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Design and concise synthesis of gem-difluoromethylenated analogue of 7-epi-castanospermine
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《Chinese Chemical Letters》2014年 第8期25卷 1115-1120页
作者:Xin-Yi Jiang Xiu-Hua Xu Feng-Ling QingKey Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Science College of Chemistry Chemical Engineering and Biotechnology Donghua University 
A novel gem-difluoromethylenated castanospermine analogue B was designed and synthesized, starting from 3-bromo-3,3-difluoropropene and L-(-)-malic acid. The key steps involve substitution cyclization reaction and R...
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