摘要：Currently,air pollution is being exacerbated by rapid social,economic,and industrial *** air pollutants include volatile organic compounds(VOCs)and *** and thermocatalytic technology can be used to convert VOCs and CO into harmless gases ***,photothermal synergistic catalysis has aroused much attention because of its higher performance than those of individual photocatalytic and thermocatalytic *** have been many reviews on separate photocatalysts and thermocatalysts for the treatment of VOCs and CO,but few reviews have focused on photothermal synergistic *** this minireview,we concentrate on recent progress into photothermal synergistic catalysis for the efficient removal of VOCs and *** treatment of typical VOCs(such as benzene,toluene,ethanol,formaldehyde,acetone,propylene,and propane)and CO are summarized and ***,we discuss the use of conventional reactor technology,such as fixed‐bed quartz reactors,for VOCs and CO *** also discuss the mechanism of the photothermal synergistic catalytic removal of VOCs and ***,we present perspectives for the photothermal synergistic catalytic removal of VOCs and CO.

摘要：受最新材料科学、计算机技术、人工智能和自动控制技术的启发,新一代交通基础设施正在走向数字化和智能化。世界上许多主要发达国家都在因地制宜,积极推动智能创新技术在交通基础设施中的应用。本文首先简要介绍了交通基础设施智能化的基本概念、科学依据和发展历程。然后,按照设计、施工、运维、淘汰的全生命周期链条,系统分析了智能化技术的研究现状和面临的主要挑战。随后,以世界上第一条基于智能建设理念建设的铁路——北京-张家口高铁为例,全面介绍了智能技术的最新成就。最后,从标准体系、理论方法和人才培养三个维度对交通基础设施智能化的未来发展进行了探讨。

摘要：用有限元方法模拟了不同形状钻头的破岩效果,研究了地层应力分布及裂缝延伸模式。按照国际钻井商协会(IADC)分类标准设计了14种钻头形状。设计了地层模型,给出了钻头尺寸、地层性质、网格划分方法和边界条件等。采用拟静态条件和质量缩放法以减少模拟时间、提高模拟精度。模拟结果表明,对于9种常用钻头形状,增加锥体高度高应力区面积会增大,而保径高度与产生的应力之间没有明显关系。减小保径高度,高应力区从鼻端和中心部位转移到保径区。对于非常用钻头形状,凸形钻头产生的应力场较大,双心钻头导眼体底部应力较集中。裂缝主要产生在保径区和鼻端,锥体高度和保径高度较大的钻头产生的垂直裂缝较长。使用平形和凸形钻头时没有产生较长的垂直裂缝。双心钻头可抑制保径区的垂直裂缝,却使地层更易出现水平裂缝,有中间段扩眼器的钻头造成的井壁损伤更小。

摘要：The rapid recombination of photo-generated electron-hole pairs,insufficient active sites,and strong photocorrosion have considerably restricted the practical application of Cd S in photocatalytic ***,we designed and constructed a 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling *** using electron spin resonance spectroscopy,ultraviolet photoelectron spectroscopy,and in-situ irradiation X-ray photoelectron spectroscopy were conducted to confirm the 2D layered CdS/WO_(3) step-scheme(S-scheme)heterojunctions and CdS/MX ohmic ***,it was found that the strong interfacial electric fields in the S-scheme heterojunction photocatalysts could effectively promote spatially directional charge separation and transport between CdS and WO_(3) *** addition,2D Ti_(3)C_(2) MXene nanosheets with a smaller work function and excellent metal conductivity when used as a co-catalyst could build ohmic junctions with Cd S nanosheets,thus providing a greater number of electron transfer pathways and hydrogen evolution *** showed that the highest visible-light hydrogen evolution rate of the optimized MX-Cd S/WO_(3) layered multi-heterostructures could reach as high as 27.5 mmol/g/h,which was 11.0 times higher than that of pure CdS ***,the apparent quantum efficiency reached 12.0% at 450 *** is hoped that this study offers a reliable approach for developing multifunctional photocatalysts by integrating S-scheme and ohmic-junction built-in electric fields and rationally designing a 2D/2D interface for efficient light-to-hydrogen fuel production.

摘要：Photocatalytic solar fuel generation is currently a hot topic because of its potential for solving the energy crisis owing to its low cost and zero-carbon ***,the rapid bulk recombination of photoexcited carrier pairs is a fundamental *** resolve this problem,we synthesized a dual cocatalysts system of cobalt phosphide(Co P)and molybdenum carbide(Mo_(2)C)embedded on strontium titanate(Sr TiO_(3))*** with those of pristine SrTiO_(3) and binary samples,the dual cocatalysts system(denoted SCM)showed a significant improvement in the hydrogen evolution and CO_(2) reduction ***,the structure of SCM effectively promoted spatial charge separation and enhanced the photocatalytic *** addition,the Schottky junction formed between the SrTiO_(3) and cocatalysts enabled the rapid transfer of photoexcited electrons from SrTiO_(3) to the cocatalysts,resulting in effective separation and prolonged photoexcited electron *** electron migration route between SrTiO_(3) and the cocatalysts was determined by in situ irradiation X-ray spectroscopy,and band structures of Sr TiO_(3) and the cocatalysts are proposed based on results obtained from UV-vis diffraction reflection spectroscopy and ultraviolet photoelectron spectroscopy *** the basis of our results,the dual cocatalysts unambiguously boosts charge separation and enhances photocatalytic *** summary,we have investigated the flux of photoexcited electrons in a dual cocatalysts system and provided a theoretical basis and ideas for subsequent research.

摘要：微生物电合成(microbial electrosynthesis,MES)利用可再生电力驱动微生物固定CO_(2)合成化学品,在推进碳循环经济中具有一定潜力,受到广泛关注。但是,很少有研究通过高效反应器设计来促进产乙酸并降低能耗。本研究中,新型流动电极MES反应器的总产乙酸速率[(16±1)g·m^(-2)·d^(-1)]比无粉末活性炭(powder activated carbon,PAC)对照[(8±3)g·m^(-2)·d^(-1)]高两倍。流动电极MES反应器的库伦效率为43.5%±3.1%,能量消耗为(0.020±0.005)k Wh·g^(-1),产乙酸的能量效率为18.7%±1.3%。基于PAC的流动电极能够降低水跨膜通量、传质阻力,但是对装置电压、流变行为、乙酸吸附的影响较小。流动电极MES反应器中,能量代谢相关基因高表达,Acetobacterium的丰度增加。MES反应器中同时存在用于碳固定的还原性乙酰辅酶A途径(Wood–Ljungdahl pathway,WLP)与还原性三羧酸循环途径(reductive citric acid cycle,r TCA)。堆叠型流动电极MES中的乙酸浓度达7.0 g·L^(-1)。本研究提供一种构建可扩展MES反应器的新方法,促进CO_(2)利用以及产物生成。

摘要：A design method of an intelligent temperature control system based on single-chip microcomputer is presented in this paper. The intelligent temperature control system is divided into four parts: monitor,heater,controlled process and feedback loop. Among them,the temperature detection circuit is designed with the conductivity of water by sensor detection. The optical coupler MOC3041 is used to implement the power control circuit,whose control object is 1 kW electric heater with the 220 V alternating current power; keyboard and display circuit SMC1602A include four buttons and LCD display to achieve human-computer interaction; Based on single-chip system STC89C52,the sensor signal and keyboard set target temperature are compared to the power automatically in order to finish the water temperature control. Through the static and dynamic data testing,the results show that the proposed method provides an effective way to realize the real-time acquisition and control of temperature.

摘要：Advanced oxidation processes(AOPs) have been applied to address multiple environmental concerns including antibiotic resistance genes(ARGs). ARGs have shown an increasing threat to human health,and they are either harbored by antibiotic-resistant bacteria(ARB) or free in the ***, the control of ARGs has been substantially limited by their low concentration and the limited knowledge about their interfacial behavior. Herein, a novel AOP catalyst, Ag/TiO_(2)/graphene oxide(GO),combined with a polyvinylidene fluoride(PVDF) ultrafiltration membrane was designed with a synergistic interfacial adsorption and oxidation function to inactivate ARGs with high efficiency in both model solutions and in secondary wastewater effluent, especially when the residue concentration was *** analysis showed that the mineralization of bases and phosphodiesters mainly caused the inactivation of ARGs. Moreover, the interfacial adsorption and oxidation processes of ARGs were studied at the molecular level. The results showed that GO was rich in sp^(2) backbones and functional oxygen groups,which efficiently captured and enriched the ARGs via p-p interactions and hydrogen bonds. Therefore,the photogenerated active oxygen species attack the ARGs by partially overcoming the kinetic problems in this process. The Ag/Ti O2/GO catalyst was further combined with a PVDF membrane to test its potential in wastewater treatment applications. This work offers an efficient method and a corresponding material for the inactivation and mineralization of intra/extracellular ARGs. Moreover, the molecularlevel understanding of ARG behaviors on a solid–liquid interface will inspire further control strategies of ARGs in the future.

摘要：Semiconductor technology and packaging is advancing rapidly toward system integration where the packaging is co-designed and co-manufactured along with the wafer ***,materials issues,in particular the mesoscale microstructure,have to date been excluded from the integrated product design cycle of electronic packaging due to the myriad of materials used and the complex nature of the material phenomena that require a multiphysics approach to *** the context of the materials genome initiative,we present an overview of a series of studies that aim to establish the linkages between the material microstructure and its responses by considering the multiple perspectives of the various multiphysics *** microstructure was predicted using thermodynamic calculations,sharp interface kinetic models,phase field,and phase field crystal *** on the predicted mesoscale microstructure,linear elastic mechanical analyses and electromigration simulations on the ultrafine interconnects were *** microstructural index extracted by a method based on singular value decomposition exhibits a monotonous decrease with an increase in the interconnect *** artificial neural network-based fitting revealed a nonlinear relationship between the microstructure index and the average von Mises stress in the ultrafine *** work to address the randomness of microstructure and the resulting scatter in the reliability is discussed in this study.

摘要：The hydrogenation of CO_(2) into methanol has attracted much attention and In_(2)O_(3) is a promising *** metal elements into In_(2)O_(3)(M/In_(2)O_(3))is one of the main strategies to improve its ***,its mechanism and active sites remain unclear and need to be further ***,the noble‐metal‐free In_(x)‐Co_(y) oxides catalysts were ***‐improved performance and obvious product selectivity shift were *** optimized catalyst(In_(1)‐Co_(4))(9.7 mmol g_(cat)^(–1) h^(–1))showed five times methanol yields than pure In_(2)O_(3)(2.2 mmol g_(cat)^(–1) h^(–1))(P=4.0 MPa,T=300°C,GHSV=24000 cm^(3)_(STP) g_(cat)^(–1) h^(–1),H_(2):CO_(2)=3).And the cobalt‐catalyzed CO_(2) methanation activity was suppressed,although cobalt was most of the metal *** unravel this selectivity shift,detailed catalysts performance evaluation,together with several in‐situ and ex‐situ characterizations,were employed on cobalt and In‐Co for comparative *** results indicated CO_(2) hydrogenation on cobalt and In‐Co catalyst both followed the formate pathway,and In‐Co reconstructed and generated a surface In_(2)O_(3)‐enriched core‐shell‐like structure under a reductive *** enriched In_(2)O_(3) at the surface significantly enhanced CO_(2) adsorption capacity and well stabilized the intermediates of CO_(2) ***_(2) and carbon‐containing intermediates adsorbed much stronger on In‐Co than cobalt led to a feasible surface C/H ratio,thus allowing the*CH_(3)O to desorb to produce CH_(3)OH instead of being over‐hydrogenated to CH_(4).