摘要：A new time-resolved shifted dual transmission grating spectrometer （SDTGS） is designed and fabricated in this work. This SDTGS uses a new shifted dual transmission grating （SDTG） as its dispersive component, which has two sub transmission gratings with different line densities, of 2000 lines/mm and 5000 lines/mm. The axes of the two sub transmission gratings in SDTG are horizontally and vertically shifted a certain distance to measure a broad range of 0.1-5 keV time-resolved X-ray spectra. The SDTG has been calibrated with a soft X-ray beam of the synchrotron radiation facility and its diffraction efficiency is also measured. The designed SDTGS can take full use of the space on a record panel and improve the precision for measuring spatial and temporal spectrum simultaneously. It will be a promising application for accurate diagnosis of the soft X-ray spectrum in inertial confinement fusion.

摘要：A novel fiber Bragg grating （FBG） rain gauge is proposed in this paper to achieve high precision rainfall measurement. One core sensitive FBG, a temperature compensation FBG and a mechanical transition system construct this novel FBG rain gauge. Sensing principle of this FBG rain gauge is explained in detail, and its theoretical calculation model is also established, which shows that the relationship between center wavelength of sensitive FBG and external rainfall has very good linearity. To verify its detection performance, the calibration experiment on one prototype of this FBG rain gauge is carried out. After experiment data analysis, the detection precision of this FBG rain gauge is 15.4/.tm which is almost two orders of magnitude higher than that of the existing rainfall measurement device. The experimental data confirm that this FBG rain gauge can achieve rainfall measurement with high precision.

摘要：Hydrogen,regarded as a promising energy carrier to alleviate the current energy crisis,can be generated from hydrogen evolution reaction(HER),whereas its efficiency is impeded by the activity of ***,effective strategies,such as strain and interfacial engineering,are imposed to tune the catalysis performance of novel two-dimensional(2D)phosphorus carbide(PC)layers using first-principle *** findings show that P site in pristine monolayer PC(ML-PC)exhibits higher HER performance than C ***,constructing bilayer PC sheet(BL-PC)can change the coordinate configuration of P atom to form 3-coordination-P atom(3-co-P)and 4-coordination-P atom(4-co-P),and the original activity of 3-co-P site is higher than the 4-co-P *** an external compressive strain is applied,the activity of the 4-co-P site is enhanced whereas the external strain can barely affect that of 3-co-P ***,the graphene substrate enhances the overall activity of the BL-PC because the graphene substrate optimizes the?GH*value of 4-co-P site,although it can barely affect the HER activity of 3-co-P site and *** desirable properties render 2 D PC-based material promising candidates for HER catalysts and shed light on the wide utilization in electrocatalysis.

摘要：A biosensor device, built from graphene nanoribbons （GNRs） with nanopores, was designed and studied by first- principles quantum transport simulation. We have demonstrated the intrinsic transport properties of the device and the effect of different nucleobases on device properties when they are located in the nanopores of GNRs. It was found that the device＇s current changes remarkably with the species of nucleobases, which originates from their different chemical compositions and coupling strengths with GNRs. In addition, our first-principles results clearly reveal that the distinguished ability of a device＇s current depends on the position of the pore to some extent. These results may present a new way to read off the nucleobases sequence of a single-stranded DNA （ssDNA） molecule by such GNRs-based device with designed nanopores

摘要：The multiple quantum transitions within d-band correlation oxides such as rare-earth nickelates(RENiO_(3))triggered by critical temperatures and/or hydrogenation opened up a new paradigm for correlated electronics applications,*** electric field sensor,bio-sensor,and neuron synapse logical ***,these applications are obstructed by the present ineffectiveness in the thin film growth of the metastable RENiO_(3)with flexibly adjustable rare-earth compositions and electronic ***,we demonstrate a metal-organic decompositions(MOD)approach that can effectively grow metastable RENiO_(3)covering a large variety of the rare-earth composition without introducing any vacuum *** the previous chemical growths for RENiO_(3)relying on strict interfacial coherency that limit the film thickness,the MOD growth using reactive isooctanoate percussors is tolerant to lattice defects and therefore achieves comparable film thickness to vacuum *** indicated by positron annihilation spectroscopy,the RENiO_(3)grown by MOD exhibit large amount of lattice defects that improves their hydrogen incorporation amount and electron transfers,as demonstrated by the resonant nuclear reaction analysis and near edge X-ray absorption fine structure *** effectively enlarges the magnitude in the resistance regulations in particular for RENiO_(3)with lighter RE,shedding a light on the extrinsic regulation of the hydrogen induced quantum transitions for correlated oxides semiconductors kinetically via defect engineering.

摘要：The design of a novel photonic crystal waveguide power splitter is *** proposed power splitter has three output ports,the coupling among three parallel photonic crystal waveguides can be considered as a multimode interference(MMI),and the positions of output waveguides are determined by those of twofold images which are formed by the self-imaging effect of multimode *** transmission characteristics of the splitter are investigated by using the finite-difference time domain(FDTD) and the plane wave expansion *** output optical power in each port can be controlled by adjusting the radius of the dielectric rods in the coupling region,and the coupling effect among output ports is decreased by using the T-shaped output *** results indicate that 1 × 1,1 × 2 and 1 × 3 type power splitters can be realized when the normalized radius of dielectric rods in the coupling region is 0.130,0.180,0.152 or 0.221,respectively.

摘要：A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths （OF,） to the different positions of the spherical [60]fullerene （C60） through a rigid linkage. The conjugates were characterized by IH-NMR, 13C-NMR, FTIR, EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy, fluorescence spectrometry, and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C60 and OFn remained unchanged when different lengths of OFn were attached to C60. The electron affinities of the OFn-C60 conjugates were close to that of C60, while slight electronic interaction was found between the two individual chromophores （C60 and OFn） in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution, suggesting an effective energy transfer from OFn to C60. It presents a systematic study on the self- assembly, structure-property relationship, and potential technical applications of the conjugates.

摘要：Circulators play a significant role in radar and microwave communication *** paper proposes a broadband and highly efficient plasmonic circulator,which consists of spoof surface plasmon polaritons(SSPPs)waveguides and ferrite disks to support non-reciprocal mode *** simulated performance of symmetrically designed circulator shows that it has an insertion loss of roughly 0.5 dB while the isolation and return loss is more than 12 dB in the frequency range of 6.0 GHz–10.0 GHz(relative bandwidth of 50%).Equivalent circuit model has been proposed to explain the operating mechanism of the plasmonic *** equivalent circuit model,numerical simulations,and experimental results are consistent with each other,which demonstrates the good performance of the proposed plasmonic circulator.

摘要：At present,metal-organic framework(MOF)-derived nano-micro architectures are actively explored for electromagnetic(EM)wave absorption owing to their flexible composition and structural manipulation that enhance dielectric and magnetic ***,the basic design principles in MOF-derived microwave absorption materials have not been *** review is devoted to analyzing design principles in MOF-derived microwave absorption materials from the following perspectives:diverse monomers(ligands and ions of MOFs),topologies,chemical states,and physical *** derived essential information regarding the EM wave absorption mechanism and the structural-functional dependency is also comprehensively ***,a clear insight into the challenges and perspectives of the industrial revolution upgrading in this promising field is proposed.

摘要：Based on the underlying graphene lattice symmetry and an itinerant magnetism model on a bipartite lattice,we propose a unifi ed geometric rule for designing graphene-based magnetic nanostructures:spins are parallel(ferromagnetic(FM))on all zigzag edges which are at angles of 0°and 120°to each other,and antiparallel(antiferromagnetic(AF))at angles of 60°and 180°.The rule is found to be consistent with all the systems that have been studied so *** the rule,we predict several novel graphene-based magnetic nanostructures:0-D FM nanodots with the highest possible magnetic moments,1-D FM nanoribbons,and 2-D magnetic superlattices.