摘要：Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology regulation, and heterojunction construction strategies to synthesize N-GQD/N-doped TiO_(2)/P-doped porous hollow g-C_(3)N_(4) nanotube (PCN) composite photocatalysts (denoted as G-TPCN). The optimal sample (G-TPCN doped with 0.1wt% N-GQD, denoted as 0.1% G-TPCN) exhibits significantly enhanced photoabsorption, which is attributed to the change in bandgap caused by elemental doping (P and N), the improved light-harvesting resulting from the tube structure, and the upconversion effect of N-GQDs. In addition, the internal charge separation and transfer capability of0.1% G-TPCN are dramatically boosted, and its carrier concentration is 3.7, 2.3, and 1.9 times that of N-TiO_(2), PCN, and N-TiO_(2)/PCN(TPCN-1), respectively. This phenomenon is attributed to the formation of Z-scheme heterojunction between N-TiO_(2) and PCNs, the excellent electron conduction ability of N-GQDs, and the short transfer distance caused by the porous nanotube structure. Compared with those of N-TiO_(2), PCNs, and TPCN-1, the H2 production activity of 0.1%G-TPCN under visible light is enhanced by 12.4, 2.3, and 1.4times, respectively, and its ciprofloxacin (CIP) degradation rate is increased by 7.9, 5.7, and 2.9 times, respectively. The optimized performance benefits from excellent photoresponsiveness and improved carrier separation and migration efficiencies. Finally, the photocatalytic mechanism of 0.1% G-TPCN and five possible degradation pathways of CIP are proposed. This study clarifies the mechanism of multiple modification strategies to synergistically improve the photocatalytic performance of 0.1% G-TPCN and provides a potential strategy for rationally designing novel photocatalysts for environmental remediation and solar energy conversion.

摘要：具有生物力学和生化活性的敷料在伤口护理和皮肤组织再生中起着至关重要的作用.然而,机械失配和药物释放管理所涉及的问题限制了当前敷料的有效使用.在本工作中,我们报道了一种简单的策略,即采用聚偏二氟乙烯(PVDF)作为底物,通过嵌入不同尺寸的沸石咪唑酸盐框架(ZIF-8)种子,以推动具有均匀蜂窝结构的高柔性金属有机框架(MOF)复合膜的受控生长,用于药物负载和释放.以嵌入的种子为控制中心,形成的多孔膜具有约0.7-3μm的宽孔隙.这种可调节的微尺度孔与ZIF-8中的固有纳米孔不仅可以有效地提高抗炎类药物的负载(姜黄素,CCM),而且还能够快速并可控地释放药物,大大提高了抗菌活性,同时促进细胞生长.其中,在40 nm种子上生长的0.7μm多孔膜的表现优于其他蜂窝膜,与2μm多孔膜(相当于裸PVDF基质)相比,细胞增殖能力提高了约2倍,针对金黄色葡萄球菌(***)和大肠杆菌(***)的抗菌活性分别提高了5倍和2.4倍,是基底抗菌活性的5倍,这是因为这种最佳孔几何结构具有CCM和Zn2+释放特性的平衡效应.这种可控分层孔阵列膜的独特性质有望真正用于伤口愈合,同时也为生物医学设计提供了新的指导.

摘要：聚合物基固态电解质得益于其易加工性,最有希望应用于下一代固态锂金属电池.目前,聚合物基态电解质的离子电导率提升策略多为加入导锂陶瓷以构建离子传输通道,其提升程度有限.电场在锂离子输运过程中存在重要影响,目前研究中有关电场对锂离子传输的影响机制尚不明确.本文将兼具高离子电导率和高介电常数的铌酸锂嵌入聚偏氟乙烯基体中,设计了一种新型复合固态电解质.铌酸锂颗粒有效调节电解质内部电场结构,增强了离子输运方向电场强度,实现了离子电导率的大幅提升(7.39×10^(-4)S cm^(-1),25℃).该电解质匹配高镍正极和锂金属负极的固态电池可稳定循环1000次以上,容量保持率为72%.该研究为设计下一代固态锂电池用高离子电导复合固态电解质提供了新的策略.

摘要：This paper proposes an operator based fault detection method for an actuator fault of an aluminum plate thermal process with input constraints. Operator-based robust right coprime factorization(RCF)approach is utilized in this method. After developing a mathematical model of the thermal process,a robust tracking operator system is designed for the process with input constraints. Following this, design of the fault detection system is given by using operator-based robust RCF approach. Finally, experiment is conducted to support the proposed design method

摘要：Development of effective chromatographic or electrophoretic separation involves judicious deciding of selection of optimal experimental conditions that can provide an adequate resolution at a reasonable run time for the separation of interested components. Box-Behnken factorial design was effectively applied for the separation optimization of eight structurally related sulfonamides using capillary zone electrophorosis and reverse high performance liquid chromatography. Optimum values for volume ratio of THF to H2O in eluent, column temperature and flow rate of eluent are found as 12 to 88, 35℃ and 1.0 mL/min, respectively. Box-Behnken modified optimization model is extended to separation by capillary electrophoresis (CE). While using CE, a satisfactory separation is achieved with a minimum resolution larger than 1.0 for a separation time less than 10 min.

摘要：We design a novel X-ray image detector by lens coupling a Gd2O2S：Tb intensifying screen with a high performance low-light-level （L^3, which often means luminescence less than 10^-3 Lux） image intensifier. Different coupling effects on imaging performance between zoom lens and fix-focus lens are analyzed theoretically. In experiment, for designing a detector of 15-inch visual field, the system coupled by zoom lens is of 12.25-lp/cm resolution, while the one with fix-focus lens is 10 lp/cm. The superiority of zoom lens is validated. It is concluded that zoom lens preserves the image information better than fix-focus lens and improves the imaging system＇s performance in this design, which is referential to the design of other optical imaging systems.

摘要：在这篇论文，我们处理追踪发生在活动收音机通讯的线性回归隧道模型的顺利变化时间的参数的问题。在考虑下面的系统与含糊的统计特征与围住的协变性和噪音受到变化时间的系数不确定性。追踪的问题的目的是发现过滤器参数以便追踪的表演，定义为追踪的错误的最少的吝啬的平方，被优化。处理问题的关键是追踪的问题被转变成过滤的并且用一个设计公式。一条多项式途径基于答案因为追踪的愿望被开发。柔韧的过滤器设计在这建议纸可以比没有随机的系数不确定性，为系统设计的标准最佳的过滤器有稍微更高计算的复杂性。然而，追踪的表演被改进。

摘要：Mini turbo-pumps having a diameter smaller than 100mm are employed in many fields;automobile radiator pump,ventricular assist pump,cooling pump for electric devices,washing machine pump and so ***,the needs for mini turbo-pumps would become larger with the increase of the application of it for electrical *** is desirable that the mini turbo-pump design is as simple as possible due to restriction to make precise *** the design method for the mini turbo-pump is not established because the internal flow condition for these small-sized fluid machineries is not clarified and conventional theory is not conductive for small-sized *** types of rotors with different outlet angles are prepared for an experiment and a numerical *** performance tests are conducted with these rotors in order to investigate the effect of the blade outlet angle on performance and internal flow condition of mini *** is clarified from the experimental results that head of the mini turbo-pump increases and maximum efficiency flow rate shifts to larger flow rate according to the increase of the blade outlet angle,however the maximum efficiency decreases with the increase of *** the present paper,the performance of the mini turbo-pump is shown and the internal flow conditions are clarified with the results of the experiment and the numerical flow ***,the effects of the blade outlet angle on the performance are investigated and high performance design with simple structure for the mini turbo-pump would be considered.

摘要：含钠层状氧化物比容量高、结构多样、组分可调、制备简单,是极具前景的钠离子电池正极材料之一.其中,P2型和O3型层状氧化物因结构的差异表现出了不同的性能特点,制备P2/O3复合相材料可在一定程度上耦合二者的优势.然而,这种复合相材料的形成机制尚不明确,材料设计缺乏指导依据.对此,本文基于阳离子势观点系统研究了P2/O3复合相的形成机制,证明了P2/03双相结构本质上源于反应热力学/动力学因素导致的元素分布不均匀性及其引起的局部阳离子势差异,进一步提出了具有普适性的“临界阳离子势+调控组分熵”材料设计原则,并阐释了以P2/O3相竞争反应为主的复合相“协同效应”,为钠离子电池新型氧化物正极材料的设计开发提供了理论依据.

摘要：The high-current superconducting proton linac is being studied for the accelerator-driven system （ADS） project undertaken by the Chinese Academy of sciences. The injector II will be operated at 162.5 MHz, and the proton out from the RFQ with an energy of 2.5 MeV will .be accelerated to 10 MeV by two cryo-modules, which are composed of eight superconducting half wave resonance cavities and nine solenoids. In this paper, the design and beam simulation of the superconducting section of the injector Ⅱ, the acceptance calculation and a stability analysis are presented.