摘要：Tissue implant-related infections are among the most serious complications after surgical implantation,including orthopedics and *** with antibacterial ion release systems are efficient and economical antibiotic substitutes to fight against bacterial ***,the excessive amount of released antibacterial ions may cause biological toxicity while killing *** raises a fundamental issue on how to properly control the amounts of ions and their ***,we develop low-dose antibacterial ions-incorporated ferroelectric implants(copper-doped potassium sodium niobate,K0.5Na0.5NbO3-Cu,KNNCu)whose surface potential can be tuned via external *** released Cu2+ions can be targeted to bacteria via endogenous electric field(EEF)between KNNCu implants and negatively charged ***,the antibacterial efficacy of the implants is determined by the amount of Cu^2+ions that reaches bacteria,instead of the total amount of released Cu2+*** amount of Cu2+ions reaching bacteria from the high-surface-potential implant is 2.4 times that from the lowsurface-potential implant within 12 h,resulting in the increased antibacterial ratio from about 65%to 100%,while remaining low cell *** work provides insights into the specific role of the EEF in guiding mass transport between charged materials and living organisms,and a new perspective for the design of high-performance antibacterial biomaterials.

摘要：由人工结构组成的超材料具有传统材料不具备的卓越性能.通过设计和排列具有特殊物理性质的单元结构可制备用于高效电磁波吸收的吸波超材料.这些亚波长尺度的单元结构是吸波超材料超越传统材料性能极限的基础,因此制造工艺的匹配尤为重要.快速发展的3D打印技术在制造具有复杂结构的材料方面展现出巨大的优势和潜力,为研究和制备吸波超材料提供了一种简单、快速、高效的方法.在这篇综述中,我们介绍了吸波超材料的概念和发展,重点介绍了利用3D打印技术制造吸波超材料的研究现状.此外,还简要介绍了超材料的典型应用,讨论了当前超材料发展的不足和3D打印技术制备吸波超材料的局限性,并提出了超材料和3D打印技术结合的发展前景.

摘要：Advanced electromagnetic(EM)wave absorbing materials with strong absorption and broad bandwidth are important for military stealth and elimination of microwave pollution in consumers’*** organic framework(MOF)-derived metal/carbon hybrids with ordered structure are significantly urgent in this *** this contribution,we presented a design strategy of hollow cage-like or solid box-like magnetic/dielectric Fe/Co/C and dielectric Fe/Mn/C EM wave absorbing nanomaterials via pyrolyzing Prussian blue’s analogs with controllable topology and phase *** solid box-like Fe/Co/C and hollow cage-like Fe/Mn/C showed favorable absorption property with a broad effective absorption bandwidth(EAB)and a low reflection loss(RL).Especially,the EAB of 8.8 GHz at a thickness of 2.5 mm for solid box-like Fe/Co/C nanocomplex prepared at 900℃is a new record for this type of *** design and tuning strategy for EM wave absorbers derived from topology-controllable MOF is important for EM functional materials possessing great potential in military stealth and consumers’electronics.

摘要：可被蓝光激发的高热稳定性红色荧光粉是制作高性能白光二极管(WLED)的关键材料.研究发现,Ce^(3+)掺杂的SrLaScO_(4)(SLO:Ce^(3+))荧光粉在440 nm激发下呈现峰值为640 nm的反常宽带红光发射.光谱学和结构分析证实Ce^(3+)离子在SLO中进入[LaO_(8)]多面体,产生强的晶体场劈裂和较大的Stokes位移,实现了比Eu^(2+)更低能量的红光发射.我们还设计并揭示了一种电荷转移相互作用的策略:在Sc^(3+)位置引入电负性较大的Ga^(3+),Ga^(3+)可以吸引更多邻位配合基团的电荷,以减少导带底部的电子占用而扩大带隙.Sc/Ga取代有效地抑制了热激活电离过程,使SrLa(Sc,Ga)O_(4):Ce^(3+)的热稳定性获得了显著提升,即在150℃的发光强度比(相对于20℃)从15%提升至31%.本研究为发现具有良好热稳定性的新型Ce^(3+)掺杂红色荧光粉提供了有效的设计原则.

摘要：Design and preparation of highly efficient zeolite catalysts for gas-phase Beckmann rearrangement of cyclohexanone oxime to caprolactam are attractive but still ***,we show a one-pot synthesis of silicalite-1 zeolite nanosheets with rich H-bonded *** key to this success is the use of urea in the synthetic *** tests of cyclohexanone oxime gas-phase Beckmann rearrangement show that the silicalite-1 zeolite nanosheets with H-bonded silanols exhibit higher selectivity for caprolactam and longer reaction lifetime than those of the conventional silicalite-1 *** simulations reveal that the ammonium decomposed by urea is a critical additive for the formation of H-bond ***,one-pot synthesis of silicalite-1 zeolite nanosheets with rich H-bonded silanols plus excellent catalytic performance in the Beckmann rearrangement offer a new opportunity for development of highly efficient zeolites for catalytic applications in the future.

摘要：Emerging quantum dots(QDs)based light-emitting field-effect transistors(QLEFETs)could generate light emission with high color purity and provide facile route to tune optoelectronic properties at a low fabrication *** efforts have been devoted to designing device structure and to understanding the underlying physics,yet the overall performance of QLEFETs remains low due to the charge/exciton loss at the interface and the large band offset of a QD layer with respect to the adjacent carrier transport ***,we report highly efficient QLEFETs with an external quantum efficiency(EQE)of over 20%by employing a dielectric-QDs-dielectric(DQD)sandwich *** DQD structure is used to control the carrier behavior by modulating energy band alignment,thus shifting the exciton recombination zone into the emissive ***,enhanced radiative recombination is achieved by preventing the exciton loss due to presence of surface traps and the luminescence quenching induced by interfacial charge *** DQD sandwiched design presents a new concept to improve the electroluminescence performance of QLEFETs,which can be transferred to other material systems and hence can facilitate exploitation of QDs in a new type of optoelectronic devices.

摘要：Discriminating between different liquids using surfaces with special wettability holds significant implications for both fundamental research and practical ***,current differentiation surfaces still struggle with challenges such as complex microstructure design,a limited detection range,and poor *** this study,we present a new platform for droplet discrimination achieved through a combination of groove structures and a liquid-like polydimethylsiloxane(PDMS)brushes *** PDMS brushes coating exhibits excellent stability and low adhesion across a wide range of liquids with surface tensions ranging from 27.5 to 72.8 mN/m,while the groove structure provides distinct energy barriers for droplet ***,liquids with varying surface tensions can be effectively discriminated,as evidenced by the increased sliding angles(SAs)observed as liquids with lower surface tension moving across the ***,we utilized a three dimensional(3D)model of the droplet developed using Surface Evolver,and conducted energy variation calculations during droplet sliding across the groove to analyze the SA differences among liquids with different surface ***,we proposed two simple differentiation platforms that successfully demonstrated effective droplet *** work introduces a novel strategy for droplet discrimination,offering innovative ideas for the design of functional *** findings may potentially be applied in other fields involving droplet manipulation,such as droplet-based microchemical reactions and bio-detection.

摘要：Electrochemical CO2 reduction is a promising strategy for the utilization of CO2 and intermittent excess *** is the only single metal catalyst that can electrochemically convert CO2 into multicarbon ***,Cu exhibits an unfavorable activity and selectivity for the generation of C2 products because of the insufficient amount of CO*provided for the C‐C *** on the strong CO2 adsorption and ultrafast reaction kinetics of CO*formation on Pd,an intimate CuPd(100)interface was designed to lower the intermediate reaction barriers and improve the efficiency of C2 product *** functional theory(DFT)calculations showed that the CuPd(100)interface enhanced the CO2 adsorption and decreased the CO2*hydrogenation energy barrier,which was beneficial for the C‐C *** potential‐determining step(PDS)barrier of CO2 to C2 products on the CuPd(100)interface was 0.61 eV,which was lower than that on Cu(100)(0.72 eV).Encouraged by the DFT calculation results,the CuPd(100)interface catalyst was prepared by a facile chemical solution method and characterized by transmission electron ***2 temperature‐programmed desorption and gas sensor experiments further confirmed the enhancement of the CO2 adsorption and CO2*hydrogenation ability of the CuPd(100)interface ***,the obtained CuPd(100)interface catalyst exhibited a C2 Faradaic efficiency of 50.3%±1.2%at‒1.4 VRHE in 0.1 M KHCO3,which was 2.1 times higher than that of the Cu catalyst(23.6%±1.5%).This study provides the basis for the rational design of Cu‐based electrocatalysts for the generation of multicarbon products by fine‐tuning the intermediate reaction barriers.

摘要：It is highly desired to improve the photoelectric property of nanosized BiOBr by promoting the photogenerated charge transfer and separation. Herein, SnO2 and Ag comodified BiOBr nanocomposites(Ag-SO-BOB) have been prepared through a simple one-pot hydrothermal *** photovoltage response of BiOBr nanoplates has 4.1-time enhancement after being modified with SnO2 nanoparticles. Transient-state surface photovoltage(TS-SPV) and the atmosphere-controlled steady-state surface photovoltage spectroscopy(AC-SPS) confirmed that this exceptional enhancement of the photovoltage response can be ascribed to the coupled SnO2 acting as platform for accepting the photoelectrons from BiOBr so as to prolong the lifetime and enhance charge separation. Remarkably, the surface photovoltage response can be further enhanced by synchronously introducing Ag nanoparticles, which is up to 15.4-times enhancement compared with bulk BiOBr nanoplates. The enhancement can be attributed to the improved O2 adsorption by introducing Ag to further enhance charge separation. Finally, the synergistic effect of SnO2 and Ag co-modification enhances the surface photovoltage response due to the enhanced charge separation and promoted O2 adsorption, which is also confirmed through photoelectrochemistry and photocatalytic experiment.

摘要：Left-hand materials have drawn increasing attention from many disciplines and found widespread application, especially in microwave engineering. A sandwiched metamaterial consisting of multi-nested square-split-ring resonators on the top side and a set of wires on the back side is proposed. Scattering parameters are retrieved by high-frequency structure simulator(HFSS) software based on the finite element method. Effects of square-split-ring number on the left-hand characteristics containing negative values of permittivity, permeability, and refractive index have been intensively investigated. Simulated results show that obvious resonant left-hand characteristics could be observed within 8-18 GHz, and the resonant frequency counts are inclined to be in direct proportion to the square-split-ring number over 8-18 GHz. Besides, the proposed sandwiched metamaterial with three square-split-ring resonators and three wires presents the widest frequency band of left-hand characteristics in a range of 8-18 GHz. Further, electromagnetic field distributions demonstrated that the induced magnetic dipole dominates the resonant absorption. The multi-peak resonance characteristics of square-split-ring resonant structure are considered to be a promising candidate for selective-frequency absorption or modulation toward microwave frequency band.