摘要：锌表面自然形成的非均匀氧化层(ZnO)会与电解液发生反应形成Zn_(4)(OH)_(6)SO_(4)·xH_(2)O(ZSH)副产物,导致锌负极表面非均匀沉积,从而阻碍水性锌离子电池实际应用.为了排除氧化层分布形式的影响,本文利用表面终止化学设计策略在锌负极表面制备了一层完全氧化的ZnO层,研究发现锌负极均匀分布的ZnO层会原位演化形成致密的ZSH功能层.均匀且致密的ZSH能够有效隔绝电解液的腐蚀,从而有效提高锌负极界面的稳定性.此外,ZSH(002)晶面边缘的不饱和悬空键(如-O)更容易和Zn(H_(2)O)_(6)^(2+)结构中的锌离子形成强Zn-O键,可以促进Zn(H_(2)O)_(6)^(2+)的脱溶剂化和锌离子沿边扩散,实现了高度可逆的锌沉积行为并限制了副反应.基于此,本文提出与“表面脱水-晶体通道转移”机制明显不同的“边缘脱水-沿边缘转移”锌离子输运新机制.更重要的是,基于此组装的全电池显示出高循环稳定性(超过1000次循环)和高库仑效率(99.07%),验证了其潜在的实际应用价值.

摘要：Multicellular microtissues of primary human hepatocytes(PHHs)co-cultured with other supporting cell types are a promis-ing model for drug screening and toxicological ***,these liver microtissues(LMs)rapidly lose their functions during ex vivo ***,in order to mimic the cellular and structural hepatic microenvironment,we co-cultured PHHs with human mesenchymal stromal cells(MSCs)and human umbilical vein endothelial cells(HUVECs)in the presence of cell-sized microparticles(MPs)derived from liver extracellular matrix(LEMPs).The microwell culture platform enabled biofabrication of size-controlled multicellular microtissues(PHH:HUVEC:MSC=3:2:1)with efficient LEMP incorporation(about 70%at a 2:1 ratio of cells:MP).The biofabricated liver microtissues(BLMs)were cultured ex vivo for 14 days and compared to the cell-only LM in terms of gene and protein expression,functional activity,cytochrome P450(CYP450)enzyme inducibility,and drug *** results supported superior hepatic-related gene expression,functional activity,and polarity for PHH in BLM compared to ***450 enzyme inducibility and dose-responsive sensitivity to toxic drugs were significantly higher in the BLM *** conclusion,microtissue engineering by incorporation of tissue-specific microparticles within a multicellular microtissue can offer some advantages for drug discovery studies and cell transplantation *** the near future,this approach could generate a scalable platform of several functional biofabricated microtissues representing different organs.

摘要：Variable stiffness composite laminates(VSCLs)are promising in aerospace engineering due to their designable material properties through changing fiber angles and stacking *** to control the thermal postbuckling and nonlinear panel flutter motions of VSCLs,a full-order numerical model is developed based on the linear quadratic regulator(LQR)algorithm in control theory,the classical laminate plate theory(CLPT)considering von Kármán geometrical nonlinearity,and the first-order Piston *** critical buckling temperature and the critical aerodynamic pressure of VSCLs are parametrically *** location and shape of piezoelectric actuators for optimal control of the dynamic responses of VSCLs are determined through comparing the norms of feedback control gain(NFCG).Numerical simulations show that the temperature field has a great effect on aeroelastic tailoring of VSCLs;the curvilinear fiber path of VSCLs can significantly affect the optimal location and shape of piezoelectric actuator for flutter suppression;the unstable panel flutter and the thermal postbuckling deflection can be suppressed effectively through optimal design of piezoelectric patches.

摘要：Alkali metal ions(M+ = Na+,Li+,K+) co-doped ZnAl2O4:Eu3+(5 mol%)(ZAE) nanopowders(NPs) were prepared via solution combustion route using Mimosa pudica(MP) leaves extract as a fuel. PXRD results of co-doped samples enhance the crystallinity and grain growth. Photoluminescence(PL) of the prepared ZAE and ZAE:M+(M+ = Na+, Li+, K+) NPs shows intense emission peaks in the range of 550-750 nm and ascribed to 5D0→7FJ(J=0-4) transitions of Eu3+ ions, respectively. A 2-fold enhancement in PL intensity was observed in Li+ co-doped samples. The optimized ZnAl2O4:Eu3+(5 mol%), Li+(1 wt%)(ZAEL)NPs were used to visualize LFPs on various porous, semi-porous and non-porous surfaces through robust powder dusting technique. The visualized latent fingerprints(LFPs) reveal well defined level 1-3 ridge characteristics under several tests such as fingerprint aging and fresh water treatment for various time durations. The obtained results clearly evidence that the prepared NPs are quite useful for multifunctional applications such as advanced forensic and solid state lightning.

摘要：分散在纳米碳基底上的分子催化剂由于具有明确的活性位点和结构可调的特点,成为了一类独特的单原子催化剂,有望代替贵金属催化剂用于电催化氧还原反应.本文中,我们开发了一种高活性氧还原催化剂,该催化剂由均匀且密集分散在泡芙状石墨烯载体上的铁酞菁(FePc/PG)构成.泡芙状石墨烯载体由于具有独特的皱褶和球状形貌,具有较大的比表面积和多尺度的孔结构,有利于FePc的高密度负载、活性位点的暴露和催化过程中传质效率的提高.当用旋转圆盘电极评估性能时,FePc/PG表现出优异的半波电位,达0.909 V(相对于可逆氢电极).此外,当用作气体扩散电极时,FePc/PG在高电流密度下表现出优异的高倍率和高功率性能.这项工作为设计纳米碳材料的形貌以及高性能异相分子催化剂提供了有效的策略,有望在多种能源转换和存储技术中得到应用.

摘要：Vectored non-covalent interactions—mainly hydrogen bonding and aromatic interactions—extensively contribute to(bio)-organic self-assembling processes and significantly impact the physicochemical properties of the associated ***,vectored non-covalent interaction-driven assembly occursmainly along one-dimensional(1D)or three-dimensional(3D)directions,and a two-dimensional(2D)orientation,especially that of multilayered,graphene-like assembly,has been reported *** this present research,by introducing amino,hydroxyl,and phenyl moieties to the triazine skeleton,supramolecular layered assembly is achieved by vectored non-covalent *** planar hydrogen bonding network results in high stability,with a thermal sustainability of up to about 330°C and a Young’s modulus of up to about 40 *** introducing wrinkles by biased hydrogen bonding or aromatic interactions to disturb the planar organization,the stability ***,the intertwined aromatic interactions prompt a red edge excitation shift effect inside the assemblies,inducing broad-spectrum fluorescence covering nearly the entire visible light region(400–650 nm).We show that bionic,superhydrophobic,pillar-like arrays with contact angles of up to about 170°can be engineered by aromatic interactions using a physical vapor deposition approach,which cannot be realized through hydrogen *** findings show the feasibility of 2D assembly with engineerable properties by modulating vectored non-covalent interactions.

摘要：Rational composition design of trimetallic phosphide catalysts is of significant importance for enhanced surface reaction and efficient catalytic ***,hierarchical Co_(x)Ni_(y)Fe_(z)P with precise control of stoichiometric metallic elements(x:y:z=(1-10):(1-10):1)has been synthesized,and Co_(1.3)Ni_(0.5)Fe_(0.2)P,as the most optimal composition,exhibits remarkable catalytic activity(η=320 mV at 10 mA cm^(−2))and long-term stability(ignorable decrease after 10 h continuous test at the current density of 10 mA cm^(−2))toward oxygen evolution reaction(OER).It is found that the surface P in Co_(1.3)Ni_(0.5)Fe_(0.2)P was replaced by O under the OER *** density function theory calculations before and after long-term stability tests suggest the clear increasing of the density of states near the Fermi level of Co_(1.3)Ni_(0.5)Fe_(0.2)P/Co_(1.3)Ni_(0.5)Fe_(0.2)O,which could enhance the OH−adsorption of our electrocatalysts and the corresponding OER performance.

摘要：基于功能基元和序构范式将功能基元序构成特定取向组织,可以最大限度的利用层状结构材料的力学性能各向异性.然而,其各向异性变形行为的微观起源尚不清楚.本文以全片层的γ-TiAl/α_(2)-Ti_(3)Al双相单晶为模型,通过沿特征取向的原位透射电镜拉伸试验和多尺度结构表征,揭示了界面功能基元主导的塑性各向异性及相应的变形机制.相比于片层内部本征的位错行为,跨γ/α2界面取向序构主导的滑移系连续性和界面强度在塑性各向异性中起决定性作用.因此,当平行或垂直于片层方向拉伸时,层状材料发生穿片层的应力传递或界面分层,进而导致强度和延展性的各向异性.这些机理对理解层状结构材料的塑性各向异性具有普遍意义,有利于高性能合金的结构设计.

摘要：Sodium-ion batteries have been achieving widespread attentions in grid-scale electrical energy storage systems owing to their earth abundant resources[1].However,the energy-density ceiling from cathode materials has been one of primary factors precluding the further practical applications of sodium-ion batteries[2].

摘要：This paper proposes an additive nanomanufacturing approach to fabricate a personalized lab-on-a-chip fluorescent peptide nanoparticles （f-PNPs） array for simultaneous multi-biomarker detection that can be used in Alzheimer＇s disease （AD） diagnosis. We will discuss optimization techniques for the additive nanomanufacturing process in terms of reliability, yield and manufacturing efficiency. One contribution of this paper lies in utilization of additive nanomanufacturing techniques to fabricate a patient-specific customize-designed lab-on-a-chip device for personalized AD diagnosis, which remains a major challenge for biomedical engineering. Through the integrated bio-design and bio-manufacturing process, doctor＇s check- up and computer-aided customized design are integrated into the lab-on-a-chip array for patient-specific AD diagnosis. In addition, f-PNPs with targeting moieties for personalized AD biomarkers will be self-assembled onto the customized lab-on-a- chip through the additive nanomanufacturing process, which has not been done before. Another contribution of this research is the personalized lab-on-a-chip f-PNPs array for AD diagnosis utilizing limited human blood. Blood-based AD assessment has been described as ＂the holy grail＂ of early AD detection. This research created the computer-aided design, fabrication through additive nanomanufacturing, and validation of the f-PNPs array for AD diagnosis. This is a highly interdisciplinary research contributing to nanotechnology, biomaterials, and biomedical engineering for neurodegenerative disease. The conceptual work is preliminary with intent to introduce novel techniques to the application. Large-scale manufacturing based on the proposed framework requires extensive validation and optimization.