摘要：Interfacial space charge storage between ionic and electronic conductor is a promising scheme to further improve energy and power density of alkali metal ion batteries(AMIBs).However,the general behavior of space charge storage in AMIBs has been less investigated experimentally,mostly due to the complicated electrochemical behavior and lack of proper characterization ***,we use operando magnetometry to verify that in FeSe_(2)AMIBs,abundant Li^(+)/Na^(+)/K^(+)(M^(+))can be stored at M_(2)Se phase while electrons accumulate at Fe nanoparticles,forming interfacial space charge *** and dynamics tests further demonstrate that with increasing ionic radius from Li^(+),Na^(+)to K^(+),the reaction kinetics can be hindered,resulting in limited Fe formation and reduced space charge storage *** work lays solid foundation for studying the complex interfacial effect in electrochemical processes and designing advanced energy storage devices with substantial capacity and considerable power density.

摘要：长寿命溶解氧海水电池是深远海观测能源网络的重要组成单元,但海水贫氧复杂环境对设计高性能氧还原催化剂提出了重要挑战.本文以酞菁铁为模型催化剂,通过理论计算与实验验证,提出了活性位点电子轴向拉伸可大幅提升催化剂在极端贫氧环境中的氧还原活性和稳定性.该研究为构建高性能海水电池提供了材料学解决方案,同时为极端环境下催化剂的变革性设计提供了新的思路.

摘要：Narrow spectral response,low charge separation efficiency and slow water oxidation kinetics of TiO_(2)limit its application in photoelectrochemical and photocatalytic water ***,a promising organic/inorganic composite catalyst Ag/PANI/3DOMM‐TiO_(2–x)with a three‐dimensional ordered macro‐and meso‐porous(3DO MM)structure,oxygen vacancy and Ti^(3+)defects,heterojunction formation and noble metal Ag was designed based on the Z‐scheme mechanism and successfully *** Ag/PANI/3DOMM‐TiO_(2–x)ternary catalyst exhibited enhanced hydrogen production activity in both photocatalytic and photoelectrochemical water *** photocatalytic hydrogen production rate is 420.90μmol g^(–1)h^(–1),which are 19.80 times and 2.06 times higher than the commercial P25 and 3DOMM‐TiO_(2),*** the photoelectrochemical tests,the Ag/PANI/3DOMM‐TiO_(2–x)photoelectrode shows enhanced separation and transfer of carriers with a high current density of 1.55 mA cm^(–2)at equilibrium potential of 1.23 V under simulated AM 1.5 G illumination,which is approximately 5 times greater than the 3DOMM‐TiO_(2).The present work has demonstrated the promising potential of organic/inorganic Z‐scheme photocatalyst in driving water splitting for hydrogen production.

摘要：本文特别针对24V电池输入条件下的低电压,大电流特性,设计了一种新颖的PWM软开关DC-DC前向式功率变换器模型。在局部运行区域,利用了ZCS PWM DC-DC前向式功率变换器的附加控制模式来实现软开关。这种新型功率变换器在低负载条件下可支持PWM-PDM双模控制一疗式,研究结果征实,在ZCS 和有功电压钳位开关条件下,基于PWM-PDM双模控制的软开关前向式功率变换器可在较大的负载范围内改善运行效率。

摘要：The datasets of the Chinese Academy of Sciences(CAS)Flexible Global ocean–Atmosphere–Land System(FGOALS-f3-L)model for the baseline experiment of the fully coupled runs in the Diagnostic,Evaluation and Characterization of Klima(DECK)common experiments of phase 6 of the Coupled Model Intercomparison Project(CMIP6)are described in this *** CAS FGOALS-f3-L model team submitted the pi Control run with a near equilibrium ocean state for 561 model years,and 160-year integrations for three ensemble members of abrupt-4×CO2 and 1pct CO2,*** ensemble members restart from the 600,650 and 700 model years in the pi Control run,*** baseline performances of the model are validated in this *** preliminary evaluation suggests that the CAS FGOALS-f3-L model can preserve the long-term stability well for a mean net radiation flux of 0.31 W m-2at the top of the atmosphere,and a limited decreasing trend of-0.03 W m-2/100 *** global annual mean SST is 16.45°C for the 561-year mean,with an increase of 0.03°C/100 *** model captures the basic spatial patterns of climate-mean SST and precipitation,but still underestimates the SST over the warm *** coupled model mitigates the precipitation bias in the ITCZ compared with the results from ***,the model’s climate sensitivity represented by the equilibrium climate sensitivity has been reduced from 4.5°C in CMIP5 to 3.0°C in *** these datasets contribute to the benchmark of model behaviors for the desired continuity of CMIP.