摘要：Understanding the influence of HCl on the NH_(3)-selective catalytic reduction reaction mechanism is crucial for designing highly efficient denitrification *** formation of chlorate species on the surface of the synthesized SbCeO_(x)catalyst,induced by HCl,significantly enhances low-temperature activity,as evidenced by a 30%increase in NO conversion at 155℃.Furthermore,it improves N_(2)selectivity at high temperatures,with a notable 17%increase observed at 405℃.Both experimental results and density functional theory calculations confirm that chlorate species form at Ce *** formation facilitates the creation of oxygen vacancies,boosting the oxygen exchange *** also increases NH_(3)adsorption at the Ce sites,promotes the formation of Sb-OH,and reduces competitive OH adsorption on these ***,compared with the reaction mechanism without HCl,the presence of chlorate species enhances NH_(3)adsorption and activation,which is vital for subsequent catalytic reactions.

摘要：A coordination polymer{[Cd(H_(2)dpa)(bpy)]·3H_(2)O}_(n)(Cd-CP)was designed and hydrothermal synthesized based on 4-(2,4-dicarboxyphenoxy)phthalic acid(H_(4)dpa),2,2'-bipyridine(bpy)and Cd(NO_(3))_(2)·4H_(2)*** structure was characterized by single-crystal X-ray diffraction,powder X-ray diffraction,elemental analysis,and infrared ***-CP belongs to the monoclinic crystal system with the P2_1/c space group and performs in a 1D double-chain *** adjacent double chains further form a 3D supramolecular network structure through hydrogen *** analysis shows that Cd-CP has good thermal *** analysis showed that Cd-CP had good choosing selectively and was sensitive to metal ions(Fe^(3+)and Zn^(2+)),2,4,6-trinitrophenylhydrazine(TRI),and pyrimethanil(Pth).Interestingly,when Cd-CP was used for fluorescence detection of metal ions,it was found to have a fluorescence quenching effect on Fe^(3+)but had an obvious enhancement effect on Zn^(2+).Therefore,we designed an“on-off-on”logic *** addition,the mechanism of fluorescence sensing has been deeply ***:2258625.

摘要：The development of low-cost,highly active platinum(Pt)-based electrocatalysts for oxygen reduction reaction(ORR)is crucial for widespread applications of fuel *** effective approach lies in alloying Pt with non-noble transition metals to modulate the physicochemical state of the Pt ***,fundamental challenges remain in understanding the structure-performance relationship due to the complexity of composition,crystal type,and surface structure during the alloying *** this study,we synthesized a series of PtCo bimetallic solid solutions with varying ratios using a liquid-phase synthesis *** exploiting the characteristics of solid solutions,the resulting PtCo bimetallic alloy maintains the face-centered cubic crystal structure of pure platinum,minimizing the complexities introduced during alloying and facilitating mechanism ***,under controlled alloy composition and crystal structure,we investigated the dependence of the electrocatalytic activity for the oxygen reduction reaction on the surface strain of the platinum *** S-PtCo-SNPs cathode designed accordingly endows both proton exchange membrane fuel cell(PEMFC)(2.08 W cm^(−2) at 4 A cm^(−2))and Zn-air battery(ZAB)(143.1 mW cm^(−2) at 214.5 mA cm^(−2))with outstanding performance.

摘要：Inorganic-organic composite electrolyte is proved an effective way to enhance the overall performance of the ***,simply combining powder fillers with polymers is not sufficient for the application of composite *** this work,we designed an ultrathin organic-inorganic composite solid electrolyte with high mechanical strength and ionic conductivity,in which the inorganic Li1.5Al0.5Ge1.5(PO_(4))3(LAGP)solid electrolyte is prefiberized into a three-dimensional nanofiber network to serve as a self-supporting skeleton for the polyethylene oxide(PEO)*** continuous skeleton structure not only significantly improves the mechanical strength of the PEO-based electrolyte,but also forms a continuous lithium-ion conduction path,promoting the rapid migration of lithium *** fiber-reinforced composite electrolyte has an ionic conductivity of 8.27×10^(−4) S cm^(-1) at 60°C and a tensile strength of up to 4.29 ***,it exhibits a reduced overpotential and stable long-term cycling performance over 1700 h when used in Li/Li symmetric *** LiFePO_(4)(LFP)|Li cell assembled with the fiber-reinforced composite electrolyte also delivers a specific capacity of about 142 mAh g^(−1) over 300 cycles at 0.5 C and maintains good cycling *** work provides a novel idea for designing the next generation of safe and reliable organic-inorganic composite solid-state electrolyte membranes.

摘要：Solid oxide cells(SOCs)are emerging devices for efficient energy storage and ***,during SOC operation,gaseous chromium(Cr)species released from Fe-Cr alloy interconnect can lead to Cr deposition and poisoning of air electrodes,causing substantial degradation in electrochemical performance and compromising the longterm stability of *** mini-review examines the mechanism of Cr deposition and poisoning in air electrodes under both fuel-cell and electrolysis ***,emphasis is placed on the recent advancements in strategies to mitigate Cr poisoning,offering insights into the rational design and development of active and Cr-tolerant air electrodes for SOCs.

摘要：The A–D–A′–D–A-type non-fused ring electron acceptors(NFREAs),consisting of electron-donating unit(D)as the bridge to link electron-accepting units(A and A′),have emerged as promising electron acceptors for organic solar cells(OSCs)and organic photodetectors(OPDs).As the units are linked by the carbon–carbon single bonds,these electron acceptors generally possess feasible synthesis and tunable optoelectronic ***,the recent progress of A–D–A′–D–A-type NFREAs is reviewed,including molecular design,device performance,structure–property relationships,and their applications in OSCs and ***,we discuss the challenges and propose the perspectives for the further development of A–D–A′–D–A-type NFREAs.

摘要：Much like travelers,brain researchers need maps to navigate the brain and map its *** atlases play a central role in neuroscience and clinical practice,and are a prerequisite for studying brain networks across *** cartography,the art and science of building brain atlases。

摘要：This paper addresses the transportation network design problem （NDP） wherein the dis- tance limit and en-route recharge of electric vehicles are taken into account. Specifically, in this work, the network design problem aims to select the optimal planning policy from a set of infrastructure design scenarios considering both road expansions and charging station allocations under a specified construction budget. The user-equilibrium mixed-vehicular traffic assignment problem with en-route recharge （MVTAP-ER） is formulated into a novel convex optimization model and extended to a newly developed bi-level program of the aggregated NDP integrating recharge facility allocation （NDP-RFA）. In the algorithmic framework, a convex optimization technique and a tailored CA are adopted for, respectively, solving the subproblem MVTAP-ER and the primal problem NDP-RFA. Systematic ex- periments are conducted to test the efficacy of the proposed approaches. The results highlight the impacts of distance limits and budget levels on the project selection and evaluation, and the benefits of considering both road improvement policy and recharge service provision as compared to accounting for the latter only. The results also report that the two design objectives, to respectively minimize the total system travel time and vehicle miles travelled, are conflicting for certain scenarios.

摘要：After the 21st century,high school history learning will focus on teachers promoting the twelve-year state *** recent years,in line with the changes in the new 108-year social curriculum,supporting strategies have been proposed:such as literacy orientation,inquiry and practice,learning process archives,and the structural direction of the controversial Chinese history into East Asian *** learning has indeed had a great impact on the people’s national spiritual education and the development of historical consciousness in Taiwan’s education *** is the reason Taiwan’s Ministry of Education strives to improve students’historical literacy and connotation application *** developing a learning policy,both external and internal learning factors need to be *** external aspect deals with the reasons for learning:Is learning for the purpose of using or accumulating historical wisdom in daily life to learn from the past and the present,on the other hand,to test the content of the course and the degree of absorption;or is it specifically for exams or other enlightenment *** internal aspect involves those most affected by the policy:students and *** studying and observing high school history learning policies for decades,some alternative future visions for history learning were found in the method of reflection on future research-the conclusion is that history is interestingly revitalized,and the preferred future is thematic *** to the famous futurology scholar Sohail Inayatuallah’s proposal:the causal layering *** helps understand how Taiwan’s historical policies *** how teachers and students on the front line respond to changes and take future *** key is to change the future:in the process of building an alternative future,whether the internal and external mix has changed or whether you want to try new things and expand your *** fact,the difficulty of teaching lie

摘要：A simple uniaxial oedometric system is developed to test the elastic modulus of granular materials. The stress- strain relationship is first measured under conditions of uniaxial compression with additional lateral stress and strain, then the elastic modulus of the material is determined by the linear fitting method. It is found that the modulus is positively correlated to the grain size and negatively correlated to the container size. Arching and dragging are revealed to be the mechanism of such correlations by using the digital image correlation method and the pressure film technology based on the statistical method.