摘要：In this work,a series of biodegradable pure iron,Fe–30Mn and Fe–30Mn–Ag alloys were developed by using a rapid solidification technology.A fine a-Fe dendrite was formed in pure iron,resulting in a high compressive yield strength of above 300 *** Fe–30Mn alloy doped with only 1%Ag exhibited a significant increase in the degradation rate in simulated body fluid due to the precipitation of Ag-rich particles in alloy matrix and the induction of the microgalvanic *** addition,the novel Fe–30Mn–Ag alloy also exhibited a good magnetic compatibility and offered a closely approaching requirement for biodegradable medical applications.

摘要：Self-healing metals possess the capability to autonomously repair structural damage during service. While self-healing concepts remain challenging to be realized in metals and metallic systems due to the small atomic volume of the mobile atoms, the slow diffusion unless at high temperatures and the strong isotropic metallic bonds, the scientific interest has increased sharply and promising progress is obtained. This article provides a comprehensive and updated review on the developments and limitations associated with the various modes of potentially healable damage induced in metals and alloys, i.e., stressinduced damage, irradiation-induced damage in bulk materials and contact damage in corrosion protective coatings. The spontaneous intrinsic healing mechanisms not requiring external assistance other than the material operating at the right temperature and an assisted healing mechanism with external intervention are reviewed. Promising strategies to achieve self-healing in metals are identified. Finally, we give some prospects for future research directions in self-healing metals.

摘要：TiO2 pigments are typically coated with inert layers to suppress the photocatalytic activity and improve the weatherability. However, the traditional inert layers have a lower refractive index compared to TiO2, and therefore reduce the lightening power of TiO2. In the present work, a uniform, amorphous, 2.9-nm-thick TiO2 protective layer was deposited onto the surface of anatase TiO2 pigments according to pulsed chemical vapor deposition at room temperature, with Ti Cl4 as titanium precursor. Amorphous TiO2 coating layers exhibited poor photocatalytic activity, leading to a boosted weatherability. Similarly, this coating method is also effective for TiO2 coating with amorphous SiO2 and SnO2 layers. However, the lightening power of amorphous TiO2 layer is higher than those of amorphous SiO2 and SnO2 layers. According to the measurements of photoluminescence lifetime, surface photocurrent density, charge-transfer resistance, and electron spin resonance spectroscopy, it is revealed that the amorphous layer can prevent the migration of photogenerated electrons and holes onto the surface, decreasing the densities of surface electron and hole, and thereby suppress the photocatalytic activity.

摘要：With the development of nanobiotechnology,the carbon nanotubes(CNTs)and protein hybrids system has attracted an increasing attention for great potential application in nanotechnology,medicine,smart materials,light industry,and *** this review,the main preparation processes,impact factors,measurement of interactions and potential applications of CNTs/protein are presented from the aspect of ***,the proper forces detection methods are illustrated comprehensively to complete the quantitative *** force microscope(AFM)and surface force apparatus(SFA)experiments are described in detail to confirm the powerful function in measuring the interaction *** addition,the impact of different protein structures(amino acid residues,αHelix,polypeptide chain,and assembled subunits)on interactions between CNTs and protein is presented and different amino acid residues may intervene largely on *** to the relatively little knowledge about the structure,function,and spatial orientation of proteins interaction with CNTs surface,we assume that the key problem is how to prepare CNTs and protein specimen with unique structure(such as the variation of secondary and tridimensional structure of protein or the single CNTs)to investigate the interaction forces instead of the designed,preparation,and detection methods.

摘要：Despite being a promising photoanode material for water splitting,WO_(3) has low conductivity,high onset potential,and sluggish water oxidation *** this study,we designed Ti-doped WO_(3) nanoplate arrays on fluoride-doped tin oxide by a seed-free hydrothermal method,and the effects of doping on the photoelectrochemical performance were *** optimal Ti-doped WO_(3) electrode achieved a photocurrent density of 0.53 mA/cm^(2) at 0.6 V(vs Ag/AgCl),110%higher than that of pure WO_(3) nanoplate ***,a significant cathodic shift in the onset potential was observed after doping.X-ray photoelectron spectroscopy valence band and ultraviolet–visible spectra revealed that the band positions of Ti-doped WO_(3) photoanodes moved upward,yielding a lower onset ***,electrochemical impedance spectroscopy measurements revealed that the conductivities of the WO_(3) photoanodes improved after doping,because of the rapid separation of photo-generated charge ***,we report a new design route toward efficient and low-cost photoanodes for photoelectrochemical applications.

摘要：Integrated printing of magnetic soft robots with complex structures using recyclable materials to achieve sustainability of the soft robots remains a persistent ***,we propose a kind of ferromagnetic fibers that can be used to print soft robots with complex *** ferromagnetic fibers are recyclable and can make soft robots *** ferromagnetic fibers based on thermoplastic polyurethane(TPU)/NdFeB hybrid particles are extruded by an *** use a desktop three-dimensional(3D)printer to demonstrate the feasibility of printing two-dimensional(2D)and complex 3D soft *** printed soft robots can be recycled and reprinted into new robots once their tasks are ***,these robots show almost no difference in actuation capability compared to prior versions and have new *** applications include lifting,grasping,and moving objects,and these functions can be operated untethered *** addition,the locomotion of the magnetic soft robot in a human stomach model shows the prospect of medical ***,these fully recyclable ferromagnetic fibers pave the way for printing and reprinting sustainable soft robots while also effectively reducing e-waste and robotics waste materials,which is important for resource conservation and environmental protection.

摘要：镁离子电池因其高理论容量和丰富的自然资源被认为是下一代储能系统的潜在候选者.然而,镁离子电池的发展受到镁负极与常见的镁盐和传统有机液体电解液溶剂不相容的限制.因此,电解液的发展是开发高效镁离子电池的决定性因素.镁离子电池的进一步应用所面临的一个主要挑战是开发具有适当的电化学窗口、与镁负极兼容、安全性高的电解液.当前,用于镁离子电池的主要电解液类型包括有机液体电解液、水系电解液、离子液体电解液和固态电解质.本文强调了每个类别中高性能镁离子电池电解液的最新进展,对先进电解液的设计策略进行了系统评估,分析了每种电解液的优点和局限性以及对现有问题的解决方案,并从电解液合成的角度讨论了镁离子电池的发展;最后,讨论并设想了镁离子电池电解液的未来设计,这将对进一步提高镁离子电池的性能提供支持.

摘要：Sodium metal anode holds great promise in pursuing high-energy and sustainable rechargeable batteries,but severely suffers from fatal dendrite growth accompanied with huge volume ***,a robust mixed conducting sodium metal anode is designed through incorporating Na SICON-type solid Na-ion conductor into bulk Na.A fast and continuous pathway for simultaneous transportation of electrons and Na+is established throughout the composite *** intimate contact between Na-ion conducting phase and Na metallic phase constructs abundant two-phase boundaries for fast redox ***,the compact configuration of the composite anode substantially protects Na metal from being corroded by liquid organic electrolyte for the minimization of side *** from the unique configuration,the composite anode shows highly reversible and durable Na plating/stripping *** symmetric cells exhibit ultralong lifespan for over 700 h at 1 mA cm^(-2)with a high capacity of 5 m Ah cm^(-2)and outstanding rate capability up to 8 m A cm^(-2)in the carbonate *** cells with Na_(3)V_(2)(PO_(4))_(3)/C cathode demonstrate impressive cycling stability(capacity decay of 0.012%per cycle)and low charge/discharge polarization as *** work provides new insights into rational design and development of robust sodium metal anode through an architecture engineering strategy for advanced rechargeable sodium batteries.

摘要：The new properties of engineered nanoparti- cles drive the need for new knowledge on the safety, fate, behavior and biologic effects of these particles on organisms and ecosystems. Titanium dioxide nanoparticles have been used extensively for a wide range of applica- tions, e.g, self-cleaning surface coatings, solar cells, water treatment agents, topical sunscreens. Within this scenario increased environmental exposure can be expected but data on the ecotoxicological evaluation ofnanoparticles are still scarce. The main purpose of this work was the evaluation of effects of TiO2 nanoparticles in several organisms, covering different trophic levels, using a battery of aquatic assays. Using fish as a vertebrate model organism tissue histological and ultrastructural observations and the stress enzyme activity were also studied. TiO2 nanoparticles （Aeroxide~ P25）, two phase composition ofanatase （65%） and rutile （35%） with an average particle size value of 27.64-11 nm were used. Results on the ECs0 for the tested aquatic organisms showed toxicity for the bacteria, the algae and the crustacean, being the algae the most sensitive tested organism. The aquatic plant Lemna minor showed no effect on growth. The fish Carassius auratus showed no effect on a 21 day survival test, though at a biochemical level the cytosolic Glutathione-S-Transferase total activity, in intestines, showed a general significant decrease （p〈0.05） after 14 days of exposure for all tested concentrations. The presence of TiO2 nanoparticles aggregates were observed in the intestine lumen but their internalization by intestine cells could not be confirmed.

摘要：Reversible logic has recently gained significant interest due to its inherent ability to reduce energy dissipation,which is the primary need for low-power digital *** of the newest areas of relevant study is reversible logic,which has applications in many areas,including nanotechnology,DNA computing,quantum computing,fault tolerance,and low-power complementary metal-oxide-semiconductor(CMOS).An electrical circuit is classified as reversible if it has an equal number of inputs and outputs,and a one-to-one relationship.A reversible circuit is conservative if the EXOR of the inputs and the EXOR of the outputs are *** addition,quantum-dot cellular automata(QCA)is one of the state-of-the-art approaches that can be used as an alternative to traditional ***,we propose an efficient conservative gate with low power demand and high speed in this ***,we present a reversible gate called ANG(Ahmadpour Navimipour Gate).Then,two non-resistant QCA ANG and reversible fault-tolerant ANG structures are implemented in QCA *** suggested reversible gate is realized through the Miller ***,reversible fault-tolerant ANG is implemented by the 2DW clocking ***,the power consumption of the suggested ANG is assessed under different energy ranges(0.5Ek,1.0Ek,and 1.5Ek).Simulations of the structures and analysis of their power consumption are performed using QCADesigner 2.0.03 and QCAPro *** proposed gate shows great improvements compared to recent designs.