摘要：We successfully designed and fabricated TES bolometers utilizing Al/Ti bilayer TESs as sensitive *** reduce the intrinsic noise level and tune the saturation power of a bolometer,the TES thermometer is placed on a suspended SiN platform which is thermally coupled to the heat bath by four long SiN beams with different *** measurement results show that the detectors have background limited noise performance,with a low noise equivalent power(NEP)on the order of10-17W/Hz1/2and have a saturation power of several tens pW at a bath temperature of 320 *** detectors are suitable for applications in ground-based astrophysics experiments by integrating absorbers for specific wavelengths.

摘要：由非平衡驱动的热传导通过物理接触传递内部的热能.描述热传导的数学方程是一个典型的偏微分方程.它广泛存在于各种工程问题中,例如粒子扩散、航天器设计和稀释制冷机运行.本文提出了一种显著优于经典算法的热传导量子算法,并在量子硬件上演示了热传导过程.作者通过一个辅助量子比特构造的对称系统来表示原始热传导系统,使得量子线路的复杂度减少到离散格点数量的对数多项式量级.与现有的基于Harrow-Hassidim-Lloyd的线性方程算法相比,本文的方法直接演化线性过程,不进行相位估计,避免相位估计涉及复杂的量子门操作和较大的输出误差,便于在目前的量子硬件实现,显示了该算法是实验友好特性.并且,作者在核自旋量子处理器上实现了两端恒温和绝热条件的一维热传导过程,温度的时空分布与理论预言很好的吻合.该算法可以自然地应用于可归约为热方程的物理过程.

摘要：quantum secure direct communication(QSDC)attracts much attention for it can transmit secret messages directly without sharing a *** this article,we propose a one-step QSDC protocol,which only requires to distribute polarization-spatial-mode hyperentanglement for one *** this QSDC protocol,the eavesdropper cannot obtain any message,so that this protocol is unconditionally secure in *** protocol is a two-way quantum communication and has high capacity for it can transmit two bits of secret messages with one pair of *** entanglement fidelities of both polarization and spatial-mode degrees of freedom being 0.98,the maximal communication distance of this onestep QSDC can reach about 216 *** can also be used to generate the *** this regard,the key generation rate is estimated about 2.5 times of that in the entanglement-based QKD with the communication distance of 150 *** the help of future quantum repeaters,this QSDC protocol can provide unconditionally secure communication over arbitrarily long distance.

摘要：电子结构和电导率是析氧反应活性的重要描述符,它们可以通过掺杂来调节.鉴于金属掺杂通常会减少电催化剂的活性位点数量,本工作探究了阴离子掺杂对尖晶石钴酸锌(ZCO)电子结构及其析氧活性的影响.与三价钴为主的ZCO相比,用电负性较低的硫取代氧会提高低自旋态(t_(2g)-^(6)e_(g)^(1))二价钴的占比,其析氧活性要高于低自旋态的三价钴(t_(2g)-^(6)e_(g)^(0)).掺硫钴酸锌(ZCO-S)中钴离子和阴离子之间的电子密度的再分布导致了二价钴的增多,而且钴和硫离子间的强共价作用也会加速电荷迁移.ZCO-S在1.65伏(相对于可逆氢电极)下的比活性比原始ZCO高11倍.相反,掺入具有较高电负性和价态的氟(F)并不能有效地改善电子结构,最终导致材料析氧活性的降低.本工作建立了所掺阴离子的电负性与钴酸锌本征析氧活性之间的联系,并提供了一种通过掺杂不同电负性的阴离子来调控尖晶石氧化物的电子结构的简单有效的方法,这为合理设计高性能尖晶石电催化剂提供了新途径.

摘要：The underlying spin-related mechanism remains unclear,and the rational manipulation of spin states is challenging due to various spin configurations under different coordination ***,it is urgent to study spin-dependent oxygen evolution reaction(OER)performance through a controllable ***,we adopt a topochemical reaction method to synthesize a series of selenides with eg occupancies ranging from 1.67 to *** process begins with monoclinic-CoSeO_(3),featuring a distinct laminar structure and Co-O6 *** topochemical reaction induces significant changes in the crystal field's intensity,leading to spin state *** transitions are driven by topological changes from a Co-O-Se-O-Co to a Co-Se-Co configuration,strengthening the crystalline field and reducing eg orbital *** reconfiguration of spin states shifts the rate-determining step from desorption to adsorption for both OER and the hydrogen evolution reaction(HER),reducing the potential-determined step barrier and enhancing overall catalytic *** a result,the synthesized cobalt selenide exhibits significantly enhanced adsorption *** material demonstrates impressive overpotentials of 35 mV for HER,250 mV for OER,and 270 mV for overall water splitting,indicating superior catalytic activity and ***,a negative relation between eg filling and OER catalytic performance confirms the spin-dependent nature of *** findings provide crucial insights into the role of spin state transitions in catalytic performance.

摘要：CO_(2) electrochemical reduction(CO_(2)ER)to high-value fuels and chemicals is a promising strategy for using CO_(2) as a carbon ***,the large-scale application of CO_(2)ER is limited by the lack of efficient and selective *** means of density functional theory(DFT)calculations,the potential of transitional metal-based covalent organic frameworks(TM-COFs,TM=Fe,Co,Ni,Cu,Zn,Ru,Rh,Pd,and Ag)as CO_(2) reduction electrocatalysts was systematically *** results show that the single TM atom can be firmly anchored on COFs for forming stable single-atom *** TM atom in phthalocyanine has excellent catalytic activity towards CO_(2)ER,while the pyridine N in pyrazine is the active site of the hydrogen evolution reaction(HER).Among studied candidates,Co-COF and Rh-COF are predicted to have limiting potential of-0.66/-0.11 and-0.49/-0.49 V for CO_(2)ER/HER,*** present study may provide a new strategy for designing novel bifunctional catalysts.

摘要：Recent advances in non-radiative wireless power transfer(WPT)technique essentially relying on magnetic resonance and near-field coupling have successfully enabled a wide range of ***,WPT systems based on double resonators are severely limited to short-or mid-range distance,due to the deteriorating efficiency and power with long transfer *** systems based on multi-relay resonators can overcome this problem,which,however,suffer from sensitivity to perturbations and fabrication ***,we experimentally demonstrate a concept of topological wireless power transfer(TWPT),where energy is transferred efficiently via the near-field coupling between two topological edge states localized at the ends of a one-dimensional radiowave topological *** a TWPT system can be modelled as a parity-time-symmetric Su-Schrieffer-Heeger(SSH)chain with complex boundary ***,the coil configurations are judiciously designed,which significantly suppress the unwanted cross-couplings between nonadjacent coils that could break the chiral symmetry of the SSH *** tuning the inter-and intra-cell coupling strengths,we theoretically and experimentally demonstrate high energy transfer efficiency near the exceptional point of the topological edge states,even in the presence of *** combination of topological metamaterials,non-Hermitian physics,and WPT techniques could promise a variety of robust,efficient WPT applications over long distances in electronics,transportation,and industry.

摘要：Spin engineering is recognized as a promising strategy that modulates the association between d‐orbital electrons and the oxygenated species,and enhances the catalytic ***,few efforts have been made to clarify whether spin engineering could make a considerable enhancement for electrocatalytic water ***,we report the spin engineering of a nanocage‐structured(Co,Ni)Se_(2)/C@FeOOH,that showed significant oxygen evolution reaction(OER)*** measurement presented that the(Co,Ni)Se_(2)/C@FeOOH sample possesses higher polarization spin number(μb=6.966μB/f.u.)compared with that of the(Co,Ni)Se_(2)/C sample(μb=6.398μB/f.u.),for which the enlarged spin polarization number favors the adsorption and desorption energy of the intermediate oxygenated species,as confirmed by surface valance band ***,the(Co,Ni)Se_(2)/C@FeOOH affords remarkable OER product with a low overpotential of 241 mV at a current of 10 mA cm^(-2) and small Tafel slope of 44 mV dec^(-1) in 1.0 mol/L KOH alkaline solution,significantly surpassing the parent(Co,Ni)Se_(2)/C *** work will trigger a solid step for the design of highly‐efficient OER electrocatalysts.