摘要：Anchoring molecular cocatalysts on semiconductors has been recognized as a general strategy to boost the charge separation efficiency required for efficient ***,the effect of molecular cocatalysts on energy funneling(i.e.,directional energy transfer)inside semiconductor photocatalysts has not been demonstrated *** we prepared CdS nanorods with both thin and thick rods and anchored the conjugated molecules 2‐mercaptobenzimidazole(MBI)and cobalt molecular catalysts(MCoA)sequentially onto the surface of *** absorption measurements revealed that MBI molecules facilitated energy funneling from thin to thick rods by the electronic coupling between thin and thick nanorods,which is essentially a light‐harvesting antenna approach to enhance the charge generation efficiency in the reaction center(here the thick rods).Moreover,MBI and MCoA molecules selectively extracted photogenerated holes and electrons of CdS nanorods rapidly,leading to efficient charge ***,CdS/MBI/MCoA displayed 15 times enhanced photocatalytic H_(2) evolution(1.65 mL)than pure CdS(0.11 mL)over 3 h of *** amount of H_(2) evolution reached 60 mL over 48 h of illumination with a high turnover number of 26294 and an apparent quantum efficiency of 71%at 420 *** study demonstrates a novel design principle for next‐generation photocatalysts.

摘要：The selective catalytic hydrogenation of carboxylic acids is an important process for alcohol production,while efficient heterogeneous catalyst systems are still being ***,we report the selective hydrogenation of carboxylic acids using earth‐abundant cobalt oxides through a reaction‐controlled catalysis *** further reaction of the alcohols is completely hindered by the presence of carboxylic acids in the reaction *** partial reduction of cobalt oxides by hydrogen at designated temperatures can dramatically enhance the catalytic activity of pristine samples.A wide range of carboxylic acids with a variety of functional groups can be converted to the corresponding alcohols at a yield level applicable to large‐scale *** monoxide was established as the preferred active phase for the selective hydrogenation of carboxylic acids.

摘要：In solid basic catalysis field,how to achieve optimized activity and desired stability through elaborate control over basic site properties remains a *** this work,taking advantage of the structure memory effect of layered double hydroxides(LDHs),rehydrated Ca4 Al1-x Gax-LDHs and Ca4 Al1-x Inx-LDHs catalysts were prepared and applied in aldol condensation reaction that isobutyraldehyde(IBD)reacts with formaldehyde(FA)to obtain hydroxypivalaldehyde(HPA).Notably,the resulting re-Ca4 Al0.90Ga0.10-LDHs exhibits an extraordinarily-high catalytic activity(HPA yield:72%),which is to our best knowledge the highest level in this *** weak Br?nsted basic site,7-coordinated Ca-OH group,which serves as an active site,catalyzes the condensation process and promotes the product *** on structure-property correlations demonstrate that Ga as a structural promoter induces a moderate expansion of the laminate lattice,which results in a significant increase in the concentration of weak basic sites in re-Ca4Al0.90Ga0.10-LDHs,accounting for its high catalytic *** work illuminates that geometric structure of basic active sites can be tuned via introducing catalyst additive,which leads to a largely improved performance of hydrotalcite solid basic catalysts towards aldol condensation reaction.

摘要：Semiconductor photocatalysts are extensively applied in environmental treatment and energy ***,one of their major disadvantages is their relatively low photocatalytic performance owing to the recombination of generated electron-hole *** presence of the phase junction is an effective way to promote the photocatalytic activity by increasing the separation efficiency of the electron-hole ***,extensive research has been conducted on the design of phase junctions of photocatalysts to improve their charge transfer properties and ***,for the design of an appropriate phase junction and the understanding of the mechanism of electron-hole separation,the development of the photocatalytic phase junction,including the preparation methods of the heterogeneous materials,is tremendously important and ***,the commonly used,externally induced phase transformation fabrication techniques and the primary components of the semiconductors are *** directions will still focus on the design and optimization of the phase junction of photocatalytic materials according to the phase transition with higher efficiencies for broadband responses and solar energy ***,the most popular phase transformation fabrication techniques of phase junctions are briefly reviewed from the application viewpoint.

摘要：The hydrogenation of CO_(2) into methanol has attracted much attention and In_(2)O_(3) is a promising *** metal elements into In_(2)O_(3)(M/In_(2)O_(3))is one of the main strategies to improve its ***,its mechanism and active sites remain unclear and need to be further ***,the noble‐metal‐free In_(x)‐Co_(y) oxides catalysts were ***‐improved performance and obvious product selectivity shift were *** optimized catalyst(In_(1)‐Co_(4))(9.7 mmol g_(cat)^(–1) h^(–1))showed five times methanol yields than pure In_(2)O_(3)(2.2 mmol g_(cat)^(–1) h^(–1))(P=4.0 MPa,T=300°C,GHSV=24000 cm^(3)_(STP) g_(cat)^(–1) h^(–1),H_(2):CO_(2)=3).And the cobalt‐catalyzed CO_(2) methanation activity was suppressed,although cobalt was most of the metal *** unravel this selectivity shift,detailed catalysts performance evaluation,together with several in‐situ and ex‐situ characterizations,were employed on cobalt and In‐Co for comparative *** results indicated CO_(2) hydrogenation on cobalt and In‐Co catalyst both followed the formate pathway,and In‐Co reconstructed and generated a surface In_(2)O_(3)‐enriched core‐shell‐like structure under a reductive *** enriched In_(2)O_(3) at the surface significantly enhanced CO_(2) adsorption capacity and well stabilized the intermediates of CO_(2) ***_(2) and carbon‐containing intermediates adsorbed much stronger on In‐Co than cobalt led to a feasible surface C/H ratio,thus allowing the*CH_(3)O to desorb to produce CH_(3)OH instead of being over‐hydrogenated to CH_(4).

摘要：Rechargeable Li-O2 batteries have attracted considerable interests because of their exceptional energy density. However, the short lifetime still remained as one of the bottle-neck obstacles for the practical application of rechargeable Li-O2 batteries. The development of efficient cathode catalyst is highly desirable to reduce the energy barrier of Li-O2 reaction and electrode failure. In this work, we report a facile strategy for the fabrication of a high-per- formance cathode catalyst for rechargeable Li-O2 batteries by the encapsulation of high content of active Fe nanorods into N-doped carbon nanotubes with high stability （denoted as Fe@NCNTs）. First-principles calculations reveal that the synergistic charge transfer and redistribution between the interface of Fe nanorods, the CNT walls and the active N dopants greatly facilitate the chemisorption and subsequent dissociation of O2 molecules into the epoxy intermediates on the carbon surface, which benefits the uniform growth of nanosized discharge products on CNT surface and thus boosts the reversibility of Li-O2 reactions. As a result, the cathode with Fe@NCNT catalyst exhibRs long cycling sta- bility with high capacities （1000 mA h g-1 for 160 cycles and 600 mA h g-t for 270 cycles）. Based on the total mass of Fe@NCNTs ＋ Li2O2, high gravimetric energy densities of 2120-2600 W h kg-~ can be achieved at the power densities of 50-795 W kg-1.

摘要：A novel tobacco-curing system with a solar-assisted heat pump was *** proposed system has various advantages,such as reducing energy consumption and pollutant emissions and enhancing the stability of system *** thermal characteristics of the system under different climate conditions were analyzed,and the economic and environmental benefits of different tobacco-curing technologies were *** indicated that the dehydration rate,the mass flux of exhaust air,and the heat load of the novel tobacco-curing system in different months had similar changes with the baking time,and all reached the maximum in the later stage of color *** with the power saving rate of a heat pump tobacco-curing system,that of the novel system reached 25.9%-35.1%.The dry leaf curing cost of the novel system was only 0.86-1.06 yuan/kg,which can reduce the cost by more than 60%compared with traditional coal-burning tobacco-curing systems in *** with other parts of the tobacco leaf,the top leaf had the lowest dry leaf curing cost due to its highest mass of dry *** payback period and the annual CO_(2) emission reduction of the novel system were 3.0-3.7 a and 15586 kg,respectively.

摘要：钾离子电池(PIBs)面临的一个关键问题是设计具有先进结构的负极材料,以实现快速电荷传输以提高钾的存储性能.采用碳二亚胺铁(FeNCN)作为阳极,由于其含有一定数量的共价键且在分子水平上具有稳定的结构,使得储钾系统能够实现优异的电化学性能.FeNCN阳极具有高导电性,带隙接近0 eV,并且由于其共价键结构具有良好的结构稳定性.此外,无定形反应产物也为离子扩散提供了多种途径.因此,FeNCN阳极表现出高可逆比容量(在50 mA g^(-1)电流密度下具有600 mA h g^(-1)比容量),显著的倍率性能和长寿命循环(电流密度为500 mA g^(-1)时拥有400 mA h g^(-1)比容量且超过300次循环).通过理论模拟、X射线原位衍射分析和X射线光电子能谱分析揭示了Fe^(2+)和K^(+)之间的转化反应机理.此外,将FeNCN负极与苝-3,4,9,10-四羧酸二酐正极材料匹配,组装成的全电池在198.6 Wkg^(-1)的功率密度下实现了184.7 W h kg^(-1)的超高能量密度,明显高于以往所有铁基负极的PIBs或钾离子混合电容器.

摘要：The design of a lead slowing down spectrometer is being developed at KAERI （Korea Atomic energy research institute） for an analysis of isotopic fissile content in spent and recycled fuel. The lead spectrometer has an advantage to assay fissile content directly from spent fuel. Accurate fissile material data must be fed back to the spent fuel design and management. For reutilization of PWR spent fuel, an isotopic fissile content analysis is required to obtain safety and economics in the fuel cycle. The LSDS （lead slowing down spectrometer） uses the different fission signatures of each fissile with respect to the interrogation neutron energy. Several simulations were done and parameter was obtained for the system working. energy between 1 keV to 0.1 eV is very sensitive to isotopic fissile material fission with good energy resolution. An external source neutron is necessary to induce enough fissile fission. A neutron production methodology is being developed for cost effectiveness, easy maintenance and high neutron yield rate. The threshold fission detector screens the prompt fast fission neutrons from an intense radiation background. The detection of a fission signature has a direct relationship with the isotopic fissile content.

摘要：Metallic glasses(MGs)have attracted great attention in wastewater treatment because of their high reactivity arising from amorphous structure,large residual stress and high density of low coordination ***,the reactivity of MGs would gradually slow down with time due to the passivation of active sites by corrosion products,resulting in limited long-term reactivity,which is also an unsolved key issue for established crystalline zero valent iron(ZVI)***,such problems are successfully overcome by introducing nanoscale chemical inhomogeneities in Fe-based MG(Fe-MGI),which apparently contributes to local galvanic cell effect and accelerates electron transfer during degradation *** importantly,the selective depletion of Fe0 causes local volume shrinkage and crack formation,leading to self-peeling of precipitated corrosion products and reacted *** fresh low coordination sites could be continuously provided,counteracting the mass transport and reactivity deteriorating ***,Fe-MGI demonstrates excellent long-term reactivity and self-refreshing properties even in neutral *** present results provide not only a new candidate but also a new route of designing ZVI materials for wastewater treatment.