摘要：本文调查研究了制度对公司慈善与财务绩效的影响,通过对比中国与美国的案例,我们发现美国公司中的CP-CFP关系更明显。在两个样本研究中,不道德股票和广告强度对于CP-CFP关系的调节结果显示,涉众的感知度和信息的可利用度是支撑CP-CFP关系的关键机制,因此CP-CFP关系受制于制度差异。

摘要：The rational design and synthesis of hybrid-type electrode nanomaterials are significant for their diverse applications,including their potential usage as high-efficiency nanoarchitectures for supercapacitors(SCs)as a class of promising energy-storage systems for powering next-generation electric vehicles and electronic ***,we reported a facile and controllable synthesis of core-shell Ni_(3)S_(2)@NiWO_(4)nanoarrays to fabricate a freestanding electrode for hybrid ***,the as-prepared freestanding Ni_(3)S_(2)@NiWO_(4)electrode presents an ultrahigh areal capacity of 2032μA h cm^(-2)at 5 mA cm^(-2),and a capacity retention of 63.6%even when the current density increased up to 50 mA cm^(-2).Remarkably,the Ni_(3)S_(2)@NiWO_(4)nanoarraybased hybrid SC delivers a maximum energy density of 1.283 mW h cm^(-2)at 3.128 mW cm^(-2)and a maximum power density of 41.105 mW cm^(-2)at 0.753 mW h cm^(-2).Furthermore,the hybrid SC exhibits a capacity retention of 89.6%even after continuous 10,000 cycles,proving its superior *** study provides a facile pathway to rationally design a variety of core-shell metal nanostructures for high-performance energy storage devices.

摘要：All-solid-state lithium-ion batteries(LIBs)using ceramic electrolytes are considered the ideal form of rechargeable batteries due to their high energy density and ***,in the pursuit of all-solid-state LIBs,the issue of lithium resource availability is selectively *** that the amount of lithium required for all-solidstate LIBs is not sustainable with current lithium resources,another system that also offers the dual advantages of high energy density and safetydall-solid-state sodium-ion batteries(SIBs)dholds significant sustainable advantages and is likely to be the strong contender in the competition for developing next-generation high-energy-density *** article briefly introduces the research status of all-solid-state SIBs,explains the sources of their advantages,and discusses potential approaches to the development of solid sodium-ion conductors,aiming to spark the interest of researchers and attract more attention to the field of all-solid-state SIBs.

摘要：声束的连续动态扫描在超声成像、水下目标定位和声呐通信等诸多领域发挥关键作用.传统方法通常依赖于发射装置的机械扫描或有源相控阵的波束整形来实时调控声束的空间指向性,存在成本高、尺寸大、主动控制系统复杂而精准操控困难等问题.本文提出并构建了一种基于无源声学超表面的紧凑型静态声呐器件,无需主动控制和机械移动,仅在单一声源的作用下即可实现声束的动态扫描操控.这种新型声呐器件由具有深度亚波长厚度的二值化振幅编码单元组合而成,能够将单一声源发射的梳状频率谱转化为具有相同频率和空间间隔的声焦点阵列,从而引入频率梯度这一新的声波操控自由度,并通过时空声干涉效应产生可连续旋转的动态扫描声束.实验结果验证了所设计超构声呐的高速、宽角度声束扫描性能.此外,通过与传统的相位梯度调控技术结合,该机制还可以对扫描声束的空间形态进行任意的调节.这种基于静态无源超构声呐的声束动态扫描机制为声波的时空调控开辟了新的研究范式,并有望在水下对抗、超声诊疗等重要领域产生实际应用价值.

摘要：Two-dimensional （2D） materials have attracted growing attention since the discovery of graphene [1]. Transition metal dichalcogenide （TMD） semiconductors, such as MoS2 and WS2, became popular materials in recent years, because they usually have intrinsic bandgaps and an in- direct-to-direct bandgap transition from bulk to mono- layer limit [2-6]. Although graphene and TMDs are promising materials in field-effect devices [7-9], their heterostructures are more advanced in charge-splitting functions for the applications in optoelectronic devices [10-15].

摘要：Patterning ultrathin MoS2 layers with regular edges or controllable shapes is appealing since the properties of MoS2 sheets are sensitive to the edge structures. In this work, we have introduced a simple, effective and well-controlled technique to etch layered MoS2 sheets with well-oriented equilateral triangular pits by simply heating the samples in air. The anisotropic oxidative etching is greatly affected by the surrounding temperature and the number of MoS2 layers, whereby the pit sizes increase with the increase of surrounding temperature and the number of MoS2 layers. First-principles computations have been performed to explain the formation mechanism of the triangular pits. This technique offers an alternative avenue to engineering the structure of MoS2 sheets.

摘要：Designing highly selective and efficient singleatom electrocatalysts is essential for ammonia production under ambient conditions. This paper describes a density functional theory study on exploring the performance trends of transition metal complexes with P-based ligands in nitrogen reduction reaction(NRR) and further develops a design principle for high-performance single-atom catalysts(SACs)of NRR. Among the explored catalysts, W@BP(0.40 eV),Ta@BP(0.47 eV), and Nb@BP(0.53 eV) are identified as remarkable candidates with low free energy change in the potential-limiting step, high stability and high electrical conductivity for NRR. It is worth noting that almost all SACs with P-based ligands exhibit high NRR selectivity, due to the fact that they adsorb *N_(2) more strongly than *H. The adsorption free energy of *N_(2) H can be considered as a descriptor for the intrinsic activity trends in NRR. Furthermore, by constructing a volcano plot of the activity against the electronic charge on metal centers, it is demonstrated that the metal center with a moderate amount of positive charge can promote the catalytic performance of NRR.

摘要：Photonic synaptic transistors are promising neuromorphic computing systems that are expected to circumvent the intrinsic limitations of von Neumann-based *** design and construction of photonic synaptic transistors with a facile fabrication process and highefficiency information processing ability are highly desired,while it remains a tremendous ***,a new approach based on spin coating of a blend of CsPbBr_(3) perovskite quantum dot(QD)and PDVT-10 conjugated polymer is reported for the fabrication of photonic synaptic *** combination of flat surface,outstanding optical absorption,and remarkable charge transporting performance contributes to high-efficiency photon-to-electron conversion for such perovskite-based ***-performance photonic synaptic transistors are thus fabricated with essential synaptic functionalities,including excitatory postsynaptic current(EPSC),paired-pulse facilitation(PPF),and long-term *** utilizing the photonic potentiation and electrical depression features,perovskite-based photonic synaptic transistors are also explored for neuromorphic computing simulations,showing high pattern recognition accuracy of up to 89.98%,which is one of the best values reported so far for synaptic transistors used in pattern *** work provides an effective and convenient pathway for fabricating perovskite-based neuromorphic systems with high pattern recognition accuracy.

摘要：The phenomenon that different molecular packing modes in aggregates result in different optical properties has attracted intense attention,since it can provide useful information to establish the relationship between the micro-and *** this paper,DBTDO-DMAC was designed with 9,10-dihydro-9,9-dimethylacridine(DMAC)as electron ***-DPA and DBTDO-Cz were designed for comparison,which adopted diphenylamine(DPA)with twisted structure and carbazole(Cz)with planar structure as donors,*** expected,two polymorphs(Crystal G and Crystal Y)of DBTDO-DMAC were obtained and exhibited distinct *** G originating from planar conformation exhibited mechanochromism(MC)phenomenon and the emission color changed from green to yellow with a redshift of 35 nm after ***,Crystal Y with folded conformation displayed obvious room-temperature phosphorescence(RTP)with yellow *** single crystal analyses,powder X-ray diffraction and theoretical calculation reveal that the different emissive behaviors are highly related to the molecular conformation and packing *** successful adjustment of molecular conformation provides some guidance in the design of other MC and/or RTP luminogens,broadens the molecule family with the tunable molecular conformation and opens up a new avenue for exploring possible adjustment of molecular packing in aggregates.

摘要：Porous titanium(Ti)scaffolds have been extensively utilized as bone substitute scaffolds due to their superior biocompatibility and excellent mechanical ***,naturally formed TiO2 on the surface limits fast *** biomolecules have been widely utilized to overcome this issue;however,homogeneous porous Ti scaffolds could not simultaneously deliver multiple biomolecules that have different release *** this study,functionally graded porous Ti scaffolds(FGPTs)with dense inner and porous outer parts were fabricated using a two-body combination and densification *** with growth factor(BMP-2)and antibiotics(TCH)exhibited suitable mechanical properties as bone substituting material and presented good structural *** release of BMP-2 was considerably prolonged,whereas the release of TCH was comparable to that of homogenous porous titanium scaffolds(control group).The osteogenic differentiation obtained using FGPTs was maintained due to the prolonged release of *** antimicrobial properties of these scaffolds were verified using *** in terms of prior release *** addition,various candidates for graded porous Ti scaffolds with altered pore characteristics were presented.