摘要：微生物电合成(microbial electrosynthesis,MES)利用可再生电力驱动微生物固定CO_(2)合成化学品,在推进碳循环经济中具有一定潜力,受到广泛关注。但是,很少有研究通过高效反应器设计来促进产乙酸并降低能耗。本研究中,新型流动电极MES反应器的总产乙酸速率[(16±1)g·m^(-2)·d^(-1)]比无粉末活性炭(powder activated carbon,PAC)对照[(8±3)g·m^(-2)·d^(-1)]高两倍。流动电极MES反应器的库伦效率为43.5%±3.1%,能量消耗为(0.020±0.005)k Wh·g^(-1),产乙酸的能量效率为18.7%±1.3%。基于PAC的流动电极能够降低水跨膜通量、传质阻力,但是对装置电压、流变行为、乙酸吸附的影响较小。流动电极MES反应器中,能量代谢相关基因高表达,Acetobacterium的丰度增加。MES反应器中同时存在用于碳固定的还原性乙酰辅酶A途径(Wood–Ljungdahl pathway,WLP)与还原性三羧酸循环途径(reductive citric acid cycle,r TCA)。堆叠型流动电极MES中的乙酸浓度达7.0 g·L^(-1)。本研究提供一种构建可扩展MES反应器的新方法,促进CO_(2)利用以及产物生成。

摘要：The design and preparation of suitable supports are of great importance for gold catalysts to attain excellent catalytic performance for alcohol *** this work,we found that ZnO-CuO mixed oxides supported gold catalysts showed much better catalytic activity for base-free aerobic oxidation of benzyl alcohol than Au/ZnO and Au/CuO catalysts,and among them Au/Zn0.7Cu0.3O displayed the best catalytic *** addition,the Au/Zn0.7Cu0.3O catalyst could selectively catalyze the aerobic oxidation of a wide range of alcohols to produce the corresponding carbonyl compounds with high yields under mild conditions without *** characterizations indicated that the outstanding catalytic performance of Au/Zn0.7Cu0.3O was correlated with the small size of Au nanoparticles(NPs),good low-temperature reducibility,high concentration of surface oxygen species,and collaborative interaction between Au NPs and mixed oxide.

摘要：The article uses a case study approach to investigate the mechanisms of ecological product value realization,and influencing ***,we use a case analysis framework based on the“economy-societynatural ecology”perspective to analyze and compare the three batches of“Typical Cases of Ecological ProductValue Realization”released by the Ministry of Natural *** find:First,different modes of ecologicalproduct value realization *** resource endowments,and institutional and environmental factors affectthe selection of the value realization ***,certain obstacles also exist for realizing ecological productvalue,which are mainly reflected in the fact that the articulation of the individual,society,and government is not yetsufficiently ***,to promote the development of regional eco-products’mode and value conversion,the implementing party needs to guide the synergy between individual concepts,social participation,and governmentaltop-level design;rationally arrange the allocation of resource elements;mitigate elemental constraints;and proposeeffective technical means and optimization strategies according to the actual situation.

摘要：CO2 is not only the most important greenhouse gas but also an important resource of elemental carbon and *** the perspective of resource and energy strategy,the conversion of CO2 to chemicals driven by renewable energy is of significance,since it can not only reduce carbon emission by the utilization of CO2 as feedstock but also store low-grade renewable energy as high energy density chemical *** studies on photoelectrocatalytic reduction of CO2 using renewable energy are increasing,artificial bioconversion of CO2 as an important novel pathway to synthesize chemicals has attracted more and more *** simulating the natural photosynthesis process of plants and microorganisms,the artificial bioconversion of CO2 can efficiently synthesize chemicals via a designed and constructed artificial photosynthesis *** review focuses on the recent advancements in artificial bioreduction of CO2,including the key techniques,and artificial biosynthesis of compounds with different carbon *** the basis of the aforementioned discussions,we present the prospects for further development of artificial bioconversion of CO2 to chemicals.

摘要：In order to achieve holistic urban plans incorporating transport infrastructure,public space and the behavior of people in these spaces,integration of urban design and computer modeling is a promising way to provide both qualitative and quantitative support to *** paper describes a systematic literature review following a four-part ***,to understand the relationship of elements of transport,spaces,and humans,w e review policy and urban design strategies for promoting positive ***,we present an overview of the integration methods and strategies used in urban design and policy ***,metrics and approaches for evaluating the effectiveness of integrated plan alternatives are ***,this paper gives a review of state-of-the-art tools with a focus on seven com puter simulation *** article explores mechanisms underlying the complex system of transport,spaces,and humans from a multidisciplinary perspective to provide an integrated toolkit for designers,planners,modelers and decision-m akers with the current methods and their challenges.

摘要：利用太阳能将CO_(2)光转化为化学燃料是前沿研究的热点.当前,科研的重点在于开发和优化各类光催化材料的性能.异质结构不仅用于增强无机半导体催化剂的活性,而且用于金属-有机框架(MOFs)光催化剂的构建.随着异质结技术的不断进步,新的相结概念应运而生.尽管关于无机半导体中的相结研究已取得一定进展,但是MOFs相结结构的探索尚处于起步阶段.本文中,我们成功设计并构建了一种具有卓越光催化CO_(2)还原性能的MOFs相结杂化材料.这种材料由具有高度连接性的卟啉配体(TCPP-Ni)与Zr6团簇紧密结合而成,在溶剂热反应条件下,PCN-222-Ni能够快速且均匀地成核.通过精准调控调节剂的用量,我们实现了同分异构体PCN-224-Ni在类似条件下较慢的晶体形成过程.最终制得的P@P杂化材料展现出高表面积、多孔性和卓越的结晶度.由于PCN-222-Ni和PCN-224-Ni之间的带隙匹配,光生载流子的分离和迁移得以促进,从而使P@P杂化材料展现出卓越的光还原CO_(2)性能.这一重大突破不仅标志着MOFs相结结构研究的重大进展,还拓宽了MOFs相结在CO_(2)光转化领域的应用前景.

摘要：精准估算陆地生态系统碳汇对中国制定碳减排措施、实现碳中和目标有重要科学支撑作用.大气反演方法基于大气二氧化碳浓度观测数据,可有效估算地面二氧化碳通量的时空分布.目前中国陆地生态系统碳汇的大气反演估算仍有巨大不确定性,其中一个重要瓶颈在于缺乏足够的二氧化碳观测站点.本文研发了针对中国区域的大气反演框架,提出了二氧化碳观测网络的站点布设方案以最大程度降低中国陆地碳汇反演估算的不确定性.研究表明,在现有站点基础上,亟需在生长季植被生产力较高的东南、东北、华北和青藏高原地区增设二氧化碳观测站点.若在中国建设30个大气二氧化碳观测站点可将碳汇估算不确定性从每年10亿吨碳降低至3亿吨碳;建设60个站点可将不确定性进一步降低至每年2亿吨碳.这些站点将是“天-空-地”综合碳观测系统的重要组成部分,服务于中国二氧化碳收支反演和精准核算.

摘要：For the purpose of enhancing air convection and controlling solar radiation, a new crushed-rock slope embankment design combined with a sun-shade measure is proposed. A newly designed embankment was constructed in the Tuotuohe section of the Qinghai-Tibet Railway and a field-testing experiment was carried out to determine its convection and temperature characteristics. The results show that distinct air convection occurred in the crushed-rock layer of the new embankment, especially in cold seasons, which was enhanced when it flowed upwards along the slope. This preliminarily indicated that the new design of the embankment slope was good for reinforcing air convection in the crushed-rock layer. The frequent fluctuations of the convection speed and the environmental wind speed were in good agreement, suggesting that the convection in the crushed rock primarily came from the ambient wind. It was also preliminarily determined that the new embankment had a better cooling effect and sun-shade effect for decreasing the temperature of the embankment slope compared with a traditional crushed-rock slope embankment, and the mean temperature difference between them was up to 1.7 °C. The mean annual temperature at the bottom boundary of the crushed-rock layer was obviously lower than that at the top boundary, and heat flux calculation showed that the shallow soil beneath the embankment slope was weakly releasing heat, all of which indicated that the new embankment slope design was beneficial to the thermal stability of the embankment. This study is helpful in providing some references for improved engineering design and maintenance of roadbeds in permafrost regions.

摘要：Chinese bayberry （Myrica rubra Sieb. et Zucc.） is one of the important subtropical fruit crops native to the South of China and Asian countries. In this study, 107 novel simple sequence repeat （SSR） molecular markers, a powerful tool for genetic diversity studies, cultivar identification, and linkage map construction, were developed and characterized from whole genome shotgun sequences. M13 tailing for forward primers was applied as a simple method in different situations. In total, 828 alleles across 45 accessions were detected, with an average of 8 alleles per locus. The number of effective alleles ranged from 1.22 to 10.41 with an average of 4.08. The polymorphic information content （PIC） varied from 0.13 to 0.89, with an average of 0.63. Moreover, these markers could also be amplified in their related species Myrica cerifera （syn. More/la cerifera） and Myrica adenophora. Seventy-eight SSR markers can be used to produce a genetic map of a cross between ＇Biqi＇ and ＇Dongkui＇. A neighbor-joining （N J） tree was con- structed to assess the genetic relationships among accessions, and the elite accessions ＇Y2010-70＇, ＇Y2012-140＇, and ＇Y2012-145＇, were characterized as potential new genotypes for cultivation.

摘要：At Quesang on the Tibetan Plateau we report a series of hand and foot impressions that appear to have been intentionally placed on the surface of a unit of soft *** travertine was deposited by water from a hot spring which is now inactive and as the travertine lithified it preserved the *** the basis of the sizes of the hand and foot traces,we suggest that two track-makers were involved and were likely *** interpret this event as a deliberate artistic act that created a work of parietal *** travertine unit on which the traces were imprinted dates to between~169 and 226 ka *** would make the site the earliest currently known example of parietal art in the world and would also provide the earliest evidence discovered to date for hominins on the High Tibetan Plateau(above 4000 m a.s.l.).This remarkable discovery adds to the body of research that identifies children as some of the earliest artists within the genus Homo.