摘要：The A_(2)B_(2)O_(7)-type rare earth zirconate compounds have been considered as promising candidates for thermal barrier coating(TBC) materials because of their low sintering rate,improved phase stability,and reduced thermal conductivity in contrast with the currently used yttria-partially stabilized zirconia (YSZ) in high operating temperature *** review summarizes the recent progress on rare earth zirconates for TBCs that insulate high-temperature gas from hot-section components in gas *** on the first principles,molecular dynamics,and new data-driven calculation approaches,doping and high-entropy strategies have now been adopted in advanced TBC materials *** this paper,the solid-state heat transfer mechanism of TBCs is explained from two aspects,including heat conduction over the full operating temperature range and thermal radiation at medium and high *** paper also provides new insights into design considerations of adaptive TBC materials,and the challenges and potential breakthroughs are further highlighted for extreme environmental *** for improving thermophysical performance are proposed in two approaches:defect engineering and material compositing.

摘要：Despite being a promising photoanode material for water splitting,WO_(3) has low conductivity,high onset potential,and sluggish water oxidation *** this study,we designed Ti-doped WO_(3) nanoplate arrays on fluoride-doped tin oxide by a seed-free hydrothermal method,and the effects of doping on the photoelectrochemical performance were *** optimal Ti-doped WO_(3) electrode achieved a photocurrent density of 0.53 mA/cm^(2) at 0.6 V(vs Ag/AgCl),110%higher than that of pure WO_(3) nanoplate ***,a significant cathodic shift in the onset potential was observed after doping.X-ray photoelectron spectroscopy valence band and ultraviolet–visible spectra revealed that the band positions of Ti-doped WO_(3) photoanodes moved upward,yielding a lower onset ***,electrochemical impedance spectroscopy measurements revealed that the conductivities of the WO_(3) photoanodes improved after doping,because of the rapid separation of photo-generated charge ***,we report a new design route toward efficient and low-cost photoanodes for photoelectrochemical applications.

摘要：The intrinsic drawbacks of electrolytes and the growth of lithium dendrites limit the development of commercial lithium *** address the aforementioned challenges,a novel biomimetic brain-like nanostructure(BBLN)solid polymer electrolyte was created by manipulating the shape of the incorporated *** designed BBLN solid polymer electrolyte was created by incorporating spherical core-shell(UIO-66@67)fillers into polymer electrolyte,which is significantly different from traditional polymer-based composite ***-66@67 spherical nanoparticles are highly favorable to eliminating polymer electrolyte stress and deformation during solidification,indicating a great potential for fabricating highly uniform BBLN solid polymer electrolytes with a substantial number of continuous ***,spherical nanoparticles can significantly reduce the crystalline structure of polymer electrolytes,improving polymer chain segmental movement and providing continuous pathways for rapid ion *** a result,BBLN solid polymer electrolyte shows excellent ionic conductivity(9.2×10^(−4)S cm^(−1)),a high lithium transference number(0.74),and outstanding cycle stability against lithium electrodes over 6500 h at room *** concept of biomimetic brain-like nanostructures in this work demonstrates a novel strategy to enhance ion transport in polymerbased electrolytes for solid-state batteries.

摘要：The active sites of monodisperse transition metal Ni-clusters were anchored on carbon nitride(CN)by an in situ photoreduction deposition method to promote the efficient separation of photogenerated charges and achieve high-efficiency photocatalytic activity for hydrogen *** Ni-cluster/CN exhibited a photocatalytic hydrogen production rate of 16.5 mmol·h^(-1)·g^(-1) and a total turnover frequency(TOF(H_(2)))value of 461.14 h^(-1).X-ray absorption spectroscopy based on synchrotron radiation indicated that CN had two reaction centers to form stable interface interactions with monodispersed Ni-clusters,in which carbon can act as an electron acceptor,while nitrogen can act as an electron ***,the hybrid electronic structure of the Ni-cluster/CN system was constructed,which was favorable for photocatalytic activity for hydrogen *** in-depth understanding of the interfacial interaction between CN and Ni-clusters will have important reference significance on the mechanistic study of development based on the cocatalyst.

摘要：The effect of depressurizing speed on mold filling behavior and entrainment of oxide film of A356 alloy was studied. Themold filling behavior and velocity fields were recorded by water simulation with particle image velocimetry. The results show thatthe gate velocity first increased dramatically, then changed with the depressurizing speed: the gate velocity increased slowly atrelatively high depressurizing speed; at reasonable depressurizing speed, the gate velocity kept unchanged; while at lowerdepressurizing speed, the gate velocity decreased firstly and then kept unchanged. High gate velocity results in melt falling backunder gravity at higher speed. The falling velocity is the main factor of oxide film entrainment in vacuum suction casting. The designcriterion of depressurizing rate was deduced, and the A356 alloy castings were poured to test the formula. The four-point bend testand Weibull probability plots were applied to assessing the fracture mechanisms of the as-cast A356 alloy. The results illuminate amethod on designing suitable depressurizing speed for mold filling in vacuum suction casting.

摘要：Laboratory-scale experiments were performed to investigate the deoxidation of H13 tool steel with CaF_(2)-MgO-Al_(2)O_(3)-CaO-SiO_(2) slags at 1873 *** calculation of thermodynamics and kinetics was also verified through the experimental *** results show that[Si]-[O]reaction is the control reaction,and with the increase of basicity of slag,the limitation of deoxidation was *** limitation of deoxidation is the lowest for the slag with basicity of *** the conditions of the basicity of 2.0 and the content of CaF_(2) more than 50%,the limitation of deoxidation is less than 10×10^(−6),and it does not depend on the contents of Al_(2)O_(3) and CaF_(2) in *** mass transport of oxygen in the metal phase is the rate-controlling step,and the slag composition has no effect on the equilibrium time of *** on this finding,the optimized slag composition is designed and it contains the following components:51.5%CaF_(2),20.3%MgO,16.2%Al_(2)O_(3),8.2%CaO and 3.8%SiO_(2).In the case of the optimized deoxidizing slag,the total oxygen content in H13 steel can be reduced from 25×10^(−6) to 6×10^(−6).