摘要：We proposed a new approach to construct zeolitic imidazolate frameworks-67 (ZIF-67) powders directly on carbon cloth without any conductive agent and adhesion agent and the ZIF-67 nanoparticles on carbon cloth were successfully converted into hollow Co3O4 nanostructure via a facile calcination process. Compared with original ZIF-67 powders, the Co3O4@CC electrode materials had admirable specific capacitance of 1164.8 F·g^-1 at an area current density of 2.5 mA·cm^-2. Furthermore, the rate performance remained 42.4% of initial value when the current density was increased to 30 mA·cm^-2 and the specific capacitance maintained 93.4% of initial capacity after 5000 cycles at an area current density of 10 mA·cm^-2. This strategy may have potential prospect for the application of MOFs in the energy storage and conversion field.

摘要：The nanoscale core/shell heterostructure is a particularly efficient motif to combine the promising properties of plasmonic materials and rare-earth compounds; however, there remain significant challenges in the synthetic control due to the large interfacial energy between these two intrinsically unmatched materials. Herein, we report a synthetic route to grow rare-earth-vanadate shells on gold nanorod （AuNR） cores. After modifying the AuNR surface with oleate through a surfactant exchange, well-packaged rare-earth oxide （e.g., Gd2O3：Eu） shells are grown on AuNRs as a result of the multiple roles of oleate. Furthermore, the composition of the shell has been altered from oxide to vanadate （GdVO4：Eu） using an anion exchange method. Owing to the carefully designed strategy, the AuNR cores maintain the morphology during the synthesis process; thus, the final Au/GdVO4： Eu core/shell NRs exhibit strong absorption bands and high photothermal efficiency. In addition, the Au/GdVO4：Eu NRs exhibit bright Eu^3＋ fluorescence with quantum yield as high as -17%; bright Sm^3＋ and Dy^3＋ fluorescence can also be obtained by changing the lanthanide doping in the oxide formation. Owing to the attractive integration of the plasmonic and fluorescence properties, such core/shell heterostructures will find particular applications in a wide array of areas, from biomedicine to energy.

摘要：Colloidal crystals are periodically ordered arrays of monodisperse colloidal particles which represent a new class of self-assembled materials showing potential applications in many ***-dimensional graphic nanostructures based on colloidal crystals have inherent periodicity from tens of nanometers to several micrometers,which gives them rich and interesting optical *** article presents a comprehensive review about the current research activities on the self-assembly of colloidal spheres which is an effective strategy for fabrication of various hierarchical and ordered nanostructures,with particular attention paid to the unique properties and applications of the colloidal crystal-based *** main aspects are elaborated:a)controllable self-assembly of colloidal crystals;b)the functions of the obtained colloidal spheres acting as the patterned mask for successive construction of numerous nanostructures;c)the novel properties and promising optical applications of the patterned nanostructures in various domains,such as plasmonic-related fields,antireflection,photonic crystals,photocatalysis and electronic *** that,the current challenges and future perspectives in this area are *** review aims to inspire more ingenious designs and exciting research for manufacturing nanostructures utilizing colloidal self-assembly.

摘要：万尼尔构型旨在描述万尼尔函数在实空间上的局域位置及其携带的电荷信息,这一物理概念的提出为刻画天然及人工晶体结构中的波函数提供了全新的视角.在二维高阶拓扑绝缘体中,万尼尔构型中的分数化电荷可以作为一种内禀的拓扑不变量来表征湮灭在体连续谱中的角模式.本文报告了一项基于测量谱电荷分布观测声学体系中万尼尔构型的实验研究.作者在构建的声子晶体中测得了表现为分数化谱电荷的拓扑角模式反常,这种模式反常可以作为一种易于观测的实空间拓扑指标对湮灭在体态中的拓扑角模式进行先验判别.在此基础上,通过将不同的万尼尔构型按照多种方式进行组合,将原本湮没在体连续谱中的角模式调制至带隙中.在组合后的声子晶体中,平庸相和非平庸相结构均可以作为包覆层,从而为在带隙中构造和调控拓扑角模式提供了一种新思路.该研究有望应用于设计高品质因子声谐振腔、声通信以及传感增强等领域.

摘要：With the ever-increasing demands of grid-scale energy storage,aqueous zinc-ion batteries(ZIBs)have garnered increasing attention around the ***,limited Zn^(2+)host materials have hindered the commercialization of ***,Mo-V oxides with different phase structures(orth-,tri-,and tetra-MoVO)were precisely constructed to develop phase-dependent Mo-V oxide cathodes for Zn^(2+)storage in *** open frameworks and varied tunnel structures formed a favorable alternative for achieving suitable Zn^(2+)diffusion *** optimized phase engineering,the high specific capacity of approximately 400 mA h g^(−1) and excellent cyclic stability of 1000 cycles were achieved with orth-MoVO as the *** large amount of six-and seven-member rings in the orth-MoVO phase,which allow for alternative Zn^(2+)insertion,play a vital role in hosting Zn^(2+)ions *** proposed phase engineering strategy provides a new approach toward cathode design in ZIBs.