摘要：Two non-ionic hydro-fluorocarbon hybrid surfactants with and without hydroxyl groups were synthesized and *** exhibited good thermal stability and superior surface *** was observed that the hydroxyl group had a profound effect on modifying the surface tension of their solutions and the morphology of the formed *** effect may be attributed to the rearranging of the alkane group from above the air/aqueous surface to below it and the disrupting of the interfacial water structure induced by the hydroxyl *** work provides a strategy to weaken the immiscibility between hydrocarbon and fluorocarbon chains by modifying their orientational structure at the interface,thus it is helpful for the design of surfactants with varied interfacial properties.