摘要：Platinum(Pt)is an efficient catalyst for hydrogen evolution reaction(HER)and oxygen reduction reaction(ORR),but the debate of the relevance between the Pt particle size and its electrocatalytic activity still *** strong metal–support interaction(SMSI)between the metal and carrier causes the charge transfer and mass transport from the support to the ***,Pt species(0.5 wt.%)with various particle sizes supported on carbon nanotubes(CNTs)have been synthesized by a photo-reduction ***^1.5 nm-sized Pt catalyst shows much higher HER performance than the counterparts in all pH solutions,and the mass activity of it is even 23–36 times that of Pt/*** for ORR,the^3 nm-sized Pt catalyst exhibits the optimal performance,and the mass activity is 3 times and even 16 times that of Pt/C in acidic and alkaline media,*** high HER and ORR performances of the^1.5 nm-and^3 nm-sized Pt catalysts benefit from the SMSI between Pt and the CNTs matrix and the higher ratio of face sites to edge sites,which is meaningful for the design of efficient electrocatalysts for renewable energy application.

摘要：The design and construction of highly effective circularly polarized luminescence(CPL)-active materials has aroused considerable attention due to their widespread applications in sensors,optical devices,and asymmetric ***,the exploration of novel CPL-active materials with high luminescence dissymmetry factor(glum)values is still a ***,we describe a new approach for the preparation of supramolecular metallacycles with amplified CPL promoted by hierarchical self-assembly involving Pt···Pt ***,the resultant metallacycles exhibited strong CPL signals with high glum values,while their corresponding precursors were CPL *** CPL amplification mechanism was comprehensively validated by ultravioletvisible absorption,emission spectroscopy,nuclear magnetic resonance spectroscopy,scanning electron microscopy,transmission electron microscopy,atomic force microscopy,coarse-grained molecular dynamics simulations,and timedependent density functional theory *** work thus provides the first example of preparing highly effective CPL-active materials based on hierarchical self-assembly involving Pt···Pt interactions.