摘要：Coal gasification fine slag(FS)is a typical solid waste generated in coal *** current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological *** recovery and the high-value utilization of residual carbon(RC)in FS are the keys to realizing the win-win situation of the coal chemical industry in terms of economic and environmental *** structural properties,such as pore,surface functional group,and microcrystalline structures,of RC in FS(FS-RC)not only affect the flotation recovery efficiency of FS-RC but also form the basis for the high-value utilization of *** this paper,the characteristics of FS-RC in terms of pore structure,surface functional groups,and microcrystalline structure are sorted out in accordance with gasification type and FS particle *** reasons for the formation of the special structural properties of FS-RC are analyzed,and their influence on the flotation separation and high-value utilization of FS-RC is *** methods based on the pore structural characterist-ics of FS-RC,such as ultrasonic pretreatment-pore-blocking flotation and pore breaking-flocculation flotation,are proposed to be the key development technologies for improving FS-RC recovery in the *** design of low-cost,low-dose collectors containing polar bonds based on the surface and microcrystalline structures of FS-RC is proposed to be an important breakthrough point for strengthening the flotation efficiency of FS-RC in the *** high-value utilization of FS should be based on the physicochemical structural proper-ties of FS-RC and should focus on the environmental impact of hazardous elements and the recyclability of chemical waste liquid to es-tablish an environmentally friendly utilization *** review is of great theoretical importance for the comprehensive understand-ing of the unique structural properties of FS-RC,the breakthrough of the technological bottleneck in the e

摘要：Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology regulation, and heterojunction construction strategies to synthesize N-GQD/N-doped TiO_(2)/P-doped porous hollow g-C_(3)N_(4) nanotube (PCN) composite photocatalysts (denoted as G-TPCN). The optimal sample (G-TPCN doped with 0.1wt% N-GQD, denoted as 0.1% G-TPCN) exhibits significantly enhanced photoabsorption, which is attributed to the change in bandgap caused by elemental doping (P and N), the improved light-harvesting resulting from the tube structure, and the upconversion effect of N-GQDs. In addition, the internal charge separation and transfer capability of0.1% G-TPCN are dramatically boosted, and its carrier concentration is 3.7, 2.3, and 1.9 times that of N-TiO_(2), PCN, and N-TiO_(2)/PCN(TPCN-1), respectively. This phenomenon is attributed to the formation of Z-scheme heterojunction between N-TiO_(2) and PCNs, the excellent electron conduction ability of N-GQDs, and the short transfer distance caused by the porous nanotube structure. Compared with those of N-TiO_(2), PCNs, and TPCN-1, the H2 production activity of 0.1%G-TPCN under visible light is enhanced by 12.4, 2.3, and 1.4times, respectively, and its ciprofloxacin (CIP) degradation rate is increased by 7.9, 5.7, and 2.9 times, respectively. The optimized performance benefits from excellent photoresponsiveness and improved carrier separation and migration efficiencies. Finally, the photocatalytic mechanism of 0.1% G-TPCN and five possible degradation pathways of CIP are proposed. This study clarifies the mechanism of multiple modification strategies to synergistically improve the photocatalytic performance of 0.1% G-TPCN and provides a potential strategy for rationally designing novel photocatalysts for environmental remediation and solar energy conversion.

摘要：The utilization of prefabricated light modular radiant heating system has demonstrated significant increases in heat transfer efficiency and energy conservation *** prefabricated building construction,this new heating method presents an opportunity for the development of comprehensive *** parameters for evaluating the effectiveness of such a system are the upper surface layer’s heat flux and *** this paper,thermal resistance analysis calculation based on a simplified model for this unique radiant heating system analysis is presented with the heat transfer mechanism’s *** results obtained from thermal resistance analysis calculation and numerical simulation indicate that the thermal resistance analysis method is highly accurate with temperature discrepancies ranging from 0.44℃ to−0.44℃ and a heat flux discrepancy of less than 7.54%,which can meet the requirements of practical engineering applications,suggesting a foundation for the prefabricated radiant heating system.

摘要：通过将采热管群与充填采矿技术相结合可提取矿井中的地热能,有效缓解高地热带来的热害问题。本文以采热管群为研究对象,分析了充填体放热过程中传热流体的温度、速度和压力分布,讨论了雷诺数、管径、管间距和管排方式对采热管群性能的影响。结果表明:当雷诺数从100增加到5000时,换热量从2.24×10^(3)kJ增加到16.78×10^(3)kJ,综合评价因子从0.087增加到1.31。当管径从4 mm增加到6 mm时,换热量从15.07×10^(3)kJ增加到17.11×10^(3)kJ,综合评价因子从1.157增加到1.388。当管间距从130 mm增加到170 mm时,换热量从14.24×10^(3)kJ增加到16.25×10^(3)kJ,综合评价因子从1.013增加到1.263。此外,四路并联布置可以保证较高的换热量和较低的压降,从而获得较高的综合评价因子。该研究为充填体中采热管群的设计和优化提供了理论参考。

摘要：High-entropy alloys(HEAs),which were introduced as a pioneering concept in 2004,have captured the keen interest of nu-merous ***,in this context,can be perceived as representing disorder and *** contrast,elemental composi-tions within alloy systems occupy specific structural sites in space,a concept referred to as *** accordance with Shannon entropy,structure is analogous to ***,the arrangement of atoms within a material,termed its structure,plays a pivotal role in dictating its *** addition to expanding the array of options for alloy composites,HEAs afford ample opportunities for diverse structural *** profound influence of distinct structural features on the exceptional behaviors of alloys is underscored by numer-ous *** features include remarkably high fracture strength with excellent ductility,antiballistic capability,exceptional radi-ation resistance,and corrosion *** this paper,we delve into various unique material structures and properties while elucidating the intricate relationship between structure and performance.

摘要：为了解决三维空间中的非线性动力学问题,本文提出了一种新的等几何实体单元,并通过张量分析中的坐标变换得到其非线性应变场.为了使所提出的单元能够无缝地应用于计算机辅助设计(CAD)和计算机辅助工程(CAE)系统中,采用三变量T样条作为等几何实体单元的基函数.借助Bézier投影法,提出了基于T样条的等几何实体单元的局部网格更新算法.在重要区域对网格进行局部细化以获得准确的结果,在重要区域以外对冗余单元进行粗化以提高计算效率.因此,非线性动力学分析中的计算效率和计算精度得到了平衡.三个静力学数值算例验证单元弹性模型的正确性.通过柔性摆仿真算例研究该单元的动力学特性.通过实验测试该单元解决非线性动力学实际问题的能力.应用局部网格更新算法进行柔性摆与障碍物碰撞接触的仿真.通过对计算结果和计算耗时的分析,研究基于局部变网格T样条的实体单元在非线性动力学问题中的有效性.

摘要：超高性能混凝土(UHPC)是一种具有巨大潜力的复合材料。为了降低UHPC的成本并获得更好的性能,有必要研究钢纤维在UHPC中的增强机理,实践中也需要一个有效的数值模型来促进UHPC的应用。钢纤维从UHPC中拔出时会产生新的裂纹面,进而需要消耗更多的能量。基于此,推导了新裂纹及其裂纹表面能的公式,提出了一种考虑钢纤维与UHPC基体之间界面断裂能的断裂相场模型。利用该模型,对含钢纤维的三维UHPC试样进行了单轴拉伸数值模拟;开展对比实验验证了所提模型的正确性。结果表明,模拟结果与实验结果吻合较好。通过分析不同试样的新裂纹面与拉伸强度间的关系,发现UHPC的抗拉强度和残余强度随钢纤维体积含量的增加而增加,随钢纤维直径的增加而降低。进一步分析发现,UHPC的抗拉强度与钢纤维的侧表面积成正比。理论分析、数值模拟和实验表明,钢纤维在UHPC中的增强机理为:钢纤维的加入使UHPC基体与钢纤维在断裂过程中产生了一些新的裂纹,这些新裂纹消耗了更多的能量。本文研究工作可为UHPC的性能设计和开发有效的UHPC数值模型提供理论依据。

摘要：聚环氧乙烷(PEO)聚合物电解质有望应用于全固态锂金属电池.然而,目前还没有提出有效的方法制备全固态PEO电解质,以克服其在室温下无法使用的局限性.在本研究中,我们基于聚合物C-H键功能化策略,通过在聚合物链上直接共价连接具有锂配位活性的丁二腈官能团,设计出了一种高离子导电性PEO电解质.该官能团有效增强了PEO链的无序性和流动性,同时也作为链间快速离子传导的活性位点,从而实现了离子周围自由体积和迁移行为的双重优化.得益于官能团对离子输运的精准调节,新型电解质表现出更强的离子传导性(离子电导率提升100倍)、更高的转移数(tLi+=0.51)和更宽的电化学窗口(>0.47 V).特别是功能化的PEO300k电解质具有超高室温离子电导率(25℃时为1.01×10^(-4)S cm^(-1))并且能够在室温下稳定工作,该研究为开发具有实际应用价值的聚合物电解质提供了新的途径.

摘要：具有随机孔隙的多孔泡沫在声音管理应用中得到越来越多的利用,其吸声系数通常作为性能评估和设计优化的关键声学参数.根据不同的加工方法,泡沫中的孔隙可以是全开或半开的,并且通常表现为分形分布特征.为了便于工程应用,有必要对这些泡沫的吸声系数进行分析预测.然而,分析预测泡沫的吸声系数是一个挑战.因此,本研究提出了半开孔和全开孔的简化代表结构来微观分析泡沫内部的流动特性,并应用分形理论来描述随机分布的孔隙.引入一个叫“开孔度”的参数来表征孔隙的开放程度,可以解析地获得代表结构的粘性和热特征长度.随后,在经典吸声系数Johnson-Champoux-Allard模型的基础上,建立了一种将代表结构与分形理论统一起来的解析模型,从而可以将吸声系数作为具有全开/半开孔泡沫的关键形态参数的函数进行预测.与已有的实验测量和数值模拟结果相比,本文提出的分析模型可以较好地预测了半开孔和全开孔泡沫的关键流动特性和吸声系数.在0到4500 Hz的频率范围内,半开孔泡沫相对于具有相同孔隙率的全开孔泡沫可以更好地衰减声波.在孔隙率为0.95的条件下,半开孔泡沫的总体吸声系数分别提高了21.2%、57.7%和75.8%,此时开孔度由0.75到0.50降低了0.25.

摘要：柔性可穿戴的紫外线探测器在个体紫外线暴露监测、智能仿生眼和军事领域受到广泛关注.然而,传统不可拉伸的材料和器件结构设计限制了设备在可动态变形的人体皮肤和非平面表面上的精确监测应用和稳定附着.在本研究中,我们提出了基于氧化铜/碳-水凝胶-氧化锌/碳的新型应变隔离异质结构的本征可拉伸(拉伸应变或弯曲高达150%)紫外线探测器,该探测器具有高灵敏度(开/关比为2100%)、高稳定性(大于4000次循环),以及快速响应和恢复时间(分别为1.5和4 s).值得注意的是,该探测器通过水凝胶桥在氧化铜/碳和氧化锌/碳电极之间引入的p-n结能带结构,以及离子导电水凝胶中I^(-)/I_(3)^(-)的电化学反应机制,显著提高了其载流子效率和紫外线响应强度.本文通过集成传感器与所设计的电路板,进一步开发了一种无线紫外线报警系统,用于紫外线强度超标警报.此外,本文还设计了一种光电传感器阵列,并将其用作视网膜假体,以实现对环境紫外线强度的实时监测和成像.本文基于水凝胶基异质结构为开发可穿戴、可拉伸的光电紫外线传感器单元和成像阵列提供了一种新的可行方法.