摘要：The unique photocatalytic mechanism of S-scheme heterojunction can be used to study new and efficient *** carefully selecting semiconductors for S-scheme heterojunction photo-catalysts,it is possible to reduce the rate of photogenerated carrier recombination and increase the conversion efficiency of light into *** are a group of compounds that include sulfides and selenides(e.g.,CdS,ZnS,Bi_(2)S_(3),MoS_(2),ZnSe,CdSe,and CuSe).Chalcogenides have at-tracted considerable attention as heterojunction photocatalysts owing to their narrow bandgap,wide light absorption range,and excellent photoreduction *** paper presents a thor-ough analysis of S-scheme heterojunction photocatalysts based on *** an introduction to the fundamental characteristics and benefits of S-scheme heterojunction photocata-lysts,various chalcogenide-based S-scheme heterojunction photocatalyst synthesis techniques are *** photocatalysts are used in numerous significant photocatalytic reactions,in-cluding the reduction of carbon dioxide,synthesis of hydrogen peroxide,conversion of organic matter,generation of hydrogen from water,nitrogen fixation,degradation of organic pollutants,and *** addition,cutting-edge characterization techniques,including in situ characterization techniques,are discussed to validate the steady and transient states of photocatalysts with an S-scheme ***,the design and challenges of chalcogenide-based S-scheme het-erojunction photocatalysts are explored and recommended in light of state-of-the-art research.

摘要：Achieving a strong redox ability and high visible-light absorption ability in a single semiconductor material is *** a heterojunction between two semiconductor materials is a feasible *** new step(S-scheme)heterojunction can effectively promote the separation and trans-fer of photogenerated electron-hole pairs and retain strong redox *** designed and pre-pared a Cd Se_(0.8)S_(0.2)-diethylenetriamine(DETA)/Sn Nb_(2)O_(6)heterostructure material via the sol-vothermal *** Cd Se_(0.8)S_(0.2)-DETA and Sn Nb_(2)O_(6)form an S-scheme heterojunction,30%Cd Se_(0.8)S_(0.2)-DETA/Sn Nb_(2)O_(6)exhibits the highest CO production rate(17.31μmol·g^(-1)·h^(-1)),which is factors of 2.8 and 4.8 higher than that of traditional solvothermal Sn Nb_(2)O_(6)(6.2μmol·g^(-1)·h^(-1))and Cd Se_(0.8)S_(0.2)-DETA(3.6μmol·g^(-1)·h^(-1)),respectively.X-ray photoelectron spectroscopy characterization data provided evidence that the transfer pathway of space charge in the CO_(2)reduction process was in accordance with the *** research provides a simple strategy through which one can optimize the band structure to promote the separation of photogenerated carriers and achieve a high efficiency of CO_(2)reduction.

摘要：Inorganic-organic hybrid materials are promising for application in the field of photocatalysis because of their excellent ***,their syntheses,mechanisms,and applications are reviewed in this ***,we introduce the role of inorganic-organic photocatalysts,their advantages and disadvantages,and their design ***,we present the top-down and bottom-up synthesis methods of the hybrid *** interaction between inorganic and organic components in hybrid materials is discussed,followed by how to improve inorganic-organic ***,the applications of hybrid materials in the field of photocatalysis,such as realizing hydrogen evolution,organic pollutant degradation,heavy metals and CO_(2) reduction,sterilization,and nitrogen fixation,are ***,the application prospects and development directions of inorganic-organic hybrid materials are explored and the unsolved problems are described.

摘要：Constructing step-scheme(S-scheme)heterojunctions can considerably facilitate separation and transfer of photocarriers,as well as promote strong redox *** interface resistance of heterojunctions immediately affects photocarrier separation and determines the photocatalytic ***,we constructed a novel Bi OBr/Ni_(2)P/g-C_(3)N_(4) heterojunction using Ni_(2)P as a novel electron bridge to reduce the interfacial resistance of photocarriers between Bi OBr and *** as-prepared 10% BiOBr/Ni2P/g-C_(3)N_(4) sample exhibited outstanding visible-light photocatalytic performance for methyl orange and rhodamine B removal,with degradation efficiencies of 91.4% and 98.9%,*** excellent photocatalytic activity of Bi OBr/Ni_(2)P/g-C_(3)N_(4) was mainly attributed to the synergistic effects of the Ni2P cocatalyst and S-scheme heterojunction,which not only reduced the interface resistance but also retained the strong redox potential of the *** addition,the formation of the S-scheme system was supported by active oxygen species investigation,current-voltage curves,and density functional theory *** work provides a guideline for the design of highly efficient S-scheme photocatalysts with transition metal phosphates as electron bridges to improve photocarriers separation.