摘要：This vertically self‐pillared(VSP)structure extends the application range of traditional porous materials with facile mass/ion transport and enhanced reaction ***,we prepare a single crystal metal‐organic framework(MOF),employing the ZIF‐67 structure as a proof of concept,which is constructed by vertically self‐pillared nanosheets(VSP‐MOF).We further converted VSP‐MOF into VSP‐cobalt sulfide(VSP‐CoS2)through a sulfidation *** plays an important role in almost all battery technologies;for metallic batteries,lithium anodes exhibit a high theoretical specific capacity,low density,and low redox ***,during the half‐cell reaction(Li++e=Li),uncontrolled dendritic Li penetrates the separator and solid electrolyte interphase *** employed as a composite scaffold for lithium metal deposition,there are many advantage to using this framework:1)the VSP‐CoS2 substrate provides a high specific surface area to dissipate the ion flux and mass transfer and acts as a pre‐catalyst,2)the catalytic Co center favors the charge transfer process and preferentially binds the Li+with the enhanced electrical fields,and 3)the VSP structure guides the metallic propagation along the nanosheet 2D orientation without the protrusive *** these features enable the VSP structure in metallic batteries with encouraging performances.

摘要：Anchoring molecular cocatalysts on semiconductors has been recognized as a general strategy to boost the charge separation efficiency required for efficient ***,the effect of molecular cocatalysts on energy funneling(i.e.,directional energy transfer)inside semiconductor photocatalysts has not been demonstrated *** we prepared CdS nanorods with both thin and thick rods and anchored the conjugated molecules 2‐mercaptobenzimidazole(MBI)and cobalt molecular catalysts(MCoA)sequentially onto the surface of *** absorption measurements revealed that MBI molecules facilitated energy funneling from thin to thick rods by the electronic coupling between thin and thick nanorods,which is essentially a light‐harvesting antenna approach to enhance the charge generation efficiency in the reaction center(here the thick rods).Moreover,MBI and MCoA molecules selectively extracted photogenerated holes and electrons of CdS nanorods rapidly,leading to efficient charge ***,CdS/MBI/MCoA displayed 15 times enhanced photocatalytic H_(2) evolution(1.65 mL)than pure CdS(0.11 mL)over 3 h of *** amount of H_(2) evolution reached 60 mL over 48 h of illumination with a high turnover number of 26294 and an apparent quantum efficiency of 71%at 420 *** study demonstrates a novel design principle for next‐generation photocatalysts.

摘要：Significant enhancement of energy density of electrical double layered capacitors is a major challenge for electrochemical capacitors to conquer the emerging field of large scale renewable energy *** enhancement of specific capacitance is an effective strategy to obtain higher energy *** of redox mediator in the electrolyte as pseudocapacitive sources could enhance the specific capacitance,but well-coupled electrode materials should be developed as ***,as a proof-of-concept experiment,N,O-codoped porous carbon nanosheets have been fabricated,wherein graphene oxide is employed as both oxygen source as well as structure directing ***,the obtained electrode materials endow electrical double layered capacitors with excellent capacitive performances,including the ultra-high specific capacitance(5073.5 F g^(-1))and excellent cycling stability,which could be attributed to the synergy of morphology and surface chemistry of N,O-codoped porous carbon *** results would form the basis for an unprecedented perspective in the development of next generation electrode materials for electrical double layered capacitors.

摘要：The design and synthesis of multifunctional nanocarriers for efficient synergistic cancer therapy have drawn great research interests in recent *** this work,a nanoplatform for chemo-photothermal therapy with targeting ligand was *** porous structured silica nanotubes(SNTs)with controllable lengths decorated with CuS nanoparticles(NPs)on the surface as photothermal agents were prepared and further conjugated with lactobionic acid groups as a cancer cell *** with average lengths of 40,55 and 150 nm were obtained and further functionalized as drug *** smallest bifunctional SNTs with targeting groups show good biocompatibility and highest cellular uptake for HepG2 *** release of doxorubicin hydrochloride(DOX)from the SNTs was dependent on the p H of the buffer solution and 808-nm near infrared(NIR)light *** integration of photothermal therapy(PTT)of CuS NPs and chemotherapy of anticancer drug leads to a better tumor inhibition effect than the individual therapy alone in vitro and in *** results demonstrate potential applications of the nanocomposites as vector for efficient chemo-photothermal therapy.

摘要：The poor oxygen evolution reaction(OER)activity of two-dimensional(2 D)transition metal carbides(MXenes)is a major obstacle to their application in highperformance water splitting and fuel cells due to the high energy barriers for the absorption of ***,we demonstrate that the lattice oxygen of M_(n)X_(n-1)O_(2)MXenes can be activated by 0 D graphene quantum dots(GQDs),thereby activating the OER via the lattice-oxygen oxidation mechanism(LOM)instead of the conventional adsorbate evolving *** pH-dependent OER activity of M_(n)X_(n-1)O_(2)@GQDs and ^(18)O isotope-labelling experiments with time-of-flight secondary-ion mass spectrometry(TOF-SIMS)provide the direct evidence of ***,the activated lattice oxygen amount can be controlled by the *** as-prepared 0 D/2 D Ti_(3)C_(2)O_(2)@GQDs heterostructure delivers a highly reduced overpotential of 390 mV(bare Ti_(3)C_(2)O_(2):530 mV)at a benchmark current density of 10 mA cm^(-2).Through optimizing the thickness and the additional conductive substrate,the overpotential at 10 mA cm^(-2)decreases to 250 mV,while the Tafel slope is reduced to 39 mV dec^(-1);these values indicate the as-prepared heterostructure is superior to the state-of-the-art MXene-based OER *** work provides a new strategy to enhance the OER activity of M_(n)X_(n-1)O_(2)and extends the application of LOM from perovskite to MXenes.

摘要：The one-pot assembly reaction of a trilacunary,lone-pair-containing[B-α-SbW9O33]*** with Co2+ions in an aqueous medium led to the isolation of a novel{SbO3(H2O)3}bridging,dicobalt-substituted,sandwich-type tungstoantimonate{Co2Sb2(H2O)10[B-β-SbW9O33]2}^4–(1a).This compound was structurally characterized in the solid state by single-crystal X-ray diffraction,elemental analyses,thermogravimetric analysis,and IR *** most remarkable feature was that 1a comprises two trilacunary[B-β-SbW9O33]9^-fragments trapping a novel,centrally symmetric,rhomb-like{Co2Sb2}belt with 10 terminal water *** combined with the photosensitizer[Ru(bpy)3]^2+and the sacrificial electron acceptor S2O82.,1a exhibited efficient catalytic activity for water oxidation with a remarkable turnover number(TON)of 193,initial turnover frequency(TOFinitial)of 5.3 s^-1,O2 yield of 30.8%,and quantum yield(ФQY)of 36.2%under light-driven conditions.

摘要：Photocatalysis activated by visible light remains highly ***,we report novel MoSe2/ZnO/ZnSe(ZM)hybrids fabricated via a simple hydrothermal method for photocatalytic reduction of Cr(VI)under visible light *** hybrids show improved photocatalytic reduction ability under visible light irradiation compared to pure ZnO owing to good visible light absorption and rapid electron transfer and *** ZM hybrid shows the highest Cr(VI)reduction rate of 100%.Moreover,the photocatalytic Cr(VI)reduction process is mainly controlled by photoinduced electrons.

摘要：Aqueous organic flow batteries have attracted dramatic attention for stationary energy storage due to their resource sustainability and low cost. However, the current reported systems can normally be operated stably under a nitrogen or argon atmosphere due to their poor stability. Herein a stable airinsensitive biphenol derivative cathode, 3,30,5,50-tetramethylaminemethylene-4,40-biphenol(TABP), with high solubility(>1.5 mol L^(-1)) and redox potential(0.91 V vs. SHE) is designed and synthesized by a scalable one-step method. Paring with silicotungstic acid(SWO), an SWO/TABP flow battery shows a stable performance of zero capacity decay over 900 cycles under the air atmosphere. Further, an SWO/TABP flow battery manifests a high rate performance with an energy efficiency of 85% at a current density of60 m A cm^(-2) and a very high volumetric capacity of more than 47 Ah L^(-1). This work provides a new and practical option for next-generation practical large-scale energy storage.

摘要：Theranostic nanoprobes can potentially integrate imaging and therapeutic capabilities into a single platform,offering a new personalized cancer diagnostic ***,there is a growing concern that their clinical application is not safe,particularly due to metal-containing elements,such as the gadolinium used in magnetic resonance imaging(MRI).We demonstrate for the first time that the photothermal melting of the DNA duplex helix was a reliable and versatile strategy that enables the on-demand degradation of the gadolinium-containing MRI reporter gene from polydopamine(PDA)-based theranostic *** combination of chemotherapy(doxorubicin)and photothermal therapy,which leads to the enhanced anti-tumor *** vivo MRI tracking reveals that renal filtration was able to rapidly clear the free gadolinium-containing MRI reporter from the mice *** results in a decrease in the long-term toxic effect of theranostic MRI *** findings may pave the way to address toxicity issues of the theranostic nanoprobes.

摘要：脊髓损伤(SCI)后如何对中枢神经进行保护性治疗是临床面临的巨大挑战.SCI发生后,在损伤部位会产生大量高毒性的活性醛分子.这类分子会扩大氧化应激范围,加重炎症反应,进而导致严重的继发性损伤.因此,高效清除活性醛分子有望成为治疗继发性脊髓损伤的新策略.本文设计制备了一种侧链上含有酰肼基团的聚多肽(PPAH)材料,它可以通过消除活性醛分子减轻继发性脊髓损伤.实验结果表明,PPAH在体外和体内都显示了清除活性醛的能力,并且能够有效保护神经细胞免受毒性醛分子(如丙烯醛)引起的氧化损伤.在大鼠SCI模型中,PPAH能够有效抑制炎症、保护神经元和抑制脱髓鞘,最终促进SCI大鼠的后肢运动功能恢复.综上,作为一种新型的活性醛分子消除材料,PPAH在治疗SCI方面显示出良好的应用前景.