摘要：Wireless millirobots engineered to infiltrate intricate vascular networks within living organisms,particularly within constricted and confined spaces,hold immense promise for the future of medical ***,with their multifaceted and intricate designs,some robots often grapple with motion and functionality issues when confronted with tight spaces characterized by small cross-sectional *** this study,drawing inspiration from the high aspect ratio and undulating swimming patterns of snakes,a millimeter-scale,snake-like robot was designed and fabricated via a combination of extrusion-based four-dimensional(4D)printing and magnetic-responsive intelligent functional inks.A sophisticated motion control strategy was also developed,which enables the robots to perform various dynamic movements,such as undulating swimming,precise turns,graceful circular motions,and coordinated cluster movements,under diverse magnetic field *** a potential application,the snake robot can navigate and release drugs in a model coronary intervention vessel with tortuous channels and fluid *** novel design and promising applications of this snake robot are invaluable tools in future medical surgeries and interventions.

摘要：Revealing the structure evolution of interfacial active species during a dynamic catalytic process is a challenging but pivotal issue for the rational design of high-performance ***,we successfully prepare sub-nanometric Pt clusters(~0.8 nm)encapsulated within the defects of CeO_(2)nanorods via an in-situ defect engineering *** as-prepared Pt@d-CeO_(2)catalyst significantly boosts the activity and stability in the water-gas shift(WGS)reaction compared to other *** on controlled experiments and complementary(in-situ)spectroscopic studies,a reversible encapsulation induced by active site transformation between the Pt^(2+)-terminal hydroxyl and Pt^(δ+)-O vacancy species at the interface is revealed,which enables to evoke the enhanced *** findings not only offer practical guidance for the design of high-efficiency catalysts but also bring a new understanding of the exceptional performance of WGS in a holistic view,which shows a great application potential in materials and catalysis.

摘要：Electromagnetic forming is one of the high-rate forming methods that can be extensively used to form and join axisymmetric metal sheet and tube. Tendency of homogeneous radial deformation during electromagnetic compression of aluminium tube was investigated through the design optimization method based on sequential coupling numerical simulation and experiments. The results show that the tendency depends on the length ratio of tube to coil (R), which has a critical value (Rc) corresponding to the relatively homogeneous radial deformation along axial direction. The tube length relative to Rc is insensitive to the discharge voltage. When R is greater than Rc, the deformed tube presents horn shape and the shorter coil makes for local deformation. If R is less than Rc, the deformed tube presents drum shape and the longer coil contributes to larger deformation at tube end. Rc increases with coli length and could approach to 1; inversely, it could approach to 0. These results indicate the design optimization method based on the sequential coupling numerical simulation is feasible, which can be used to realize the controllable and precise deformation of metal tube.

摘要：The systematical studies of Zr-based BMGs were summarized in terms of their compositional design and their structural characterization. In particular, several key issues of BMG materials were focused, including initial alloy design and subsequent composition optimization, solidification microstructure characterization and crystallization process specification. The results show that a compositional designing approach is successfully developed and, through extensive microstructure characterization using transmission electron microscopy, several new crystalline phases are discovered in these newly developed Zr-based BMG alloys. Crystallization behavior of Zr-based BMG is also determined based on the microstructure analysis.

摘要：The demand of high-end electromagnetic wave absorbing materials puts forward higher requirements on comprehensive performances of small thickness,lightweight,broadband,and strong ***,a novel multi-layer stepped metamaterial absorber with gradient electromagnetic properties is *** complex permittivity and permeability of each layer are tailored via the proportion of carbonyliron and carbon-fiber dispersing into the epoxy *** proposed metamaterial is further optimized via adjusting the electromagnetic parameters and geometric sizes of each *** with the four-layer composite with gradient electromagnetic properties which could only realize reflection loss(RL)of less than−6 dB in 2.0-40 GHz,the optimized stepped metamaterial with the same thickness and electromagnetic properties realizes less than−10 dB in the relevant frequency ***,the RL of less than−15 dB is achieved in the frequency range of 11.2-21.4 GHz and 28.5-40 *** multiple electromagnetic wave absorption mechanism is discussed based on the experimental and simulation results,which is believed to be attributed to the synergy effect induced by multi-scale structures of the ***,combining multi-layer structures and periodic stepped structures into a novel gradient absorbing metamaterial would give new insights into designing microwave absorption devices for broadband electromagnetic protections.

摘要：Three acceptor-donor-acceptor （A-D-A） small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d：2＇,3＇-d＇]benzo[1,2-b：4,5-b＇]dithiophene as the central building block, octyl cyanoacetate, 3-octylrhodanine and thiobarbituric acid as the end groups were designed and synthesized as donor materials in solution-processed photovoltaic cells （OPVs）. The impacts of these different electron withdrawing end groups on the photophysical properties, energy levels, charge carrier mobility, morphologies of blend films, and their photovoltaic properties have been systematically investigated. OPVs device based on DRDTBDT gave the best power conversion efficiency （PCE） of 8.34%, which was significantly higher than that based on DCAODTBDT （4.83%） or DTBDTBDT （3.39%）. These results indicate that rather dedicated and balanced consideration of absorption, energy levels, morphology, mobility, etc. for the design of small-molecule-based OPVs （SM-OPVs） and systematic investigations are highly needed to achieve high performance for SM-OPVs.

摘要：Manganese tetravalent oxide(MnO_(2)),a superstar Faradic electrode material,has been investigated extensively for capacitive desalination,enabling higher salt adsorption capacity compared to the great majority of carbonous ***,few works paid attention on the relationship between the valences of manganese oxide and their desalination *** the first time,we prepared the spindle-like manganese oxides/carbon composites with divalent(MnO@C),trivalent(Mn_(2)O_(3)@C)and divalent/trivalent(Mn_(3)O_(4)@C)manganese by pyrolysis of manganese carbonate precursor under different condition,*** electrochemical behavior in three-electrode system and electrosorption performance obtained in hybrid membrane capacitive deionization(HMCDI)cells assembled with capacitive carbon electrodes were systematically evaluated,*** salt adsorption capacity(as large as 31.3,22.2,and 18.9 mg·g^(−1))and corresponding average salt adsorption rates(0.83,0.53,and 1.71 mg·g^(−1)min−1)were achieved in 500 mg·L^(−1) NaCl solution for MnO@C,Mn_(2)O_(3)@C,and Mn_(3)O_(4)@C,*** fifteen electrosorption-desorption cycles,ex-situ water contact angle and morphology comparison analysis demonstrated the superior cycling durability of the manganese oxide electrodes and subtle difference between their surface ***,density functional theory(DFT)was also conducted to elaborate the disparity among the valence states of manganese(+2,+3 and +2/+3)for in-depth *** work introduced manganese oxide with various valences to blaze new trails for developing novel Faradic electrode materials with high-efficiency desalination performance by valence engineering.

摘要：Controllable self-assembly of noble metal nanocrystals is of broad interest for the development of highly active electrocatalysts. Here we report an efficient arginine-mediated hydrothermal approach for the high-yield synthesis of cube-like Pt nanoassemblies （Pt-CNAs） with porous cavities and rough surfaces based on the self-assembly of zero dimensional Pt nanocrystals. In this process, arginine acts as the reductant, structure directing agent, and linker between adjacent nanocrystals. Interestingly, the Pt-CNAs exhibit single-crystal structures with dominant {100} facets, as evidenced by X-ray diffraction. Based on electrocatalytic studies, the as-synthesized Pt-CNAs exhibit improved electrocatalytic activity as well as good stability and CO tolerance in the methanol oxidation reaction. The Pt-CNA＇s good performance is attributed to their unique morphology and surface structure. We believe that the synthetic strategy outlined here could be extended to other rationally designed monometallic or bimetallic nanoassemblies for use in high performance fuel cells.

摘要：Marine biofouling is a major issue deteriorating the service performance and lifespan of marine *** development of a durable,long-term,and environment-friendly antifouling coating is therefore of significant importance but still a critical challenge in maritime ***,we developed a Cu-Ti composite antifouling coating with micron-sized alternating laminated-structure of Cu/Ti by plasma spraying of mechanically mixed Cu/Ti *** coating was designed to enable controlled release of Cu ions through galvanic dissolution of Cu laminates from the Cu/Ti micro-galvanic cell in aqueous *** showed that remarkable antifouling efficiency against bacterial survival and adhesion up to~100%was achieved for the Cu-Ti ***/Ti micro-galvanic cell was in-situ formed within Cu-Ti coating and responsible for its Cu ions *** successive dissolution of Cu laminates resulted in the formation of micro-channels under Ti laminates near surface,which contributed to controlled slow Cu ions release and self-polishing ***,environment-friendly antifouling capability and∼200%longer antifouling lifetime than that of the conventional organic antifouling coatings can be achieved for the Cu-Ti *** the other hand,as compared to the conventional organic antifouling coatings,the Cu-Ti composite coating presented much higher mechanical durability due to its strong adhesion strength,excellent mechanical properties,and two orders lower wear *** present laminated Cu-Ti coating exhibits combination of outstanding antifouling performance and high mechanical durability,which makes this coating very potentially candidates in marine antifouling application.

摘要：As surgical procedures transition from conventional resection to advanced tissue-regeneration technologies,human disease therapy has witnessed a great leap *** particular,three-dimensional(3D)bioprinting stands as a landmark in this setting,by promising the precise integration of biomaterials,cells,and bioactive molecules,thus opening up a novel avenue for tissue/organ *** by the editorial board of Bio-Design and Manufacturing,this review brings together a cohort of leading young scientists in China to dissect the core functionalities and evolutionary trajectory of 3D bioprinting,by elucidating the intricate challenges encountered in the manufacturing of transplantable *** further delve into the translational pathway from scientific research to clinical application,emphasizing the imperativeness of establishing a regulatory framework and rigorously enforcing quality-control ***,this review outlines the strategic landscape and innovative achievements of China in this field and provides a comprehensive roadmap for researchers worldwide to propel this field collectively to even greater heights.