摘要：Nanomaterials have garnered recognition for their notable surface effects and demonstration of superior mechanical *** studies on the surface effects of nanomaterials,employing the finite element method,often relied on simplified twodimensional models due to theoretical ***,these simplified models inadequately represent the mechanical properties of nanomaterials and fail to capture the substantial impact of surface effects,particularly the curvature dependence of *** study applies the principle of minimum energy and leverages the Steigmann-Ogden surface theory of nanomaterials to formulate a novel finite element surface element that comprehensively accounts for surface *** conducted an analysis of the stress distribution and deformation characteristics of four typical 2D and 3D nanomaterial *** accuracy of the developed surface element and finite element calculation method was verified through comparison with established *** resulting finite element model provides a robust and compelling scientific approach for accurately predicting the mechanical performance of nanomaterials.

摘要：Phase transformation of two-dimensional(2D)nanomaterials can lead to significant changes in electronic and optical properties,which enables the development of novel *** strategies for phase engineering of 2D nanomaterials have drawn considerable attention in recent *** review focuses on the state-of-the-art progress in the phase transformation of 2D nanomaterials and their catalytic ***,the basic concepts of phase transformation and the outstanding electronic and optical properties induced by phase transformation are briefly ***,different strategies for achieving phase transformation are discussed in detail and classified into several types based on their characteristics,including(i)doping,(ii)external fields,(iii)optical irradiation,(iv)strain effect,(v)high-energy particle excitation,and(vi)thermal *** applications of 2D nanomaterials in catalysis based on phase transformation have also been ***,a summary of the technical challenges to phase control in 2D nanomaterials and potential opportunities for developing novel applications is presented.

摘要：Molybdenum-based catalysts have demonstrated significant potential in the electrocatalytic hydrogen evolution reaction(HER).However,the limited exposure of active sites and strong hydrogen adsorption result in suboptimal ***,a Mo_(2)N±MoSe_(2) heterojunction is prepared on carbon cloth(MNS/CC)to enhance the *** strong electronic interaction between Mo_(2)N and MoSe_(2),combined with the lower work function of Mo_(2)N,creates an intrinsic electric field at the heterojunction interface,which markedly improves charge transfer ***,the optimized electronic structure of Mo sites further enhances charge transfer and intrinsically catalytic activity in *** a result,MNS/CC requires overpotentials of mere 65 and 210 mV to achieve current densities of 20 mA cm^(−2) and 1 A cm^(−2),respectively,with a Tafel slope of only 96 mV dec−***,MNS/CC maintains stable operation at 1 A cm^(−2) for 240 h without significant *** results offer insights into the design of non-precious metal-based electrocatalysts for industrial hydrogen production.

摘要：Long-lasting phosphorescent （LLP） materials have attracted considerable attention since green and blue emitting persis- tent Eu2＋ doped alkaline earth phosphors were reported in the mid-1990s [1-3]. Over the past few decades, a consid- erable effort has been made to design novel LLP materials for a wide range of applications such as emergency lighting, interior decoration, road signs, and in vivo bioimaging [4-6]. For these applications, long persistence times are often desir- able. Two types of active center involved are： emitters and traps in LLP phosphors. Emitters are capable of emitting ra- diation after being excited, and their color is determined by the emission wavelength of the LLP phosphor. Traps states usually do not emit radiation, but store the excitation energy later releasing it to the emitters under thermal disturbance. Thus, traps play an important role in photo-energy storage of LLP phosphors. The trap type and trap distribution are gen- erally associated with lattice defects and/or co-dopants. The overall nature of the trap states determines the persistence in- tensity and time. Thus, design of LLP phosphors focuses on generating suitable trap levels and trap densities.

摘要：The separator is a key component of sodium-ion battery,which greatly affects the electrochemical performances and safety characteristics of the *** glass fiber separator cannot meet the requirements of large-scale application because of high cost and poor mechanical ***,the novel composite separators are prepared by a simple slurry sieving process using glass fiber separator scraps and ordinary qualitative filter paper as raw *** the composite mass ratio is 1:1,the composite separator has excellent comprehensive properties,including tensile strength of 15.8 MPa,porosity of 74.3%,ionic conductivity of 1.57×10^(-3)S·cm^(-1)and thermal stability at 210℃.The assembled sodium-ion battery shows superior cycling performance(capacity retention of 94.1%after 500 cycles at 1C)and rate capacity(retention rate of 87.3%at 10C),and it maintains fine interface *** above results provide some new ideas for the separator design of high-performance and low-cost sodium-ion batteries.

摘要：A new complementary metal oxide semiconductor UV/blue-extended photodiode was presented for light detection in the UV/blue spectral range. Photoelectric characteristics of this presented photodiode were studied by numerical modeling and device simulation. Technology computer aided design simulation was done first to analyze its photoelectric characteristics. The structure characteristic and depletion situation of space between two adjacent P+ anodes were discussed. The reverse characteristic, spectral response characteristic and DC characteristic were discussed in detail. For the numerical modeling, dead layer effect is considered in the building of analytical mode. Dead layer is a space in which the boron doping profile decreases towards the surface due to high doping effects and boron redistribution, which affects the sensitivity of photodiode in the UV range seriously. Reverse characteristics and spectral response characteristics were modeled and analyzed typically. At last, silicon test results were given and compared with the simulated result, which shows reasonable match for each.

摘要：Optimization of grain boundary engineering(GBE) process is explored in a Fe–20Cr–19Mn–2Mo–0.82N high-nitrogen and nickel-free austenitic stainless steel, and its intergranular corrosion(IGC) property after GBE treatment is experimentally evaluated. The proportion of low Σ coincidence site lattice(CSL) boundaries reaches 79.4% in the sample processed with 5% cold rolling and annealing at 1423 K for 72 h;there is an increase of 32.1% compared with the solution-treated sample. After grain boundary character distribution optimization, IGC performance is noticeably improved. Only Σ3 boundaries in the special boundaries are resistant to IGC under the experimental condition. The size of grain cluster enlarges with increasing fraction of low ΣCSL boundaries, and the amount of Σ3 boundaries interrupting the random boundary network increases during growth of the clusters, which is the essential reason for the improvement of IGC resistance.

摘要：Hydrogen,regarded as a promising energy carrier to alleviate the current energy crisis,can be generated from hydrogen evolution reaction(HER),whereas its efficiency is impeded by the activity of ***,effective strategies,such as strain and interfacial engineering,are imposed to tune the catalysis performance of novel two-dimensional(2D)phosphorus carbide(PC)layers using first-principle *** findings show that P site in pristine monolayer PC(ML-PC)exhibits higher HER performance than C ***,constructing bilayer PC sheet(BL-PC)can change the coordinate configuration of P atom to form 3-coordination-P atom(3-co-P)and 4-coordination-P atom(4-co-P),and the original activity of 3-co-P site is higher than the 4-co-P *** an external compressive strain is applied,the activity of the 4-co-P site is enhanced whereas the external strain can barely affect that of 3-co-P ***,the graphene substrate enhances the overall activity of the BL-PC because the graphene substrate optimizes the?GH*value of 4-co-P site,although it can barely affect the HER activity of 3-co-P site and *** desirable properties render 2 D PC-based material promising candidates for HER catalysts and shed light on the wide utilization in electrocatalysis.

摘要：The multiple quantum transitions within d-band correlation oxides such as rare-earth nickelates(RENiO_(3))triggered by critical temperatures and/or hydrogenation opened up a new paradigm for correlated electronics applications,*** electric field sensor,bio-sensor,and neuron synapse logical ***,these applications are obstructed by the present ineffectiveness in the thin film growth of the metastable RENiO_(3)with flexibly adjustable rare-earth compositions and electronic ***,we demonstrate a metal-organic decompositions(MOD)approach that can effectively grow metastable RENiO_(3)covering a large variety of the rare-earth composition without introducing any vacuum *** the previous chemical growths for RENiO_(3)relying on strict interfacial coherency that limit the film thickness,the MOD growth using reactive isooctanoate percussors is tolerant to lattice defects and therefore achieves comparable film thickness to vacuum *** indicated by positron annihilation spectroscopy,the RENiO_(3)grown by MOD exhibit large amount of lattice defects that improves their hydrogen incorporation amount and electron transfers,as demonstrated by the resonant nuclear reaction analysis and near edge X-ray absorption fine structure *** effectively enlarges the magnitude in the resistance regulations in particular for RENiO_(3)with lighter RE,shedding a light on the extrinsic regulation of the hydrogen induced quantum transitions for correlated oxides semiconductors kinetically via defect engineering.

摘要：Circulators play a significant role in radar and microwave communication *** paper proposes a broadband and highly efficient plasmonic circulator,which consists of spoof surface plasmon polaritons(SSPPs)waveguides and ferrite disks to support non-reciprocal mode *** simulated performance of symmetrically designed circulator shows that it has an insertion loss of roughly 0.5 dB while the isolation and return loss is more than 12 dB in the frequency range of 6.0 GHz–10.0 GHz(relative bandwidth of 50%).Equivalent circuit model has been proposed to explain the operating mechanism of the plasmonic *** equivalent circuit model,numerical simulations,and experimental results are consistent with each other,which demonstrates the good performance of the proposed plasmonic circulator.