets larger in coating than in alloy target, at meantime, the content of one element with lower average charged state gets less. For each one of the two constituents, the less the atom percent in alloy target, the larger the difference of its contents between the coating and the target. For triple constituent alloy target, the content change of one element with moderate average charged state is discussed in detail. Its content in coating getting larger or less is determined by the combination result of the contents of the other two elements in alloy target. For a given content of the element with moderate average charged state in triple alloy target, the content deviation level of that element from coating to alloy target will be not larger than that using binary alloy target containing only that element and one of the two others. According to the wanted coating composition, the composition design of alloy target is easily deduced from the formula.

摘要：New empirical formulas of the transmission coefficient for permeable breakwaters were suggested based on available experimental data regarding the low-crest structure （LCS）, including the permeable rubble mound breakwater and pile-type breakwater. The rationality of the present formulas was verified by their comparison with existing empirical and analytical formulas. Numerical flume results were obtained by solving the modified Boussinessq-type wave equations （MBEs）, and a new expression relating the friction coefficient of to the relative submerged depth Rt/H8 was also derived. Comparative analysis shows that the results of the present formulas agree with the numerical flume results as well as available experimental data, and the present formulas are superior to the existing empirical and analytical expressions in estimating the transmission coefficient. The present formulas can provide references for estimation of the transmission coefficient in engineering practice.

摘要：In this article, we report the principle and conceptual design of a fundamentally different technology in fabricating high precision aberration free optical devices. The tip-tilt of facet in a mirror array is produced by digitally controlled line-tilts of rows and columns. It has not only provided a cost-effective designing methodology in optical physics but also led to a much finer precision of 1 mili arc sec or less. As examples of the application of the proposed digitalised optics, two case studies have been given： a 10 m Schmidt telescope （off-axis） and an 8 m Cassegrain telescope （on-axis）.

摘要：Prevailing tissue degeneration caused by musculoskeletal maladies poses a great demand on bioscaffolds,which are artificial,biocompatible structures implanted into human bodies with appropriate mechanical *** advances in additive manufacturing,i.e.,3D printing,facilitated the fabrication of bioscaffolds with unprecedented geometrical complexity and size flexibility and allowed for the fabrication of topologies that would not have been achieved *** our work,we explored the effect of porosity on themechanical properties of a periodic cellular *** structure was derived from the mathematically created triply periodic minimal surface(TPMS),namely the Sheet-Diamond ***,we employed a series of software including MathMod,Meshmixer,Netfabb and Cura to design the ***,we utilized additive manufacturing technology to fabricate the cellular structures with designated ***,we performed compressive testing to deduce the mechanical properties of each cellular *** showed that,in comparison with the highporosity group,the yield strength of the low-porosity group was 3 times higher,and the modulus was 2.5 times *** experiments revealed a specific relationship between porosity and Young’s modulus of PLA-made Sheet-Diamond TPMS ***,it was observed that the high-and low-porosity structures failed through distinctive mechanisms,with the former breaking down via buckling and the latter via micro-fracturing.

摘要：An alternative scheme is proposed for engineering three-dimensional maximally entangled states for two modes of a superconducting microwave cavity. In this scheme, an appropriately prepared four-level atom is sent through a bimodal cavity. During its passing through the cavity, the atom is coupled resonantly with two cavity modes simultaneously and addressed by a classical microwave pulse tuned to the required transition. Then the atomic states are detected to collapse two modes onto a three-dimensional maximally entangled state. The scheme is different from the previous one in which two nonlocal cavities are used. A comparison between them is also made,

摘要：A new muon and pion capture system is proposed for the China Spallation Neutron Source （CSNS）, currently under construction. Using about 4% of the pulsed proton beam （1.6 GeV, 4 kW and 1 Hz） of CSNS to bombard a cylindrical graphite target inside a superconducting solenoid, both surface muons and pions can be acquired. The acceptance of this novel capture system - a graphite target wrapped up by a superconducting solenoid - is larger than the normal muon beam lines using quadrupoles at one side of the separated muon target. The muon and pion production at different capture magnetic fields was calculated using Geant4. The bending angle of the capture solenoid with respect to the proton beam was also optimized in simulation to achieve more muons and pions. Based on the layout of the muon experimental area reserved at the CSNS project, a preliminary muon beam line was designed with multi-purpose muon spin rotation areas （surface, decay and low-energy muons）. Finally, high-flux surface muons （10S/s） and decay muons （109/s） simulated by G4beamline will be available at the end of the decay solenoid based on the first phase of CSNS. This collection and transport system will be a very effective beam line at a proton current of 2.5uA.

摘要：The GRACE Earth＇s gravitational field complete up to degree and order 120 is recovered based on the same and different three-axis resolution indexes from satellite-borne accelerometer using the improved energy conservation principle. The results show that designing XA1（2） as low-sensitivity axis （3 × 10^-9 m/s^2） of accelerometer and designing YA1（2） and ZA1（2） as high-sensitivity axes （3 × 10^-10 m/s^2） are reasonable. The physical reason why the resolution of XA1（2） is one order of magnitude lower than YA1（2） and ZA1（2） is that non-conservative forces acting on GRACE satellites are mainly decomposed into YA1（2） and ZA1（2） in the orbital plane. Since XA1（2） is not orthogonal accurately to orbital plane during the development of accelerometer, the measurement of XA1（2） can not be thrown off entirely, but be reduced properly.

摘要：In order to discover highly active ecdysone analogs, a series of new substituted pyrazole amide derivatives were obtained using structure-guided optimization method and further screened for their insecticidal activities, in the basis of the core structures of the two active compounds N-（3-methoxyphenyl）-3-（tert-butyl）-1-phenyl-1H-pyrazole-5-carboxamide（6e） and N-（4-（tert-butyl）phenyl）-3-（tert-butyl）-1-phenyl-1H-pyrazole-5-carboxamide（6i）, previously presented by us. The chemical structures of the title compounds were identified by spectral analyses. The preliminary bioassay results indicated that one among the synthesized pyrazole derivatives, compound 34, endowed with good activity against Mythimna Separata at 10 mg/L, which was equal to that displayed by the positive control tebufenozide. In addition, examples of molecular docking and molecular dynamics studies demonstrated that 34 may be the potential inhibitor to Ec R and its docking conformation was similar to that of tebufenozide. In addition, increasing the hydrophobic effect and considering the suitable bulk effect on pyrazole ring are beneficial to the inhibiting activity to Ec R and activity in vivo.

摘要：The design and synthesis of novel polypyrazolyl aromatic bridging ligands 1,3,5-tris（3,5-dimethyl-1-pyrazol-4-yl）benzene and 2,4,6-tris（4-（3,5-dimethyl-^1H-pyrazol-4-yl）phenyl）-1,3,5-triazine from simple starting materials mesitylene and p-tolunitrile were reported.

摘要：A novel pure and N-doped waved-graphene electro-catalyst with various wavelengths for oxygen reduction reaction（ORR） is explored in acid medium based on the firstprinciples calculations. The associative and dissociative mechanism are both explored from the O_2 adsorption to the H_2 O formation step by step, from which the dissociative mechanism is likely the only way with an effective 4e-process. Furthermore, a very favorable and effective mechanism is proposed for the ORR process, which may provide a guideline on the design of new non-metal electro-catalysts.