摘要：We have theoretically investigated two series of cyclometalated Pt（II） complexes, a series [Pt （C, N, N） Cl] and b series [Pt （C, N, Npyrazolyl） Cl]. The geometrical and electronic structures are calculated at the ECP60MWB//6-31G＊（H, C, Cl, N, S） basis set level using DFT method; one-photon absorption （OPA） properties are calculated by using both TDDFT and ZINDO methods and two-photon absorption （TPA） properties are obtained with the ZINDO/SOS method. The resonance integrals parameters （βsp and βd） for Pt are adjusted to -1 and -28.5 eV, respectively, to make max OPA wavelength calculated by ZINDO closest to the experimental data and TDDFT results. The calculated results indicate the molecule 2b （[Pt （Cnaphthyl, N, Npyrazolyl） Cl]） has the biggest potential as outstanding TPA materials because （i） the TPA properties of b series are more outstanding in IR wavelength range, the molecules in b series have good transparencies and possess 1-pyrazolyl-NH that is also available for another metal coordination （e.g., dimerization） and chemical interactions; （ii） when C is CnaphthyI in the C, N, N ligand of cyclometalated Pt（II） complexes, the molecules have the best conjugation effect and the best TPA properties.

摘要：We investigate the area and entropy spectra of D-dimensional large Schwarzschild black holes. By utilizing the new physical interpretation of quasinormal mode frequency we find that a large Schwarzschild-AdS black hole has an equally spaced area spectrum and an equidistant entropy spectrum; both are dependent on the spacetime dimension.

摘要：In this paper, we study the thermodynamic geometry for the charged Ad S black hole surrounded by quintessence. Three different kinds of the geometries are constructed, and the corresponding curvatures are obtained. It is found that there are different divergence behaviors of these curvatures, which is general thought to closely link to the phase transition of the black hole.

摘要：We review a recent work on masses of mesons and nucleons within a hard wall model of holographic QCD in a unified *** order to treat meson and nucleon properties on the same footing,we introduced the same infrared （IR） cut for both *** framework of present approach,the best fit to the experimental data is achieved introducing the anomalous dimension for baryons.

摘要：The severe bulk recombination and sluggish oxygen evolution reaction(OER)dynamics of photoanodes severely restrict the application of photoelectrochemical(PEC)*** solve these two problems,crystallographic facet orientation and cocatalyst emergence with a high-quality photoanode/cocatalyst interface were realized through an air annealing-assisted strategy to treat atomic layer deposition(ALD)-modified SnSnanosheet *** on experimental observations and theoretical calculations,the reduced(001)crystal facet of SnSdecreases the recombination of photogenerated carriers in the bulk and improves the carrier separation of the ***,the unexpectedly formed ZnTiOSfilm decreases the overpotential of the surface OER,reduces interface recombination,and extends the carrier *** synergistic effects lead to significantly enhanced PEC performance,with a high photocurrent density of 1.97 mA cm^(-2)at 1.23 V *** hydrogen electrode(RHE)and a low onset potential of 0.21 V ***,which are superior to reported mostly SnS-based photoanodes.

摘要：The photo-induced ultrafast electron dynamics in both anatase and rutile TiO_(2) are investigated by using the Boltzmann transport equation with the explicit incorporation of electron-phonon scattering *** structural parameters required for dynamic simulations are obtained from ab initio *** results show that although the longitudinal optical modes significantly affect the electron energy relaxation dynamics in both phases due to strong Fr?hlich-type couplings,the detailed relaxation mechanisms have obvious *** the case of a single band,the energy relaxation time in anatase is 24.0 fs,twice longer than 11.8 fs in *** discrepancy is explained by the different diffusion distributions over the electronic Bloch states and different scattering contributions from acoustic modes in the two *** for the multiple-band situation involving the lowest six conduction bands,the predicted overall relaxation times are about 47 fs and 57 fs in anatase and rutile,respectively,very different from the case of the single *** slower relaxation in rutile is attributed to the existence of multiple rate-controlled steps during the dynamic *** present findings may be helpful to control the electron dynamics for designing efficient TiO_(2)-based devices.

摘要：We study the self-gravitating stars with a linear equation of state, P = aρ, in AdS space, where a is a constant parameter. There exists a critical dimension, beyond which the stars are always stable with any central energy density; below which there exists a maximal mass configuration for a certain central energy density and when the central energy density continues to increase, the configuration becomes unstable. We find that the critical dimension depends on the parameter a, it runs from d = 11.1429 to 10.1291 as a varies from a = 0 to 1. The lowest integer dimension for a dynamically stable self-gravitating configuration should be d = 12 for any a E [0, 1] rather than d = 11, the latter is the case of self-gravitating radiation configurations in AdS space.

摘要：Understanding the excited state dynamics of donor-acceptor(D-A)complexes is of fundamental importance both experimentally and ***,we have first explored the photoinduced dynamics of a recently synthesized paddle-wheel BODIPY-hexaoxatriphenylene(BODIPY is the abbreviation for BF_(2)-chelated dipyrromethenes)conjugates D-A complexes with the combination of both electronic structure calculations and nonadiabatic dynamics *** the basis of computational results,we concluded that the BODIPY-hexaoxatriphenylene(BH)conjugates will be promoted to the local excited(LE)states of the BODIPY fragments upon excitation,which is followed by the ultrafast exciton transfer from LE state to charge transfer(CT).Instead of the photoinduced electron transfer process proposed in previous experimental work,such a exciton transfer process is accompanied with the photoinduced hole transfer from BODIPY to ***,solvent effects are found to play an important role in the photoinduced ***,the hole transfer dynamics is accelerated by the acetonitrile solvent,which can be ascribed to significant influences of the solvents on the charge transfer states,*** energy gaps between LE and CT excitons are reduced greatly and the non-adiabatic couplings are increased in the *** present work not only provides valuable insights into the underlying photoinduced mechanism of BH,but also can be helpful for the future design of novel donor-acceptor conjugates with better optoelectronic performance.

摘要：Thermodynamics of phase transition for a black hole in 5D Einstein-Gauss-Bonnet gravity with a negative cosmological constant is *** the Bekenstein-Hawking entropy is adopted,we find the heat capacity,volume expansion coefficient and isothermal compressibility are divergent at the critical points,which implies the existence of phase *** fact that the phase transitions are indeed second order is revealed by studying the Ehrenfest's equations and the Prigogine-Defay *** near the critical points,we also explicitly calculate the critical exponents of the relevant thermodynamic quantities at fixed charge or fixed *** is shown that the corresponding critical exponents satisfy the thermodynamic scaling *** Generalized Homogeneous Function hypothesis is also checked by studying the Helmholtz free energy,which is shown to be consistent with the thermodynamic scaling law.

摘要：Topological phases of matter have been extensively investigated in solid-state materials and classical wave systems with integer dimensions. However, topological states in non-integer dimensions remain almost unexplored. Fractals, being self-similar on different scales, are one of the intriguing complex geometries with non-integer dimensions. Here, we demonstrate fractal higher-order topological states with unprecedented emergent phenomena in a Sierpin? ski acoustic metamaterial. We uncover abundant topological edge and corner states in the acoustic metamaterial due to the fractal geometry. Interestingly,the numbers of the edge and corner states depend exponentially on the system size, and the leading exponent is the Hausdorff fractal dimension of the Sierpin? ski carpet. Furthermore, the results reveal the unconventional spectrum and rich wave patterns of the corner states with consistent simulations and experiments. This study thus unveils unconventional topological states in fractal geometry and may inspire future studies of topological phenomena in non-Euclidean geometries.