摘要：In order to design the relief system size of di-tert-butyl peroxide(DTBP) storage tanks,the runaway re-action of DTBP was simulated by accelerating rate calorimeter(ARC).The results indicated that under adiabatic conditions the initial exothermic temperature was 102.6 ℃,the maximum self-heating rate was 3.095×107 ℃·min-1,the maximum self-heating temperature was 375.9 ℃,and the pressure produced by unit mass was 4.512 MPa·*** by ARC test,the emergency relief system for DTBP was a hybrid *** on Design Institute for Emergency Relief System(DIERS) method,the releasing mass flow rate W was determined by Leung methods,and the mass velocity G was calculated by two modified Omega *** two relief sizes calculated by monograph Omega method and arithmetic Omega method are close,with only 0.63% relative *** monograph Omega method is more convenient to apply.

摘要：For further understanding of self-heating of coal, we tested the reactions of seven different ranks of coal under inert atmosphere. In the test, 50-gram of coal sample ranged from 0.18 mm to 0.38 mm was put into a special designed copper reaction vessel and let pure nitrogen to flow into the coal sample from the bottom at a rate of 100 mL/min. The programmed temperature enclosure was run at a programmed rate of 0.8 ~C/min. The concentration of the carbon oxides and the coal temperature were tested. The results show that the coal reactions under inert atmosphere can generate CO and C02. The reactions under inert atmosphere are affected by coal ranks, initial pore structure of coal and sulfur content. For low ranks of coal, the productions of carbon oxides are piecewise. The coal temperature is lower than the surrounding temperature throughout the reactions under inert atmosphere, but it rises quickly and reaches a crossing point temperature in the later stage under dry-air atmosphere. Based on the analysis, it indicates the self-reaction of initial active groups exists in the self-heating of coal besides the reactions in the two parallel reactions model. Spontaneous combustion of coal is due to both the oxidation heat accumulation and the chain reaction. A new reaction model of self-heating of coal was orooosed.

摘要：A further understanding of the self-heating of coal was obtained by investigating the crossing point temperature（CPT） of different ranks of *** tests were carried out using a self-designed experimental system for coal self-heating.50 g（±0.01 g） of coal particles ranging from 0.18 mm to 0.38 mm in size were put into a pure copper reaction vessel attached to the center of a temperature programmed *** temperature program increased the temperature at a rate of 0.8℃/*** air was permitted to flow into the coal reaction vessel at different *** surrounding temperature and the coal temperature were monitored by a temperature *** results indicate that CPT is affected by coal rank,moisture,sulfur, and the experimental *** ranked coals show higher CPT values.A high moisture content causes a delay phenomenon during the self-heating of the *** at 40℃decreases the effects of *** reactivity of sulfur components in the coal is low under dry and low-temperature conditions. These components form a film that covers the coal surface and slightly inhibits the self-heating of the coal. The flow rate of dry air,and the heating rate of the surroundings,also affect the self-heating of the *** most appropriate experimental conditions for coal samples of a given weight and particle size were determined through contrastive *** on this analysis we propose that CPTs be determined under the same,or nearly the same conditions,for evaluation of the spontaneous combustion of coal.

摘要：基于理论推导,结合实体实验及FDS模拟实验,讨论不同粒径细水雾扑救电缆舱火灾的灭火有效性。自行设计电缆舱灭火研究实验台,以聚氯乙烯电缆为研究对象进行全尺寸实验。对比空烧实验与粒径为80、110、150μm细水雾作用下的火场参数,结合FDS模拟粒径为50~250μm的9种工况,分析火场温度、O2体积分数及灭火时间变化规律。结果认为,在压力和流量满足一定条件的情况下,50~100μm细水雾扑救电缆舱的火灾效果较好;115~130μm是细水雾系统表面冷却机理过渡为隔氧窒息机理的临界粒径值;细水雾系统隔氧窒息作用的灭火效果优于表面冷却作用。